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| | (DIMETHYLSULFIDE)GOLD(I) CHLORIDE Basic information | | Reaction |
| Product Name: | (DIMETHYLSULFIDE)GOLD(I) CHLORIDE | | Synonyms: | CHLORO(DIMETHYLSULFIDE)GOLD(I);(DIMETHYLSULFIDE)GOLD(I) CHLORIDE;(Dimethylsulfide)gold(I) chloride,95%;(Dimethylsulfide)gole(I)chloride,95%;(DiMethylsulfide)gole(I)chloride, (CH3SCH3)AuCl;Chloro(dimethyl sulfide)gold;Chloro(methyl sulfide)gold;Dimethylsulfide gold chloride | | CAS: | 29892-37-3 | | MF: | C2H7AuClS | | MW: | 295.55 | | EINECS: | | | Product Categories: | Au | | Mol File: | 29892-37-3.mol |  |
| | (DIMETHYLSULFIDE)GOLD(I) CHLORIDE Chemical Properties |
| Melting point | 160°C(dec.)(lit.) | | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | | form | solid | | color | white to off-white | | Sensitive | light sensitive, store cold | | InChI | InChI=1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H | | InChIKey | PXVFOWATODEOKQ-UHFFFAOYSA-N | | SMILES | S(C)(C)[Au+][Cl-] |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | HS Code | 2930.90.9250 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | (DIMETHYLSULFIDE)GOLD(I) CHLORIDE Usage And Synthesis |
| Reaction |
- Gold(I) precursor to more advanced gold catalysts
- Gold catalyst for the conversion of propargyl sulfoxides to α-thioenones.
| | Uses | Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:
- chloro(trimesitylphosphine)gold(I)
- gold(I) N-heterocyclic carbene (NHC) complexes
- bis(carbene)gold(I) complex of ferrocenyl complexes
- gold(I) acetylide complexes
| | reaction suitability | core: gold
reagent type: catalyst |
| | (DIMETHYLSULFIDE)GOLD(I) CHLORIDE Preparation Products And Raw materials |
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