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GOLD (I) CHLORIDE

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GOLD (I) CHLORIDE Basic information
Uses
Product Name:GOLD (I) CHLORIDE
Synonyms:Gold(I) chloride,97% AuCl;Gold(I) chloride,97%;Gold(I) chloride, 99.99% trace metals basis;Gold(I) chloride, 99.9% trace metals basis;Gold(I) chloride (99.99%-Au) PURATREM;goldchloride(aucl);AUROUS CHLORIDE;GOLD (I) CHLORIDE
CAS:10294-29-8
MF:AuCl
MW:232.42
EINECS:233-655-8
Product Categories:metal halide;Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Gold Catalysis;Gold CatalystsMetal and Ceramic Science;Gold Salts;GoldCatalysis and Inorganic Chemistry;GoldMetal and Ceramic Science;Salts;Au
Mol File:10294-29-8.mol
GOLD (I) CHLORIDE Structure
GOLD (I) CHLORIDE Chemical Properties
Melting point 289 °C (dec.)(lit.)
density 7.57 g/mL at 25 °C(lit.)
storage temp. Inert atmosphere,2-8°C
form Powder
Specific Gravity7.57
color Yellow to green
Water Solubility Very slightly soluble in water. soluble in HCl, HBr organic solvents.
Sensitive Moisture Sensitive
Merck 14,4515
crystal systemsquare
Solubility Product Constant (Ksp)pKsp: 12.7
Space groupI41/amd
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.67390.67390.86999090900.3951
InChI1S/Au.ClH/h;1H/q+1;/p-1
InChIKeyFDWREHZXQUYJFJ-UHFFFAOYSA-M
SMILES[Cl-].[Au+]
CAS DataBase Reference10294-29-8(CAS DataBase Reference)
EPA Substance Registry SystemGold chloride (AuCl) (10294-29-8)
Safety Information
Hazard Codes C
Risk Statements 34-43
Safety Statements 26-27-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
TSCA TSCA listed
HazardClass 8
PackingGroup III
HS Code 28439000
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsSkin Corr. 1B
Skin Sens. 1
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
GOLD (I) CHLORIDE Usage And Synthesis
UsesGold (I) Chloride is used chiefly in photography as a print toning agent, as a starting solution to form other gold compounds, as a precursor to the preparation of Ultra Pure Gold Metal, in gilding ceramic ware and glass, and in the manufacture of purple of Cassius.
Chemical PropertiesYellow orthorhombic crystals; density 7.6 g/cm3; decomposes on heating at about 298°C; loses its stoichiometric composition at 170°C; very slightly soluble in cold water; decomposes in hot water; soluble in hydrochloric and hydrobromic acids, and alkali cyanide solutions.
Physical propertiesYellow orthorhombic crystals; density 7.6 g/cm3; decomposes on heating at about 298°C; loses its stoichiometric composition at 170°C; very slightly soluble in cold water; decomposes in hot water; soluble in hydrochloric and hydrobromic acids, and alkali cyanide solutions.
UsesGold(I) chloride is used as a starting material for the preparation of Phosphine ligated gold(I) complexes, which is used as catalysts in synthetic chemistry. It is also used to prepare metallic gold and potassium auric bromide and potassium chloride.
PreparationGold(I) chloride is prepared by thermal decomposition of gold trichloride: AuCl3 AuCl + Cl2.
General DescriptionThe structure of gold chloride is monoclinic. It sublimes at elevated temperatures.
reaction suitabilityreagent type: catalyst
core: gold
GOLD (I) CHLORIDE Preparation Products And Raw materials
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