Dimethyl-d6 sulfide

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Dimethyl-d6 sulfide Basic information
Product Name:Dimethyl-d6 sulfide
Synonyms:HEXADEUTERODIMETHYL SULFIDE;DIMETHYL SULFIDE-D6;(METHYL SULFIDE)-D6;di[(2H3)methyl] sulphide;Di(2H3)methyl sulfide;(Methyl sulfide)-d6, Hexadeuterodimethyl sulfide;1,1'-ThiobisMethane-d3;Dimethyl sulfide-d6 99 atom % D
CAS:926-09-0
MF:C2D6S
MW:68.17
EINECS:213-133-6
Product Categories:Alphabetical Listings;D;High Throughput NMR;Labware;NMR;NMR Solvents;NMR Solvents and Reagents;Routine NMR;Solvent by Application;Solvents;Solvents for High Throughput NMR;Spectroscopy Solvents (IR;Stable Isotopes;Tubes and Accessories;UV/Vis);Additional NMR Solvents;Aldrich High Purity NMR Solvents for Routine NMR
Mol File:926-09-0.mol
Dimethyl-d6 sulfide Structure
Dimethyl-d6 sulfide Chemical Properties
Boiling point 36.5 °C (lit.)
density 0.928 g/mL at 25 °C (lit.)
refractive index n20/D 1.431(lit.)
Fp −34 °F
solubility Chloroform (Soluble), Ethyl Acetate (Slightly), Methanol (Sparingly)
form Liquid
color Colourless
BRN 2036892
InChI1S/C2H6S/c1-3-2/h1-2H3/i1D3,2D3
InChIKeyQMMFVYPAHWMCMS-WFGJKAKNSA-N
SMILES[2H]C([2H])([2H])SC([2H])([2H])[2H]
Safety Information
Hazard Codes F,Xn
Risk Statements 22-36/37/38-41
Safety Statements 16-23-26-36
RIDADR UN 1164 3/PG 2
WGK Germany 3
Storage Class3 - Flammable liquids
Hazard ClassificationsFlam. Liq. 2
MSDS Information
ProviderLanguage
SigmaAldrich English
Dimethyl-d6 sulfide Usage And Synthesis
UsesIsotope labelled 1,1тАЩ-Thiobismethane is used in the synthesis of heterocyclic carbene complexes that are toxic to cancer cells. It is also used in the synthesis of compounds displaying antimalarial activity.
General DescriptionDimethyl sulfide-d6 [(CD3)2S] is a deuterated NMR solvent useful in NMR-based research and analyses. It can form 1:1 complex with halothane by the formation of C–H…S hydrogen bonds. During the reaction of (CD3)2S with singlet oxygen in aprotic solvents, the H-D exchange in the methyl group was observed. The electronic spectra of (CD3)2S has been measured between 1250 and 2500.
Dimethyl-d6 sulfide Preparation Products And Raw materials
Preparation ProductsTrimethyl-d9-sulfonium iodide
Tag:Dimethyl-d6 sulfide(926-09-0) Related Product Information
Dimethyl sulfide Dimethyl-d6 sulfone Dimethyl-d6 sulfide 2-[(4-Chlorophenyl)sulfanyl]-4,8-dimethylquinoline Trimethyl-d9-sulfoxonium iodide L-Methionine-d3 (S-methyl-d3)-methyl-d3 sulfonium chloride Trimethyl-d9-sulfonium iodide benzyl 4,6-dimethyl-2-quinazolinyl sulfide 2-chlorobenzyl 4,6-dimethyl-2-pyrimidinyl sulfide 2-(10,11-dihydro-5H-dibenzo[b,f]azepin-5-yl)-2-oxoethyl 4,6-dimethyl-2-pyrimidinyl sulfide Dimethyl-D6 Sulfide + 1% TMS (v/v) Butyl(3,3-dimethyl-1-butynyl) sulfide Dimethyl(pentafluorophenyl)phosphine sulfide Butyl [(Z)-3,3-dimethyl-1-butenyl] sulfide Dimethyl-D6 Sulfide + 0.05% TMS (v/v) Dimethyl-D6 Sulfide "100%"