TIGLOYL CHLORIDE

TIGLOYL CHLORIDE Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
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TIGLOYL CHLORIDE Basic information
Product Name:TIGLOYL CHLORIDE
Synonyms:TRANS-2-METHYL-2-BUTENOYL CHLORIDE;TIGLOYL CHLORIDE;(E)-2-methylcrotonoyl chloride;Tiglyl chloride;(E)-2-METHYL-BUT-2-ENOYL CHLORIDE;(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride;(E)-2-Methyl-2-butenoic acid chloride;2-Methylcrotonic acid chloride
CAS:35660-94-7
MF:C5H7ClO
MW:118.56
EINECS:252-659-0
Product Categories:
Mol File:35660-94-7.mol
TIGLOYL CHLORIDE Structure
TIGLOYL CHLORIDE Chemical Properties
Boiling point 145 °C
density 1,08 g/cm3
refractive index n20/D 1.471
Fp 22 °C
storage temp. -20°C
solubility soluble in Chloroform, Methanol
form clear liquid
color Colorless to Almost colorless
InChI1S/C5H7ClO/c1-3-4(2)5(6)7/h3H,1-2H3/b4-3+
InChIKeyTUNLYEHIVPWOHK-ONEGZZNKSA-N
SMILESC\C=C(/C)C(Cl)=O
Safety Information
Hazard Codes T
Risk Statements 10-23/24/25-34
Safety Statements 16-26-36/37/39-45
RIDADR 3265
WGK Germany 3
HazardClass 8/3
PackingGroup II
HS Code 2916199590
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B
MSDS Information
TIGLOYL CHLORIDE Usage And Synthesis
Chemical PropertiesClear Colourless Oil
UsesTigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.
Synthesis Reference(s)Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5
TIGLOYL CHLORIDE Preparation Products And Raw materials
Preparation ProductsCephalomannine-->N-Succinimidyl Methacrylate-->N-Tigloylglycine-->2-Butenamide, 2-methyl-N-(1-methylethyl)-, (E)- (9CI)-->Ajugamarin H1
Tag:TIGLOYL CHLORIDE(35660-94-7) Related Product Information
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