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| | TIGLOYL CHLORIDE Basic information |
| Product Name: | TIGLOYL CHLORIDE | | Synonyms: | TRANS-2-METHYL-2-BUTENOYL CHLORIDE;TIGLOYL CHLORIDE;(E)-2-methylcrotonoyl chloride;Tiglyl chloride;(E)-2-METHYL-BUT-2-ENOYL CHLORIDE;(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride;(E)-2-Methyl-2-butenoic acid chloride;2-Methylcrotonic acid chloride | | CAS: | 35660-94-7 | | MF: | C5H7ClO | | MW: | 118.56 | | EINECS: | 252-659-0 | | Product Categories: | | | Mol File: | 35660-94-7.mol |  |
| | TIGLOYL CHLORIDE Chemical Properties |
| Boiling point | 145 °C | | density | 1,08 g/cm3 | | refractive index | n20/D 1.471 | | Fp | 22 °C | | storage temp. | -20°C | | solubility | soluble in Chloroform, Methanol | | form | clear liquid | | color | Colorless to Almost colorless | | InChI | 1S/C5H7ClO/c1-3-4(2)5(6)7/h3H,1-2H3/b4-3+ | | InChIKey | TUNLYEHIVPWOHK-ONEGZZNKSA-N | | SMILES | C\C=C(/C)C(Cl)=O |
| Hazard Codes | T | | Risk Statements | 10-23/24/25-34 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | 3265 | | WGK Germany | 3 | | HazardClass | 8/3 | | PackingGroup | II | | HS Code | 2916199590 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B |
| | TIGLOYL CHLORIDE Usage And Synthesis |
| Chemical Properties | Clear Colourless Oil | | Uses | Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans. | | Synthesis Reference(s) | Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5 |
| | TIGLOYL CHLORIDE Preparation Products And Raw materials |
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