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| | 1-Chloro-2-butene Basic information |
| Product Name: | 1-Chloro-2-butene | | Synonyms: | (2E)-1-Chloro-2-butene;1-chloro-2-buten;1-chloro-but-2-ene;1-chlorobut-2-ene;2-Butene,1-chloro-;2-Butenyl chloride;2-butenylchloride;alpha-Chloro-beta-butylene | | CAS: | 591-97-9 | | MF: | C4H7Cl | | MW: | 90.55 | | EINECS: | 209-739-5 | | Product Categories: | | | Mol File: | 591-97-9.mol |  |
| | 1-Chloro-2-butene Chemical Properties |
| Melting point | -65°C | | Boiling point | 85-86 °C(lit.) | | density | 0.923 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.430 | | Fp | -12°C | | storage temp. | 0-6°C | | solubility | water: soluble14g/L at 20°C | | form | clear liquid | | color | Colorless to Light yellow | | Water Solubility | 999mg/L(temperature not stated) | | Merck | 14,2130 | | BRN | 605304 | | Henry's Law Constant | 9.5×10-4 mol/(m3Pa) at 25℃, Ebert et al. (2023) | | Stability: | Stable. Highly flammable. Incompatible with strong oxidizing agents. | | InChI | 1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+ | | InChIKey | YTKRILODNOEEPX-NSCUHMNNSA-N | | SMILES | C\C=C\CCl | | CAS DataBase Reference | 591-97-9(CAS DataBase Reference) | | NIST Chemistry Reference | 2-Butene, 1-chloro-(591-97-9) | | EPA Substance Registry System | 2-Butene, 1-chloro- (591-97-9) |
| Hazard Codes | F,C | | Risk Statements | 11-22-34-43 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2924 3/PG 2 | | WGK Germany | 2 | | RTECS | EM4264000 | | F | 19 | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29049090 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 3 Oral
Aquatic Chronic 3
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1A
Skin Sens. 1 |
| | 1-Chloro-2-butene Usage And Synthesis |
| Description | 1-Chloro-2-butene is a butenylating agent via Grignard and other organometallic reagents, organoborane compounds, other nucleophiles, and organosilane compounds. | | Chemical Properties | colourless liquid | | Uses | Crotyl chloride has been used:
- to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
- in the preparation of (E)-crotyltrichlorosilane
| | Preparation | pure isomers of 1-Chloro-2-butene can be prepared by chloride displacement of corresponding alcohols via Ph3P in various solvents, and other chlorinating agents. | | General Description | Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes. |
| | 1-Chloro-2-butene Preparation Products And Raw materials |
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