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| | Dimethylthiocarbamoyl chloride Basic information |
| | Dimethylthiocarbamoyl chloride Chemical Properties |
| Melting point | 39-43 °C (lit.) | | Boiling point | 90-95 °C/0.5 mmHg (lit.) | | density | 1.204 (estimate) | | refractive index | 1.6100 (estimate) | | Fp | 209 °F | | storage temp. | 2-8°C | | solubility | Soluble in chloroform and tetrahydrofuran. | | pka | 0.30±0.50(Predicted) | | form | Low Melting Crystalline Solid or Crystals | | color | Slightly yellow to yellow | | Water Solubility | reacts | | Sensitive | Moisture Sensitive | | BRN | 635823 | | InChI | 1S/C3H6ClNS/c1-5(2)3(4)6/h1-2H3 | | InChIKey | PHWISQNXPLXQRU-UHFFFAOYSA-N | | SMILES | CN(C)C(Cl)=S | | CAS DataBase Reference | 16420-13-6(CAS DataBase Reference) | | NIST Chemistry Reference | Carbamothioic chloride, dimethyl-(16420-13-6) | | EPA Substance Registry System | Carbamothioic chloride, dimethyl- (16420-13-6) |
| Hazard Codes | C | | Risk Statements | 22-34-29-14 | | Safety Statements | 26-36/37/39-45-8-30-22-27 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 2 | | F | 10-19-21 | | Hazard Note | Corrosive | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29302000 | | Storage Class | 11 - Combustible Solids |
| | Dimethylthiocarbamoyl chloride Usage And Synthesis |
| Chemical Properties | slightly yellow to yellow low melting crystalline | | Uses | Dimethylthiocarbamoyl chloride is used as an intermediate in the synthesis of pharmaceuticals. It finds application in chemoselective deoxygenation of pyridine-N-oxides. It is also used as a starting reagent in the synthesis of dimethylthiocarbamates. | | Uses | Dimethylthiocarbamoyl chloride was used in chemoselective deoxygenation of pyridine-N-oxides. It was used in the synthesis of (±)-thia-calanolide A. It was used as starting reagent in the synthesis of dimethylthiocarbamates. | | Purification Methods | Crystallise it twice from pentane and/or distil it at low pressure. [Beilstein 4 III 147.] |
| | Dimethylthiocarbamoyl chloride Preparation Products And Raw materials |
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