| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Email: |
saleschina@alfa-asia.com |
- 1-Iodonaphthalene
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- $320.00
-
2026-09-20
- CAS:90-14-2
- Min. Order: 1KG
- Purity: 98%
- Supply Ability: 20 tons
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| | 1-Iodonaphthalene Basic information |
| | 1-Iodonaphthalene Chemical Properties |
| Melting point | 4°C | | Boiling point | 163-165 °C/15 mmHg (lit.) | | density | 1.74 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.701(lit.) | | Fp | >230 °F | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | solubility | 0.007g/l | | form | liquid (clear) | | color | clear very deep brown-yellow | | Specific Gravity | 1.74 | | Water Solubility | Slightly soluble in water. | | Sensitive | Light Sensitive | | BRN | 1906415 | | Dielectric constant | 4.5599999999999996 | | InChI | 1S/C10H7I/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H | | InChIKey | NHPPIJMARIVBGU-UHFFFAOYSA-N | | SMILES | Ic1cccc2ccccc12 | | CAS DataBase Reference | 90-14-2(CAS DataBase Reference) | | NIST Chemistry Reference | 1-Iodonaphthalene(90-14-2) | | EPA Substance Registry System | Naphthalene, 1-iodo- (90-14-2) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-37/39 | | WGK Germany | 3 | | F | 8 | | TSCA | TSCA listed | | HS Code | 29036990 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2 |
| | 1-Iodonaphthalene Usage And Synthesis |
| Chemical Properties | clear yellow to brown liquid | | Uses | 1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine. | | General Description | Ultrafast relaxation of 1-iodonaphthalene has been studied by time-resolved femtosecond pump-probe mass spectrometry. 1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine. | | References | [1] Tetrahedron Letters, 2011, vol. 52, # 16, p. 1993 - 1995
[2] Synlett, 2014, vol. 25, # 7, p. 995 - 1000
[3] Journal of Fluorine Chemistry, 2016, vol. 189, p. 59 - 67
[4] Chemistry - A European Journal, 2011, vol. 17, # 20, p. 5652 - 5660
[5] Catalysis Communications, 2013, vol. 32, p. 15 - 17 |
| | 1-Iodonaphthalene Preparation Products And Raw materials |
| Raw materials | Hydrochloric acid-->Diethyl ether-->Acetic acid-->Hexane-->Potassium iodide-->Sodium thiosulfate-->Naphthalene-->Potassium bromate-->1-Iodo-8-methylnaphthalene-->1,8-Diiodonaphthalene-->1,8-Dimethylnaphthalene | | Preparation Products | 1-Naphthalenemethanol-->7H-Benz[de]anthracen-7-one, 11-nitro--->1-(4-Bromophenyl)-naphthlene-->4,4'-Dinitrodiphenic acid-->2-(1-Naphthylene)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane-->1,1'-Binaphthyl |
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