Hydrocarbon halides

Hydrocarbon halide, or hydrocarbon for short, refers to the product produced during the process of hydrogen atoms replaced by by halogen (fluorine, chlorine, bromine, iodine) in the hydrocarbon molecules. According to the different hydrocarbon groups, it could be divided into categories like aliphatic halogenated hydrocarbons (including saturated and unsaturated halogenated hydrocarbons), aromatic halogenated hydrocarbons. According to the amount of halogen atoms contained in the molecule, it could be divided into categories like halogenated hydrocarbons, dihalogenated hydrocarbons and polyhalogenated hydrocarbons. Most of the halogenated hydrocarbons are liquid. The proportion of Iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. They are insoluble in water and could be dissolved in any proportion with hydrocarbons, they also could dissolve many other organics. The proportion of Hydrocarbon halide would decreases with the increase of the amount of carbon atoms. When there are the same hydrocarbon groups, the boiling point and the proportion of the halogenated hydrocarbons would increase in the order of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons. In the isomer, the more branches it gets, the lower boiling point it has. Most of these substances are toxic and can burn. And their combustion properties decrease with the increase of the amount of halogen atoms in the compound. When it comes to storage, fire hazard should be managed in A, B, C three categories according to fire risk indicators. When it catch fire, the gas should be treated by the C class of fire treatment, liquid by B class of fire treatment. Eenough attention should be payed to anti-virus.
The amount of naturally occurring halo hydrocarbons is very small, and the majority of halo hydrocarbons are synthesized by halogenation of alkanes, and compounded by unsaturated hydrocarbons. It also could be compounded during the reaction between alcohol with hydrohalic acid.
The amount of Halohydrocarbons are more isomers than corresponding hydrocarbons. Apart from the carbon isomerism, unsaturated bond position isomerization, cis-trans isomerism and optical isomerism, there are halogen atom isomerizations as well.. when the Halogenated hydrocarbon was named, the hydrocarbon plays a rule as the matrix while halogen atom plays as substituents. The position, number and name of halogen should be lined out before the name of the hydrocarbon. At room temperature, apart from methyl chloride, methyl bromide, ethyl chloride, vinyl chloride and others which are gas in room temperature, the halo hydrocarbon is liquid in general and the highly  halogenated hydrocarbon is solid.
Halohydrocarbons is not dissolvable in water, but soluble in a variety of organic solvents, and can be dissolved in a variety of weak polarity and non-polar organic compounds. So it  is a kind of commonly used solvent. The relative density of iodinated hydrocarbons, brominated hydrocarbons and polyhalogenated hydrocarbons are all higher than 1. The boiling point of halogenated hydrocarbons increases with the increasing atomic amount of halogen atoms. The boiling point of the same series of halogenated hydrocarbons increases with increase of the amount of carbon chain. The more branched the isomer, the lower the boiling point would it have (except from fluorinated alkanes).
The chemical property of halogenated hydrocarbons is much more active than paraffin, so  halogenated hydrocarbons can produce a variety of chemical reactions, and turn them into various types of compounds. It has an important position in organic synthesis. Halo hydrocarbon has been applied widely in many trades, apart from being used as a solvent, it also could be used as refrigerant, extinguishing agent, anesthetics and preservatives.
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Structure Chemical Name CAS MF
4,4'-Diiodobiphenyl 4,4'-Diiodobiphenyl 3001-15-8 C12H8I2
2-Bromo-m-xylene 2-Bromo-m-xylene 576-22-7 C8H9Br
3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE 3,5-BIS(TRIFLUOROMETHYL)IODOBENZENE 328-73-4 C8H3F6I
4-Bromocumene 4-Bromocumene 586-61-8 C9H11Br
2,6-Dimethylfluorobenzene 2,6-Dimethylfluorobenzene 443-88-9 C8H9F
4-CHLORO-2-FLUOROIODOBENZENE 4-CHLORO-2-FLUOROIODOBENZENE 6797-79-1 C6H3ClFI
1,4-Dibromobenzene 1,4-Dibromobenzene 106-37-6 C6H4Br2
3-Iodotoluene 3-Iodotoluene 625-95-6 C7H7I
4-Iodotoluene 4-Iodotoluene 624-31-7 C7H7I
2,4,6-Trimethybromombenzene 2,4,6-Trimethybromombenzene 576-83-0 C9H11Br
2,5-Dimethylbromobenzene 2,5-Dimethylbromobenzene 553-94-6 C8H9Br
alpha,alpha'-Dibromo-p-xylene alpha,alpha'-Dibromo-p-xylene 623-24-5 C8H8Br2
4-Bromo-o-xylene 4-Bromo-o-xylene 583-71-1 C8H9Br
1-Chlorooctadecane 1-Chlorooctadecane 3386-33-2 C18H37Cl
1-Bromotetradecane 1-Bromotetradecane 112-71-0 C14H29Br
2-Bromofluorene 2-Bromofluorene 1133-80-8 C13H9Br
1-Bromohexane 1-Bromohexane 111-25-1 C6H13Br
2,7-Dibromofluorene 2,7-Dibromofluorene 16433-88-8 C13H8Br2
1,3-Dichloropropane 1,3-Dichloropropane 142-28-9 C3H6Cl2
1-Bromo-3,5-difluorobenzene 1-Bromo-3,5-difluorobenzene 461-96-1 C6H3BrF2
1-Bromo-3-methylbutane 1-Bromo-3-methylbutane 107-82-4 C5H11Br
3-Bromofluorobenzene 3-Bromofluorobenzene 1073-06-9 C6H4BrF
1-Bromoheptane 1-Bromoheptane 629-04-9 C7H15Br
5-Bromo-m-xylene 5-Bromo-m-xylene 556-96-7 C8H9Br
3,3-Dimethylallyl bromide 3,3-Dimethylallyl bromide 870-63-3 C5H9Br
4-Bromo-2-fluorobenzyl bromide 4-Bromo-2-fluorobenzyl bromide 76283-09-5 C7H5Br2F
(2-Bromoethyl)benzene (2-Bromoethyl)benzene 103-63-9 C8H9Br
2-FLUORO-6-(TRIFLUOROMETHYL)BENZYL BROMIDE 2-FLUORO-6-(TRIFLUOROMETHYL)BENZYL BROMIDE 239087-08-2 C8H5BrF4
2-Bromobiphenyl 2-Bromobiphenyl 2052-07-5 C12H9Br
2,6-Difluorobenzyl bromide 2,6-Difluorobenzyl bromide 85118-00-9 C7H5BrF2
2-(Trifluoromethyl)benzyl bromide 2-(Trifluoromethyl)benzyl bromide 395-44-8 C8H6BrF3
2-Fluorobenzyl bromide 2-Fluorobenzyl bromide 446-48-0 C7H6BrF
1-Bromohexadecane 1-Bromohexadecane 112-82-3 C16H33Br
2,3,4-Trifluorobenzyl bromide 2,3,4-Trifluorobenzyl bromide 157911-55-2 C7H4BrF3
1-Chlorotetradecane 1-Chlorotetradecane 2425-54-9 C14H29Cl
2-Methylbenzyl chloride 2-Methylbenzyl chloride 552-45-4 C8H9Cl
4-Fluoro-2-(trifluoromethyl)benzyl bromide 4-Fluoro-2-(trifluoromethyl)benzyl bromide 206860-48-2 C8H5BrF4
Bromodiphenylmethane Bromodiphenylmethane 776-74-9 C13H11Br
1,4-Dibromo-2,5-dimethylbenzene 1,4-Dibromo-2,5-dimethylbenzene 1074-24-4 C8H8Br2
1,5-Dibromopentane 1,5-Dibromopentane 111-24-0 C5H10Br2
1-BROMO-2,3,5,6-TETRAFLUOROBENZENE 1-BROMO-2,3,5,6-TETRAFLUOROBENZENE 1559-88-2 C6HBrF4
1,4-Dibromo-2,5-difluorobenzene 1,4-Dibromo-2,5-difluorobenzene 327-51-5 C6H2Br2F2
1-Bromo-2-iodobenzene 1-Bromo-2-iodobenzene 583-55-1 C6H4BrI
2,3-DIFLUOROETHOXYBENZENE 2,3-DIFLUOROETHOXYBENZENE 121219-07-6 C8H8F2O
4-Bromobenzyl bromide 4-Bromobenzyl bromide 589-15-1 C7H6Br2
3-Chloromethyl-benzotrifluoride 3-Chloromethyl-benzotrifluoride 705-29-3 C8H6ClF3
2-Bromobenzyl bromide 2-Bromobenzyl bromide 3433-80-5 C7H6Br2
1-Bromooctadecane 1-Bromooctadecane 112-89-0 C18H37Br
2-Iodotoluene 2-Iodotoluene 615-37-2 C7H7I
1-Bromo-4-iodobenzene 1-Bromo-4-iodobenzene 589-87-7 C6H4BrI
1-Bromo-3-iodobenzene 1-Bromo-3-iodobenzene 591-18-4 C6H4BrI
2-Bromooctane 2-Bromooctane 557-35-7 C8H17Br
Allyl bromide Allyl bromide 106-95-6 C3H5Br
2-BROMO-4-FLUORO-1-IODOBENZENE 2-BROMO-4-FLUORO-1-IODOBENZENE 202865-73-4 C6H3BrFI
4-Fluorobenzyl chloride 4-Fluorobenzyl chloride 352-11-4 C7H6ClF
4,4'-Dibromobiphenyl 4,4'-Dibromobiphenyl 92-86-4 C12H8Br2
Chlorotriethylsilane Chlorotriethylsilane 994-30-9 C6H15ClSi
4-Fluorobenzyl bromide 4-Fluorobenzyl bromide 459-46-1 C7H6BrF
1-Bromonaphthalene 1-Bromonaphthalene 90-11-9 C10H7Br
4-Bromofluorobenzene 4-Bromofluorobenzene 460-00-4 C6H4BrF
1-Bromododecane 1-Bromododecane 143-15-7 C12H25Br
2,5-Difluorobenzyl bromide 2,5-Difluorobenzyl bromide 85117-99-3 C7H5BrF2
5-Bromo-1,2,3-trifluorobenzene 5-Bromo-1,2,3-trifluorobenzene 138526-69-9 C6H2BrF3
3,5-Bis(trifluoromethyl)bromobenzene 3,5-Bis(trifluoromethyl)bromobenzene 328-70-1 C8H3BrF6
3,5-Di-tert-butylbromobenzene 3,5-Di-tert-butylbromobenzene 22385-77-9 C14H21Br
3,5-Bis(trifluoromethyl)benzyl bromide 3,5-Bis(trifluoromethyl)benzyl bromide 32247-96-4 C9H5BrF6
1-Chloro-2-iodobenzene 1-Chloro-2-iodobenzene 615-41-8 C6H4ClI
1-Bromo-2,4-difluorobenzene 1-Bromo-2,4-difluorobenzene 348-57-2 C6H3BrF2
4-Bromo-1-butene 4-Bromo-1-butene 5162-44-7 C4H7Br
4-(TRIFLUOROMETHYL)BENZYL BROMIDE 4-(TRIFLUOROMETHYL)BENZYL BROMIDE 402-49-3 C8H6BrF3
2-(Trifluoromethyl)benzyl chloride 2-(Trifluoromethyl)benzyl chloride 21742-00-7 C8H6ClF3
2,4-Difluorobenzyl bromide 2,4-Difluorobenzyl bromide 23915-07-3 C7H5BrF2
3-Fluorobenzyl bromide 3-Fluorobenzyl bromide 456-41-7 C7H6BrF
1,3-Difluorobenzene 1,3-Difluorobenzene 372-18-9 C6H4F2
1-Bromodecane 1-Bromodecane 112-29-8 C10H21Br
1-Fluoro-4-iodobenzene 1-Fluoro-4-iodobenzene 352-34-1 C6H4FI
2-Bromo-2-methylpropane 2-Bromo-2-methylpropane 507-19-7 C4H9Br
2,3-Difluorobenzyl bromide 2,3-Difluorobenzyl bromide 113211-94-2 C7H5BrF2
1-Bromo-3,5-dimethyladamantane 1-Bromo-3,5-dimethyladamantane 941-37-7 C12H19Br
2-Bromonaphthalene 2-Bromonaphthalene 580-13-2 C10H7Br
3-Chlorobenzyl bromide 3-Chlorobenzyl bromide 766-80-3 C7H6BrCl
2-Bromochlorobenzene 2-Bromochlorobenzene 694-80-4 C6H4BrCl
5-Bromo-1-pentene 5-Bromo-1-pentene 1119-51-3 C5H9Br
1,10-Dibromodecane 1,10-Dibromodecane 4101-68-2 C10H20Br2
1,4-Dibromobutane 1,4-Dibromobutane 110-52-1 C4H8Br2
4-Pentylbromobenzene 4-Pentylbromobenzene 51554-95-1 C11H15Br
3-Bromobenzyl bromide 3-Bromobenzyl bromide 823-78-9 C7H6Br2
1-BROMO-2,4-DICHLOROBENZENE 1-BROMO-2,4-DICHLOROBENZENE 1193-72-2 C6H3BrCl2
2,4,5-Trifluorobenzyl bromide 2,4,5-Trifluorobenzyl bromide 157911-56-3 C7H4BrF3
1,2-Dibromo-4,5-difluorobenzene 1,2-Dibromo-4,5-difluorobenzene 64695-78-9 C6H2Br2F2
Benzyl bromide Benzyl bromide 100-39-0 C7H7Br
2-Bromotoluene 2-Bromotoluene 95-46-5 C7H7Br
3-Chlorobenzyl chloride 3-Chlorobenzyl chloride 620-20-2 C7H6Cl2
4-Bromo-1,2-difluorobenzene 4-Bromo-1,2-difluorobenzene 348-61-8 C6H3BrF2
1,3-Dibromopropane 1,3-Dibromopropane 109-64-8 C3H6Br2
1,3-Dibromobenzene 1,3-Dibromobenzene 108-36-1 C6H4Br2
4-Methylbenzyl bromide 4-Methylbenzyl bromide 104-81-4 C8H9Br
2-Bromofluorobenzene 2-Bromofluorobenzene 1072-85-1 C6H4BrF
1,2-Dibromobenzene 1,2-Dibromobenzene 583-53-9 C6H4Br2
1-Chloro-4-iodobenzene 1-Chloro-4-iodobenzene 637-87-6 C6H4ClI
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