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| | Ethyl dibromoacetate Basic information |
| Product Name: | Ethyl dibromoacetate | | Synonyms: | Ethyl dibromoacetate, tech., 83%;Ethyl dibromoacetate , 83%, tech.;ethyl 2,2-dibroMoacetate;Acetic acid, dibromo-, ethyl ester;Dibromoacetic acid, ethyl ester;dibromo-aceticaciethylester;Ethyl dibromoacetate, pract., 95%;Acetic acid, 2,2-dibromo-, ethyl ester | | CAS: | 617-33-4 | | MF: | C4H6Br2O2 | | MW: | 245.9 | | EINECS: | 210-510-7 | | Product Categories: | | | Mol File: | 617-33-4.mol |  |
| | Ethyl dibromoacetate Chemical Properties |
| Melting point | 76-78° | | Boiling point | 77 °C (12 mmHg) | | density | 1.902 | | refractive index | 1.492-1.502 | | Fp | 76-78°C/12mm | | storage temp. | RT, stored under nitrogen | | solubility | Soluble in hexane, ether, CH2Cl2, acetone, EtOAc, ethanol. | | Appearance | Colorless to light yellow Liquid | | EPA Substance Registry System | Acetic acid, dibromo-, ethyl ester (617-33-4) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 37/39-26 | | RIDADR | 3265 | | TSCA | TSCA listed |
| | Ethyl dibromoacetate Usage And Synthesis |
| Description | Ethyl dibromoacetate is used in preparation of α-bromo and α,α-dialkyl substituted esters; undergoes Reformatsky/Darzens reactions with aldehydes and ketones. | | Chemical Properties | clear colorless to slighlty brown liquid | | Uses | Ethyl dibromoacetate can be used to produce diphenoxy-acetic acid ethyl ester. It is used in organic synthesis. | | Purification Methods | Wash the ester briefly with conc aqueous NaHCO3, then with aqueous CaCl2. Dry it with CaSO4 and distil it under reduced pressure. [Hornyak & Amis J Am Chem Soc 79 2079 1957, Beilstein 2 H 219, 2 I 97, 2 III 484, 2 IV 533.] |
| | Ethyl dibromoacetate Preparation Products And Raw materials |
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