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Santa Cruz Biotechnology Inc
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Product Name:(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate
CAS:65012-74-0
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Absin Bioscience Inc.
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CAS:65012-74-0
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Riedel-de Haen AG
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800 558-9160 |
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Product Name:(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate
CAS:65012-74-0
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SIGMA-RBI
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800 736 3690 (Orders) |
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| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Basic information |
| Product Name: | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE | | Synonyms: | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE;(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I);bicycloheptadiene(diphenylphosphino)butane rhodium ClO4 | | CAS: | 65012-74-0 | | MF: | C35H36ClO4P2Rh | | MW: | 720.96 | | EINECS: | | | Product Categories: | | | Mol File: | 65012-74-0.mol | ![(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Structure](CAS/GIF/65012-74-0.gif) |
| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Chemical Properties |
| Melting point | 210 °C (dec.)(lit.) | | solubility | sol CH2Cl2, MeOH, THF/MeOH, and H2O/MeOH mixtures; sparingly sol THF; insol Et2O |
| Hazard Codes | O,Xi | | Risk Statements | 8-36/37/38 | | Safety Statements | 17-26-36 | | RIDADR | UN 1479 5.1/PG 2 | | WGK Germany | 3 | | HazardClass | 5.1 | | PackingGroup | III |
| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Usage And Synthesis |
| Uses |
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is a catalyst precursor used in the asymmetric hydrogenation of amino acid precursors, as well as in transfer hydrogenation and hydrosilation reactions
| | Synthesis | Cationic rhodium-chiraphos complexes are usually prepared in situ or from the procedure given below. In reactions employing the various rhodium-chiraphos complexes, the diene ligand is frequently hydrogenated prior to catalysis to afford the active solvated catalyst precursors [RhS2(chiraphos)]+.
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| | (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Preparation Products And Raw materials |
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