(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate

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(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate Basic information
Product Name:(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate
Synonyms:(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I);bicycloheptadiene(diphenylphosphino)butane rhodium ClO4;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate
CAS:65012-74-0
MF:C35H36ClO4P2Rh
MW:720.96
EINECS:
Product Categories:
Mol File:65012-74-0.mol
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate Structure
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate Chemical Properties
Melting point 210 °C (dec.)(lit.)
solubility sol CH2Cl2, MeOH, THF/MeOH, and H2O/MeOH mixtures; sparingly sol THF; insol Et2O
Safety Information
Hazard Codes O,Xi
Risk Statements 8-36/37/38
Safety Statements 17-26-36
RIDADR UN 1479 5.1/PG 2
WGK Germany 3
HazardClass 5.1
PackingGroup III
MSDS Information
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SigmaAldrich English
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate Usage And Synthesis
Uses (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is a catalyst precursor used in the asymmetric hydrogenation of amino acid precursors, as well as in transfer hydrogenation and hydrosilation reactions
SynthesisCationic rhodium-chiraphos complexes are usually prepared in situ or from the procedure given below. In reactions employing the various rhodium-chiraphos complexes, the diene ligand is frequently hydrogenated prior to catalysis to afford the active solvated catalyst precursors [RhS2(chiraphos)]+.
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate Preparation Products And Raw materials
Tag:(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate(65012-74-0) Related Product Information
(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)-butane] rhodium(I) perchlorate (S)-(-)-1,2-Bis(diphenylphosphino)propane (2S,3S)-(-)-Bis(diphenylphosphino)butane 1,2-Bis(dimethylphosphino)ethane 1,2-Bis(phenylphosphino)ethane 2,5-Norbornadiene diphenyl(2-phosphinoethyl)phosphine 1,2-Bis-(diphenylphosphino)propane 1,2-Bis(diphenylphosphino)ethane