N N-bis-[(R)-1-phenylethyl]dibenzo[d f][

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N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ Basic information
Product Name:N N-bis-[(R)-1-phenylethyl]dibenzo[d f][
Synonyms:BIPOL-A1(R), (R,R)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(R)-1-phenylethyl]phosphoramidite;N,N-bis[(1S)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;N,N-Bis[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosp hepin-6-amine,99%e.e.;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine,97%;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1R)-1-phenylethyl]-;N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N N-bis-[(R)-1-phenylethyl]dibenzo[d f][
CAS:500103-26-4
MF:C28H26NO2P
MW:439.49
EINECS:
Product Categories:Chiral Phosphine;CPN;phosphine-amine ligand
Mol File:500103-26-4.mol
N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ Structure
N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ Chemical Properties
Melting point 99-102 °C
Boiling point 578.4±53.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
pka-0.31±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
InChI1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
InChIKeyJISGHECLGYELKD-UHFFFAOYSA-N
SMILESC[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
Safety Information
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ Usage And Synthesis
UsesN,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
  • In the asymmetric hydrovinylation of 1,3-diene.
  • In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.

reaction suitabilityreaction type: click chemistry
N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ Preparation Products And Raw materials
Tag:N N-bis-[(R)-1-phenylethyl]dibenzo[d f][(500103-26-4) Related Product Information
N N-bis-[(R)-1-phenylethyl]dibenzo[d f][ (+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, (11bR) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethane adduct (R,R)-(+)-Bis(alpha-methylbenzyl)amine hydrochloride N N-bis-[(S)-1-phenylethyl]dibenzo[d f][ (+)-N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, (11bR)