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Diethyl sulfide

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Diethyl sulfide manufacturers

  • 1,1'-Thiobisethane
  • 1,1'-Thiobisethane pictures
  • $1.10
  • 2026-05-15
  • CAS:352-93-2
  • Min. Order: 1g
  • Purity: 99.0% Min
  • Supply Ability: 100 Tons
  • Diethyl sulfide
  • Diethyl sulfide pictures
  • $10.00
  • 2023-02-13
  • CAS:352-93-2
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 50MT
Diethyl sulfide Basic information
Product Name:Diethyl sulfide
Synonyms:sulfured’ethyle;Thioethyl ether;thioethylether;DIETHYL THIOETHER;DIETHYL SULPHIDE;DIETHYL SULFIDE;Diethyl suffide;ETHYL THIOETHER
CAS:352-93-2
MF:C4H10S
MW:90.19
EINECS:206-526-9
Product Categories:sulfide Flavor
Mol File:352-93-2.mol
Diethyl sulfide Structure
Diethyl sulfide Chemical Properties
Melting point −100 °C(lit.)
Boiling point 90-92 °C(lit.)
density 0.837 g/mL at 25 °C(lit.)
vapor pressure 105 mm Hg ( 37.7 °C)
refractive index n20/D 1.442(lit.)
FEMA 3825 | DIETHYL SULFIDE
Fp 15 °F
solubility H2O: insoluble
form liquid
Specific Gravity0.837
color Colorless to Almost colorless
Odorethereal sulfurous
Odor Typesulfurous
biological sourcesynthetic
Odor Threshold0.000033ppm
Water Solubility Miscible with alcohol, ethanol and ether. Slightly miscible with carbon tetrachloride. Immiscible with water.
Specific Heat CapacityCp(liquid): 1.9 J/(g·K); Cp(gas): 1.3 J/(g·K), at 25℃
JECFA Number454
Merck 14,3854
BRN 1696909
Henry's Law Constant3.5×10-3 mol/(m3Pa) at 25℃, Burkholder et al. (2019)
Dielectric constant7.2(20℃)
Stability:Stable. Highly flammable. Incompatible with strong oxidizing agents.
Major Applicationcleaning products
cosmetics
food and beverages
personal care
InChI1S/C4H10S/c1-3-5-4-2/h3-4H2,1-2H3
InChIKeyLJSQFQKUNVCTIA-UHFFFAOYSA-N
SMILESCCSCC
LogP1.95 at 20℃
CAS DataBase Reference352-93-2(CAS DataBase Reference)
NIST Chemistry ReferenceDiethyl sulfide(352-93-2)
EPA Substance Registry SystemDiethyl sulfide (352-93-2)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-38-36/38
Safety Statements 9-16-26-33-36
RIDADR UN 2375
WGK Germany 3
RTECS LC7200000
13
TSCA TSCA listed
HazardClass 3
PackingGroup II
HS Code 29309090
Storage Class3 - Flammable liquids
Hazard ClassificationsEye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
Hazardous Substances Data352-93-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Diethyl sulfide Usage And Synthesis
Chemical PropertiesDiethyl sulfide is a colourless to pale yellow liquid with an ether-like aroma. Its boiling point is 92°C. It is insoluble in water but soluble in ethanol and oils.
OccurrenceReported found in cabbage, sauerkraut, mustard, egg, chicken, beef, pork, beer (0.0002 to 0.0017 ppm), grape brandy (cognac, armagnac, weinbrand).
UsesSolvent for Anhydrous mineral salts; in plating baths for coating metals with gold or silver.
UsesDiethyl sulfide is used as a solvent for anhydrous mineral salts and in plating baths for coating metals with gold or silver. It is used as a flavoring agent. It is also used in the addition reaction with platinum dichloride to prepare platinum ethynyl dimers and polymers with pendant ferrocenyl group. Further, it is used in the preparation of triethylsulfoniuim ethylsulfate by reaction with sulfuric acid diethyl ester. In addition to this, it is used in the quantification procedure of volatile sulfur compounds by solid-phase microextraction.
UsesDiethyl sulfide may be used as an analytical standard for the determination of the analyte in wastewater, wines, and beer by gas chromatography (GC) based techniques.
DefinitionChEBI: Diethyl sulfide is an ethyl sulfide compound having two ethyl groups attached to a sulfur atom.
Synthesis Reference(s)Tetrahedron Letters, 14, p. 3853, 1973 DOI: 10.1016/S0040-4039(01)87056-8
General DescriptionA colorless oily liquid with a garlic-like odor. Less dense than water. Flash point 20°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals.
Air & Water ReactionsHighly flammable. Slightly soluble in water.
Reactivity ProfileOrganosulfides, such as 1,1'-Thiobisethane, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid.
Health HazardMay cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardHIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety ProfileMildly toxic by ingestion. A skin and eye irritant. A very dangerous fire hazard when exposed to heat, flame, or sparks; can react vigorously with oxidizers. Reacts with water, steam, acids, or acid fumes to produce toxic and flammable vapors. To fight fire, use water spray or mist, dry chemical, CO2, foam. When heated to decomposition it yields highly toxic fumes of SOx. See also SULFIDES.
Purification MethodsWash the sulfide with aqueous 5% NaOH, then water, dry with CaCl2 and distil it from sodium. It can also be dried with MgSO4 or silica gel. Alternative purification is via the Hg(II) chloride complex [(Et)2S.2HgCl2] (see dimethyl sulfide). [Beilstein 1 IV 1394.]
Diethyl sulfide Preparation Products And Raw materials
Raw materialsTriethyloxonium tetrafluoroborate-->ETHYL VINYL SULFIDE-->Diethyl sulfoxide-->2-Chloroethyl ethyl sulfide-->tert-Butyldimethylsilane-->Ethanethiol
Preparation ProductsIprobenfos-->U-47319
Tag:Diethyl sulfide(352-93-2) Related Product Information
ETOXAZOLE Ethanethiol DI-N-BUTYL SULFOXIDE S-Trityl-L-cysteine 3,6-Dithia-1,8-octanediol (BENZYLTHIO)ACETIC ACID Ethyl 2-hydroxyethyl sulfide 3,3'-Thiodipropionic acid Methylthioethane 2,2'-Thiodiacetic acid 2-Chloroethyl ethyl sulfide L-Ethionine D-Glucose diethyl mercaptal S-Carboxymethyl-L-cysteine 3,3'-Thiodipropanol Lanthionine 2,2'-Sulfonyldiethanol S-Ethyl trifluorothioacetate