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| | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Basic information |
| Product Name: | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide | | Synonyms: | DOP;10H-9-Oxa-10-phosphaphenanthrene 10-oxide;9H,10H-9-Oxa-10-phosphaphenanthrene-10-oxide;9-Oxa-10-phospha-9,10-dihydrophenanthrene 10-oxide;PD-3710;9,10-DIHYDRO-9-OXA-10-PHOSPAPHENANTHRENE-10-OXIDE(DOPO);9,10-Dihydro-9-oxa-10-phosphaphenanthrene;9,10-DIHYDRO-9-OXA-10-PHOSPAPHENANTHRENE- | | CAS: | 35948-25-5 | | MF: | C12H9O2P | | MW: | 216.17 | | EINECS: | 252-813-7 | | Product Categories: | Piperazines ,Oxazolines/Oxazolidines;flame retardant;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials;Industrial/Fine Chemicals | | Mol File: | 35948-25-5.mol |  |
| | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Chemical Properties |
| Melting point | 119°C | | Boiling point | 399.7±25.0 °C(Predicted) | | vapor pressure | 0.004Pa at 25℃ | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | Solid | | color | White to Off-White | | Water Solubility | 3.574g/L at 25℃ | | InChI | InChI=1S/C12H9O2P/c13-15-12-8-4-2-6-10(12)9-5-1-3-7-11(9)14-15/h1-8,15H | | InChIKey | VBQRUYIOTHNGOP-UHFFFAOYSA-N | | SMILES | O1C2=CC=CC=C2C2=CC=CC=C2P1=O | | LogP | 1.87 | | CAS DataBase Reference | 35948-25-5(CAS DataBase Reference) | | EPA Substance Registry System | 6H-Dibenz[c,e][1,2]oxaphosphorin, 6-oxide (35948-25-5) |
| | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Usage And Synthesis |
| Uses | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide is an high effective componant of flame retardant epoxy resins. | | Flammability and Explosibility | Non flammable | | Synthesis | General procedure for the synthesis of 9,10-dihydro-9-oxa-10-phosphaphenanthrene from 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene: 10 g of 6-chloro-6H-dibenzo[c,e][1,2]oxaphosphorine (0.0426 mol), 1.2 g of hydrochloric acid (0.0335 mol), and 2.1 g of water were added to a reactor and stirred for 5 minutes to form a homogeneous solution. The reaction mixture was heated at 80 °C for 1 h. Upon completion of the reaction, the system was divided into an organic layer and an aqueous layer. The temperature of the organic layer was maintained at 80 °C, and the organic layer was separated and transferred to another reactor. Reduced pressure distillation was carried out at 165 °C and 0.3 mbar to give 9.03 g of the white solid product 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide [Yield: 98%; Color: 8 Hazen; Purity: 99.25% (major component: minor component = 99.25%: 0.75%); Melting point: 122.13 °C (DSC peak)] . | | References | [1] Patent: US2011/34717, 2011, A1. Location in patent: Page/Page column 3
[2] Patent: US2007/173659, 2007, A1. Location in patent: Page/Page column 5
[3] J. Gen. Chem. USSR (Engl. Transl.), 1972, vol. 42, p. 88 - 90
[4] Zhurnal Obshchei Khimii, 1972, vol. 42, p. 93 - 96
[5] Heterocycles, 2011, vol. 83, # 4, p. 743 - 753 |
| | 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-oxide Preparation Products And Raw materials |
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