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Alfa Aesar |
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400-6106006 |
| Email: |
saleschina@alfa-asia.com |
| Company Name: |
Energy Chemical |
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400-0056266 |
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| | Phenoxyacetonitrile Basic information |
| | Phenoxyacetonitrile Chemical Properties |
| Boiling point | 235-238 °C(lit.) | | density | 1.09 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.524(lit.) | | Fp | >230 °F | | storage temp. | 2-8°C | | form | clear liquid | | color | Colorless to Almost colorless | | BRN | 2206192 | | InChI | 1S/C8H7NO/c9-6-7-10-8-4-2-1-3-5-8/h1-5H,7H2 | | InChIKey | VLLSCJFPVSQXDM-UHFFFAOYSA-N | | SMILES | N#CCOc1ccccc1 | | CAS DataBase Reference | 3598-14-9(CAS DataBase Reference) |
| Hazard Codes | Xn | | Risk Statements | 20/21/22 | | Safety Statements | 36 | | RIDADR | 3276 | | WGK Germany | 3 | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29269090 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
| | Phenoxyacetonitrile Usage And Synthesis |
| Chemical Properties | clear light yellow-brown liquid | | Uses | Phenoxyacetonitrile is a building block that has been used as a reactant for the preparation of [[(oxo)pyridazinyl]phenoxy]acetonitrile derivatives to be used as vasodilators. | | Uses | Phenoxyacetonitrile may be used in the synthesis of:
- 2,4-dihydroxyphenoxyacetophenones
- methylthio(phenoxy)acetonitrile
- 2,4-diamino-5-(3,4,5-trimethoxyphenoxy)pyrimidine
| | References | [1] M. HAMANA T. H Y Fujimura. Reactions of quinoline and 4-chloroquinoline 1-oxides with phenoxyacetonitrile, chloromethylphenylsulfone, and methyl-thiomethyl-p-tolylsulfone[J]. Heterocycles, 1987, 25 1: 229-233. DOI:10.3987/S-1987-01-0229.
[2] A. Jonczyk* Essa H M. A SIMPLE PROCEDURE FOR THE PREPARATION OF (METHYL- AND PHENYLTHIO)ARYLOXYACETONITRILES[J]. Organic Preparations and Procedures International, 1993, 25 1: 690-693. DOI:10.1080/00304949309356267.
[3] STOGRYN E L. Synthesis of trimethoprim variations. Replacement of methylene by polar groupings[J]. Journal of Medicinal Chemistry, 1972, 15 2: 200-201. DOI:10.1021/jm00272a019. |
| | Phenoxyacetonitrile Preparation Products And Raw materials |
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