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N-tert-Butylformamide

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N-tert-Butylformamide manufacturers

N-tert-Butylformamide Basic information
Product Name:N-tert-Butylformamide
Synonyms:N-tert-Butylformamide,97%;N-tert-butylmethanamide;N-tert-Butylformamide;n-(1,1-dimethyl)formamide(nlm);n-(1,1-dimethylethyl)-formamid;N-(1,1-dimethylethyl)formamide;n-(tert-butyl)-formamid;n-t-butylformamide
CAS:2425-74-3
MF:C5H11NO
MW:101.15
EINECS:219-369-6
Product Categories:Amides;Carbonyl Compounds;Organic Building Blocks
Mol File:2425-74-3.mol
N-tert-Butylformamide Structure
N-tert-Butylformamide Chemical Properties
Melting point 16 °C(lit.)
Boiling point 202 °C(lit.)
density 0.903 g/mL at 25 °C(lit.)
refractive index n20/D 1.433(lit.)
Fp 203 °F
pka16.47±0.23(Predicted)
form clear liquid
color Colorless to Light yellow
BRN 1738869
InChIInChI=1S/C5H11NO/c1-5(2,3)6-4-7/h4H,1-3H3,(H,6,7)
InChIKeySDLAKRCBYGZJRW-UHFFFAOYSA-N
SMILESC(NC(C)(C)C)=O
CAS DataBase Reference2425-74-3(CAS DataBase Reference)
EPA Substance Registry SystemFormamide, N-(1,1-dimethylethyl)- (2425-74-3)
Safety Information
Safety Statements 23-24/25
RIDADR NA1993
WGK Germany 3
RTECS LQ1450000
8
TSCA TSCA listed
HS Code 2924.19.1150
HazardClass CBL
Storage Class10 - Combustible liquids
Hazardous Substances Data2425-74-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
N-tert-Butylformamide Usage And Synthesis
UsesN-tert-Butylformamide was used to investigate the ability of low molecular weight amides to function as non-aqueous amphiphile self-assembly media.
General DescriptionN-tert-Butylformamide forms nanostructure due to segregation of the molecules into polar and non-polar domains, analogous to amphiphile self-assembly.
Safety ProfileA poison by intravenous route. When heated to decomposition it emits toxic fumes of NOx
Purification MethodsIf the IR indicates some hydrolysis, then dissolve it in Et2O, wash it with 20% aqueous Na2CO3, dry it (MgSO4), filter and fractionate it. Collect the fraction that solidifies on cooling and recrystallise it from Et2O at low temperature if necessary. [Emmons J Am Chem Soc 79 5753 1957, Beilstein 4 III 324, 4 IV 661.]
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