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Cyclohexyl methacrylate

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Cyclohexyl methacrylate Basic information
Product Name:Cyclohexyl methacrylate
Synonyms:2-methyl-2-propenoic acid cyclohexyl ester;CYCLOHEXYL METHACRYLATE;CYCLOHEXYL A-METHYLACRYLATE;2-methyl-2-propenoicacicyclohexylester;2-Propenoicacid,2-methyl-,cyclohexylester;Ageflex CHMA;Cyclohexyl 2-methylacrylate;Cyclohexyl methacrylate, monomer
CAS:101-43-9
MF:C10H16O2
MW:168.23
EINECS:202-943-5
Product Categories:
Mol File:101-43-9.mol
Cyclohexyl methacrylate Structure
Cyclohexyl methacrylate Chemical Properties
Boiling point 68-70 °C4 mm Hg(lit.)
density 0.964 g/mL at 25 °C(lit.)
vapor pressure 18.4Pa at 20℃
refractive index n20/D 1.458(lit.)
Fp 181 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless to slightly yellow
Odorester-like odor
Water Solubility negligible
BRN 2045235
Cosmetics Ingredients FunctionsNAIL SCULPTING
Cosmetic Ingredient Review (CIR)Cyclohexyl methacrylate (101-43-9)
InChI1S/C10H16O2/c1-8(2)10(11)12-9-6-4-3-5-7-9/h9H,1,3-7H2,2H3
InChIKeyOIWOHHBRDFKZNC-UHFFFAOYSA-N
SMILESCC(=C)C(=O)OC1CCCCC1
LogP3.9 at 23℃
CAS DataBase Reference101-43-9(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid, 2-methyl-, cyclohexyl ester(101-43-9)
EPA Substance Registry SystemCyclohexyl methacrylate (101-43-9)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-R36/37/38-43-36-22
Safety Statements 26-28-37/39-S37/39-S26-46-24/25-36/37
WGK Germany 1
TSCA TSCA listed
HS Code 29162090
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
Hazardous Substances Data101-43-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Methyl-2-propenoic acid cyclohexyl ester English
SigmaAldrich English
ACROS English
ALFA English
Cyclohexyl methacrylate Usage And Synthesis
Description Cyclohexyl Methacrylate (CHMA) is a very useful starting material for chemical synthesis since it easily undergoes addition reactions with a wide range of organic and inorganic compounds. The compound is an ester of Methacrylic acid and is used as a raw material component in synthesizing polymers. It is a monofunctional monomer consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group. Copolymers of CHMA can be prepared with (meth)acrylic acid and its salts, amides, and esters and with (meth)acrylates, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, unsaturated polyesters, and drying oils, etc.
Chemical Propertiesclear colorless to slightly yellow liquid
UsesCyclohexyl methacrylate (CHMA) is mainly used in coatings, plastics, textiles, leather, and paper industries as a solution polymerization, suspension polymerization monomer, or comonomer.
Flammability and ExplosibilityNon flammable
Purification MethodsPurify as for methyl methacrylate (p 164). [Tong & Kenyon J Am Chem Soc 68 1355 1946, Beilstein 6 III 25, 6 IV 39.]
Cyclohexyl methacrylate Preparation Products And Raw materials
Raw materialsMethyl methacrylate-->Cyclohexanol-->Methacrylic acid
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