2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt NEW

In short, it is a versatile and high-performance sulfonic acid-based monomer. It's most commonly known by its acronym NaAMPS (pronounced "na-amps"), which stands for Sodium AMPS. Its key feature is that it provides a very strong, permanent negative charge (anionic character) to the molecules and materials it's incorporated into.

Detailed Breakdown

1. What is it?

NaAMPS is the sodium salt of a synthetic monomer that contains two key functional groups:

• An acrylamide group, which allows it to readily polymerize (form long chains) with other monomers.

  A very strong sulfonic acid group (in its salt form), which is responsible for its exceptional properties.

Its chemical formula is C₇H₁₂NNaO₄S.

2. Breaking Down the Name

The long systematic name describes its molecular structure:

• 2-Acrylamido: An acrylamide group (-CH₂=CH-C(O)-NH-) is attached to the second carbon of the propane chain.

  2-methyl: There is a methyl group (-CH₃) on that same second carbon.

  1-propanesulfonic acid: A three-carbon (propane) backbone with a sulfonic acid group (-SO₃H) on the first carbon.

  Sodium salt: The acidic hydrogen on the sulfonic acid group has been replaced by a sodium ion (Na⁺), making it NaSO₃⁻. This makes the molecule water-soluble and stable to handle.

3. Key Properties and Characteristics

• Highly Ionic (Anionic): The sulfonate group (SO₃⁻) is permanently charged, meaning it won't lose its charge with changes in pH. This is a major advantage over carboxylic acid-based monomers (like acrylic acid), which can lose their charge in acidic conditions.

  Excellent Water Solubility: The ionic nature makes it very soluble in water.

  Hydrophilic (Water-Loving): It imparts hydrophilicity to polymers.

  Hydrolytically Stable: The acrylamido group is attached to a tertiary carbon, making it highly resistant to hydrolysis (breaking down in water), especially compared to other acrylamide-based monomers. This is due to the steric hindrance from the methyl groups.

  High Reactivity: The vinyl group (CH₂=CH-) is very reactive and allows it to easily copolymerize with a wide range of other monomers.

4. Primary Uses and Applications

NaAMPS is a workhorse monomer used to introduce permanent anionic charge and improve the performance of polymers in many industries:

• Water Treatment:

• Scale Inhibition: Prevents minerals like calcium carbonate and sulfate from precipitating out of water and forming scale on equipment.

  Dispersant: Keeps suspended particles like clay, silt, and iron oxides from agglomerating and depositing.

• Superabsorbent Polymers (SAPs):

• Used in diapers, hygiene products, and water-retaining soils for agriculture. Incorporating NaAMPS improves the absorption rate and capacity, especially under load (e.g., when a baby sits on a diaper).

• Oil and Gas Industry:

• Drilling Fluid Additive: Helps control the viscosity and fluid loss of drilling muds.

  Enhanced Oil Recovery (EOR): Thickening polymers used to push out more oil from reservoirs often use NaAMPS for its superior salt and temperature tolerance.

• Coatings and Paints:

• Used as a thickener and stabilizer in latex paints to control viscosity and prevent pigment settling.

  Acts as a dispersant for pigments.

• Textiles:

• Used in fabric sizing and as a thickener in printing pastes.

• Adhesives and Sealants:

• Improves water resistance and adhesion properties.

• Ion Exchange Membranes:

• Used to create membranes for fuel cells and water desalination due to its ionic character and stability.

5. Synthesis

It is produced in a two-step process:

1. The precursor, 2-acrylamido-2-methylpropanesulfonic acid (AMPS acid), is synthesized by reacting acrylonitrile, isobutylene, and sulfuric acid (or oleum).

2. The AMPS acid is then neutralized with sodium hydroxide (NaOH) to produce the stable, crystalline sodium salt, NaAMPS.

Summary

In essence, whenever an application requires a polymer that remains charged, highly water-absorbent, and stable in harsh (salty, hot, or acidic/alkaline) conditions, NaAMPS is a top-choice monomer.