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ChemicalBook >> CAS DataBase List >> Dichloroacetic acid methyl ester

Dichloroacetic acid methyl ester

Dichloroacetic acid methyl ester price.
  • $5 - $215
  • Product name: Dichloroacetic acid methyl ester
  • CAS: 116-54-1
  • MF: C3H4Cl2O2
  • MW: 142.97
  • EINECS:204-146-8
  • MDL Number:MFCD00000843
  • Synonyms:Methyl dichloroacetate solution;1,1-Dichloro-2-methoxy-2-oxoethane;Dichloroacetic acid methyl;Methyl dichloroacetate, synthesis grade;Methyl dichloroacetate,purum;TwoMethyl chloroacetate;dichloro-aceticacimethylester ;ethanoicacid,dichloro-,methylester
14 prices
Selected condition:
Brand
  • AK Scientific
  • Azepine
  • Matrix Scientific
  • Sigma-Aldrich
  • TCI Chemical
  • Thermo Scientific Chemicals
  • TRC
Package
  • 100mg
  • 500mg
  • 2.500g
  • 5G
  • 25g
  • 100g
  • 500g
  • 500ml
  • 100 mL
  • ManufacturerAK Scientific
  • Product numberJ53124
  • Product descriptionMethyl dichloroacetate
  • Packaging100g
  • Price$20
  • Updated2021-12-16
  • Buy
  • ManufacturerAzepine
  • Product numberAZ0001-0076
  • Product descriptionMethyl dichloroacetate 98
  • Packaging5G
  • Price$5
  • Updated2021-12-16
  • Buy
  • ManufacturerAzepine
  • Product numberAZ0001-0076
  • Product descriptionMethyl dichloroacetate 98
  • Packaging25g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging100mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging500mg
  • Price$87
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134240
  • Product descriptionMethyl2,2-dichloroacetate 95%+
  • Packaging2.500g
  • Price$215
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number35840
  • Product descriptionMethyl dichloroacetate ≥99%
  • Packaging500ml
  • Price$107
  • Updated2026-04-30
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number36547
  • Product descriptionMethyl dichloroacetate PESTANAL?, analytical standard
  • Packaging100mg
  • Price$30
  • Updated2022-05-15
  • Buy
  • ManufacturerTCI Chemical
  • Product numberD0309
  • Product descriptionMethyl Dichloroacetate >99.0%(GC)
  • Packaging500g
  • Price$57
  • Updated2026-04-30
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  • ManufacturerTCI Chemical
  • Product numberD0309
  • Product descriptionMethyl Dichloroacetate >99.0%(GC)
  • Packaging25g
  • Price$17
  • Updated2026-04-30
  • Buy
  • ManufacturerThermo Scientific Chemicals
  • Product number14862
  • Product descriptionMethyl dichloroacetate, 99% 99%
  • Packaging100 mL
  • Price$26.4
  • Updated2026-04-24
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  • ManufacturerThermo Scientific Chemicals
  • Product numberB24399
  • Product descriptionMethyl dichloroacetate, 99%
  • Packaging500g
  • Price$68.65
  • Updated2026-04-24
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  • ManufacturerThermo Scientific Chemicals
  • Product numberB24399
  • Product descriptionMethyl dichloroacetate, 99%
  • Packaging100g
  • Price$35.65
  • Updated2026-04-24
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  • ManufacturerTRC
  • Product numberD432005
  • Product descriptionDichloroaceticAcidMethylEster
  • Packaging5g
  • Price$85
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J53124 Methyl dichloroacetate 100g $20 2021-12-16 Buy
Azepine AZ0001-0076 Methyl dichloroacetate 98 5G $5 2021-12-16 Buy
Azepine AZ0001-0076 Methyl dichloroacetate 98 25g $15 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 100mg $53 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 500mg $87 2021-12-16 Buy
Matrix Scientific 134240 Methyl2,2-dichloroacetate 95%+ 2.500g $215 2021-12-16 Buy
Sigma-Aldrich 35840 Methyl dichloroacetate ≥99% 500ml $107 2026-04-30 Buy
Sigma-Aldrich 36547 Methyl dichloroacetate PESTANAL?, analytical standard 100mg $30 2022-05-15 Buy
TCI Chemical D0309 Methyl Dichloroacetate >99.0%(GC) 500g $57 2026-04-30 Buy
TCI Chemical D0309 Methyl Dichloroacetate >99.0%(GC) 25g $17 2026-04-30 Buy
Thermo Scientific Chemicals 14862 Methyl dichloroacetate, 99% 99% 100 mL $26.4 2026-04-24 Buy
Thermo Scientific Chemicals B24399 Methyl dichloroacetate, 99% 500g $68.65 2026-04-24 Buy
Thermo Scientific Chemicals B24399 Methyl dichloroacetate, 99% 100g $35.65 2026-04-24 Buy
TRC D432005 DichloroaceticAcidMethylEster 5g $85 2021-12-16 Buy

Properties

Melting point :-52 °C (lit.)
Boiling point :143 °C (lit.)
Density :1.381 g/mL at 25 °C (lit.)
refractive index :n20/D 1.442(lit.)
Flash point :176 °F
storage temp. :room temp
solubility :4g/l
form :Liquid
color :Clear colorless
PH :3.8 (4g/l, H2O, 20℃)
Water Solubility :Slightly soluble
BRN :1747542
InChI :1S/C3H4Cl2O2/c1-7-3(6)2(4)5/h2H,1H3
InChIKey :HKMLRUAPIDAGIE-UHFFFAOYSA-N
SMILES :COC(=O)C(Cl)Cl
CAS DataBase Reference :116-54-1(CAS DataBase Reference)
NIST Chemistry Reference :Acetic acid, dichloro-, methyl ester(116-54-1)
EPA Substance Registry System :Acetic acid, 2,2-dichloro-, methyl ester (116-54-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Methyl dichloroacetate may be used in the diastereoselctive synthesis of bicyclic chlorocyclopropane, as difunctional initiator during atom transfer radical polymerization of methyl or n-butyl acrylate, as reagent during CrCl2-induced olefination of aldehydes. It is a reactant involved in nucleophilic substitution reactions with nitro(pentafluorosulfanyl)benzenes, azide-alkyl halide cycloaddition and atom transfer radical addition, Chemical modification of STn antigen for enhancement of synthetic carbohydrate vaccines, three component reaction of arynes with cyclic ethers and active methines, catalytic radical haloalkylation for synthesis of neodysidenin and addition reactions for syntehsis of enantiopure 3,4-diamino esters or amides.

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