1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE synthesis
- Product Name:1-CHLORO-4-(1,2-DIBROMOETHYL)BENZENE
- CAS Number:23135-16-2
- Molecular formula:C8H7Br2Cl
- Molecular Weight:298.4
1073-67-2
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23135-16-2
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Yield:23135-16-2 100%
Reaction Conditions:
with bromine in chloroform at 0;Inert atmosphere;
Steps:
General Procedure C: Synthesis of Dibromides
General procedure: To an oven dried 10 mL round-bottomed flask charged with 4-methylstyrene (224.5 mg, 1.9mmol, 1 equiv) and CHCl3 (1 mL, 1.9 M) was added bromine (110 μL, 2.15 mmol, 1.15equiv) dropwise under N2 at 0 °C. The reaction was allowed to reach room temperaturebefore being diluted with CH2Cl2 (5 mL) and washed with saturated aqueous sodium bisulfitesolution (10 mL). The organics were passed through a hydrophobic frit and concentrated toafford (1,2-dibromoethyl)toluene as an off white solid (528.2 mg, quant.).
References:
Wilson, Kirsty L.;Murray, Jane;Jamieson, Craig;Watson, Allan J. B. [Synlett,2018,vol. 29,# 5,art. no. ST-2017-D0751-L,p. 650 - 654] Location in patent:supporting information
622-98-0
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23135-16-2
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1073-67-2
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$7.00/5g
6314-52-9
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23135-16-2
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536-38-9
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104-88-1
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23135-16-2
25 suppliers
$60.80/10g