Welcome to chemicalbook!
Chinese English Japanese Germany Korea
010-86108875
logo
Inquriy
Try our best to find the right business for you.
Messages
Do not miss inquiry messages Please log in to view all inquiry messages.
My chemicalbook

Welcome back!

Structured search
18162-48-6872-50-4Methylene ChloridenaphthaleneTHFTitanium Dioxide
ChemicalBook CAS DataBase List 2-Allylphenol
1745-81-9

2-Allylphenol synthesis

12synthesis methods
Commercial production of 2 allylphenol is essentially the manufacture of a simple substituted phenol rather than a multi step pesticide synthesis. Industrial routes typically begin with ortho cresol or phenol derivatives, which undergo Friedel–Crafts type alkylation or transition metal catalysed allylation to introduce the allyl side chain at the ortho position. Catalysts such as Lewis acids or palladium complexes are used to control regioselectivity and suppress rearrangement to propenylphenols. The crude product is then purified by fractional distillation to remove unreacted phenol
(2-Allylphenoxy)trimethylsilan

18042-43-8
28 suppliers
$43.20/5g

2-Allylphenol

1745-81-9
305 suppliers
$14.00/5g

-

Yield:1745-81-9 98%

Reaction Conditions:

with methanol;1,3-disulfonic acid imidazolium hydrogen sulfate at 20; for 0.0666667 h;Green chemistry;

Steps:

General procedure for the deprotection of trimethylsilyl ethers
General procedure: A mixture of the substrate (1 mmol), ionic liquid [Dsim]HSO4 (6.5 mg, ∼0.02 mmol) in methanol (2 mL) was stirred at room temperature. After completion of the reaction (monitored by TLC), solvent was evaporated, water (1 mL) was added to the mixture, and stirred vigorously. Decantation of the mixture gave almost pure product(s). The products were characterized by comparison of their IR and NMR data. The ionic liquid was dried at 65 ◦C under vacuum to remove moisture, and then reused.

References:

Shirini, Farhad;Khaligh, Nader Ghaffari;Akbari-Dadamahaleh, Somayeh [Journal of Molecular Catalysis A: Chemical,2012,vol. 365,p. 15 - 23]

FullText

3383-05-9 Synthesis
2-ALLYL PHENYL ALLYL ETHER

3383-05-9
2 suppliers
inquiry

2-Allylphenol

1745-81-9
305 suppliers
$14.00/5g

References
Allyl phenyl ether

1746-13-0
250 suppliers
$9.00/5g

2-Allylphenol

1745-81-9
305 suppliers
$14.00/5g

References
1-allyl-2-(benzyloxy)benzene

51496-94-7
7 suppliers
inquiry

2-Allylphenol

1745-81-9
305 suppliers
$14.00/5g

References
59152-49-7 Synthesis
2,3-Dihydro-2-(iodoMethyl)benzofuran

59152-49-7
14 suppliers
$165.00/100mg

2-Allylphenol

1745-81-9
305 suppliers
$14.00/5g

References

2-Allylphenol Related Search:

Allyl bromide Sodium allylsulfonate Phenol Red 3-Aminophenol Phenol Diallylamine 5,8-Dihydroxy-1,4-naphthoquinone Quercetin 5-Hydroxy-1,4-naphthalenedione PLUMBAGIN