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ChemicalBook CAS DataBase List 4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine
846563-66-4

4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine synthesis

1synthesis methods
5736-94-7 Synthesis
4-N-HEXYLOXYBENZALDEHYDE

5736-94-7
119 suppliers
$42.20/5g

176220-38-5 Synthesis
4,4'-Bis(diethylmethylphosphonate)-2,2'-bipyridine

176220-38-5
85 suppliers
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4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine

846563-66-4
21 suppliers
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Yield:846563-66-4 85%

Reaction Conditions:

with potassium tert-butylate in N,N-dimethyl-formamide at 25;Inert atmosphere;Horner-Wadsworth-Emmons reaction;

References:

Klein, Cédric;Baranoff, Etienne;Nazeeruddin, Md. Khaja;Gr?tzel, Michael [Tetrahedron Letters,2010,vol. 51,# 47,p. 6161 - 6165] Location in patent:experimental part

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