ChemicalBook--->CAS DataBase List--->132-32-1

132-32-1

132-32-1 Structure

132-32-1 Structure
IdentificationMore
[Name]

3-Amino-9-ethylcarbazole
[CAS]

132-32-1
[Synonyms]

2-AMINO-9-ETHYL CARBAZOLE
3AC
3-AMINO-9-ETHYLCARBAZOLE
3-AMINO-N-ETHYLCARBAZOLE
9-ETHYL-9H-CARBAZOL-3-YLAMINE
9-ETHYLCARBAZOL-3-AMINE
AEC
AEC BUFFER
AEC SINGLE SOLUTION (RED)
AEC SUBSTRATE BUFFER
AKOS BBS-00003629
TIMTEC-BB SBB000498
3-amino-9-ethyl-carbazol
3-amino-n-ethylcarbazol
9-ethyl-9h-carbazol-3-amin
9-Ethyl-9H-carbazol-3-amine
Carbazole, 3-amino-9-ethyl-
3-Amino-9-ethylcarbazole (AEC)
3-Amino-9-ethyl carbazole, Technical Grade AEC, Technical Grade
9-ethylcarbazol-3-ylamine
[EINECS(EC#)]

205-057-7
[Molecular Formula]

C14H14N2
[MDL Number]

MFCD00004964
[Molecular Weight]

210.27
[MOL File]

132-32-1.mol
Chemical PropertiesBack Directory
[Definition]

A hydrochloride salt and free amine solid compound.
[Appearance]

3-Amino-9-ethylcarbazole is a brown or tan, crystalline compound.
[Melting point ]

85-88 °C(lit.)
[Boiling point ]

355C
[density ]

1,15g/cm
[refractive index ]

1.6180 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

tablet
[pka]

4.99±0.30(Predicted)
[color ]

Brown to Very Dark Brown
[BRN ]

174969
[InChI]

InChI=1S/C14H14N2/c1-2-16-13-6-4-3-5-11(13)12-9-10(15)7-8-14(12)16/h3-9H,2,15H2,1H3
[InChIKey]

OXEUETBFKVCRNP-UHFFFAOYSA-N
[SMILES]

N1(CC)C2=C(C=CC=C2)C2=C1C=CC(N)=C2
[CAS DataBase Reference]

132-32-1(CAS DataBase Reference)
[NIST Chemistry Reference]

9H-carbazol-3-amine, 9-ethyl-(132-32-1)
[EPA Substance Registry System]

132-32-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)
GHS08
[Signal word ]

Danger
[Hazard statements ]

H350
[Precautionary statements ]

P201-P202-P280-P308+P313-P405-P501
[Hazard Codes ]

T
[Risk Statements ]

R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

FE3590000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29339900
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Carc. 1B
[Safety Profile]

Suspected carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NOx,.
[Hazardous Substances Data]

132-32-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Hydrochloric acid-->Methanol-->Acetic acid-->N,N-Dimethylformamide-->Nitric acid-->Ammonium hydroxide-->Iron-->Diethyl oxalate-->Sodium sulfide-->Potassium tert-butoxide-->Carbazole-->9-Ethyl-3-nitrocarbazole-->Imidazole-2-carboxaldehyde
[Preparation Products]

Permanent Violet RL-->REMASTRAL BLUE FFRL-->N4-(9-Ethyl-9H-carbazol-3-yl)-N2-(3-Morpholin-4-yl-propyl)-pyriMidine-2,4-diaMine-->DIRECT BLUE 108-->9H-Carbazole, 9-ethyl-3-iodo-
Hazard InformationBack Directory
[General Description]

Tan powder.
[Reactivity Profile]

3-AMINO-9-ETHYLCARBAZOLE(132-32-1) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
[Air & Water Reactions]

Insoluble in water.
[Hazard]

Questionable carcinogen; poison.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes.
[Potential Exposure]

Plant workers engaged in the manufacture of this compound and its use in pigment manufacture. Laboratory workers using this material in colorimetric enzyme assays and as a biological stain
[Fire Hazard]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy. Personal Protective Methods: Wear-protective eye protection, gloves, and clothing to prevent any reasonable probability of skin or eye contact. Safety equipment suppliers/ manufacturers can provide recommendations on the most protective glove/clothing material for your operation. All protective clothing (suits, gloves, footwear, headgear) should be clean, available each day, and put on before work. Contact lenses should not be worn when working with this chemical. Wear dust-proof chemical goggles and face shield unless full facepiece respiratory protection is worn. Employees should wash immediately with soap when skin is wet or contaminated. Provide emergency showers and eyewash.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

3-Amino-9-ethylcarbazole neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
[Chemical Properties]

3-Amino-9-ethylcarbazole is a brown or tan, crystalline compound.
[Chemical Properties]

brown fine crystalline powder and chunks
[Waste Disposal]

Incinerator equipped with a scrubber or thermal unit to reduce nitrogen oxides emissions.
[Uses]

3-Amino-9-ethylcarbazole (AEC) has been used as a chromogen in immunohistochemistry to visualize the cells. It has also been used as a substrate in enzyme-linked immune absorbent spot (ELISpot).
[Preparation]

Prepared by reducing 3-nitro-N-ethylcarbazole with sodium sulfide.
[storage]

Store at -20°C
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

9-Ethylcarbazol-3-amine(132-32-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3-Amino-9-ethylcarbazole(132-32-1)MS
3-Amino-9-ethylcarbazole(132-32-1)1HNMR
3-Amino-9-ethylcarbazole(132-32-1)13CNMR
3-Amino-9-ethylcarbazole(132-32-1)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Amino-9-ethylcarbazole, tech., 90%(132-32-1)
[Alfa Aesar]

3-Amino-9-ethylcarbazole, 95%(132-32-1)
[Sigma Aldrich]

132-32-1(sigmaaldrich)
[TCI AMERICA]

3-Amino-N-ethylcarbazole,>90.0%(LC)(T)(132-32-1)
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