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1445085-82-4

1445085-82-4 Structure

1445085-82-4 Structure
IdentificationBack Directory
[Name]

SPhos Pd G3
[CAS]

1445085-82-4
[Synonyms]

SPhos Pd G3 97%
(2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl) [2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate
[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)phosphine](methanesulfonato)palladium
Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)dichloromethane adduct
Methanesulfonato(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct, Min. 98%
Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct OMS-SPhos
Methanesulfonato(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct, Min. 98% [SPhos Palladacycle]
[Molecular Formula]

C39H48NO5PPdS
[MDL Number]

MFCD28411651
[MOL File]

1445085-82-4.mol
[Molecular Weight]

866.201
Chemical PropertiesBack Directory
[Melting point ]

197-214°C
[storage temp. ]

2-8°C
[form ]

solid
[color ]

pale yellow
[InChIKey]

RSFANHZWYCDNBZ-UHFFFAOYSA-N
[SMILES]

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.COc3cccc(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6
[CAS DataBase Reference]

1445085-82-4
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Description]

SPhos Pd G3 is a common palladium catalyst ligand. As a third-generation composite palladium catalyst, SPhos Pd G3 is often used to catalyze Susuka-Miyaura, Buchwald-Hartwig, and other cross-coupling reactions. This product is used for organic synthesis, pharmaceutical research and development, and other scientific purposes.
[Chemical Properties]

Palladium(II) methanesulfonate (2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenylyl)(2'-amino-1,1'-biphenyl-3-yl)is a yellowish-white solid at ambient temperature and pressure, and it is poorly soluble in water, but it is soluble in common organic solvents, especially in strong polar organic solvents. It is a stable palladium precatalyst linked to phosphine and is often used as a catalyst in coupling reactions.
[Uses]

SPhos Pd G3 is stable phosphine-ligated palladium precatalyst that can be used in the catalysis of C-C and C-N bond formation reactions.
[Application]

SPhos Pd G3 is stable phosphine-ligated palladium precatalyst that can be used in the catalysis of C-C and C-N bond formation reactions.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Questions And AnswerBack Directory
[Reactions]

Palladium precatalyst for the arylation of amines. Reactions of 1445085-82-4
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