| Identification | More | [Name]
Tetrabutylammonium hydrogen sulfate | [CAS]
32503-27-8 | [Synonyms]
IPC-TBA-HS
TBAHS
TETRABUTYLAMMONIUM BISULFATE
TETRABUTYLAMMONIUM HYDROGEN SULFATE
TETRABUTYLAMMONIUM HYDROGEN SULPHATE
TETRA-N-BUTYLAMMONIUM HYDROGENSULFATE
TETRA-N-BUTYLAMMONIUM HYDROGEN SULPHATE
1-Butanaminium, N,N,N-tributyl-, sulfate (1:1)
1-Butanaminium,N,N,N-tributyl-,sulfate(1:1)
n,n,n-tributyl-1-butanaminiusulfate(1:1)
TETRABUTYLAMM.HYDROGENSULPHATE
TETRABUTYLAMMONIUM HYDROGEN SULFATE 98+%
Tetrabutylammonium bisulfate solution
TETRABUTYLAMMONIUM HYDROGENSULFATE 97%
Tetrabutylammonium bisulfate, Concentrate
TetrabutylAmmoniumHydrogenSulfateForSynthesis
TetrabutylAmmoniumHydrogenSulfateForHplc
Tetra-n-butylammoniumhydrogensulfate,98%
tetrabutylammonium hydrogen sulfate solution
Tetrabutylammonium hydrogen sulphate 97% | [EINECS(EC#)]
251-068-5 | [Molecular Formula]
C16H37NO4S | [MDL Number]
MFCD00011637 | [Molecular Weight]
339.53 | [MOL File]
32503-27-8.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
171-174 °C
| [Boiling point ]
213.3-593.92℃[at 101 325 Pa] | [bulk density]
650kg/m3 | [density ]
1.01 | [vapor pressure ]
0Pa at 25℃ | [storage temp. ]
Store below +30°C. | [solubility ]
H2O: soluble10% (w/v), clear, colorless | [form ]
Solution | [color ]
White to beige | [Specific Gravity]
1.01 | [Odor]
Amine like | [PH]
1-2 (100g/l, H2O, 20℃) | [PH Range]
1 - 2 | [Stability:]
Stable, but moisture sensitive. Incompatible with strong oxidizing agents. | [Water Solubility ]
Soluble | [Sensitive ]
Hygroscopic | [λmax]
λ: 210 nm Amax: 0.06
λ: 220 nm Amax: 0.05
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02 | [Detection Methods]
NMR,TITR | [BRN ]
3599663 | [InChI]
1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1 | [InChIKey]
SHFJWMWCIHQNCP-UHFFFAOYSA-M | [SMILES]
OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC | [LogP]
0.96 at 25℃ | [CAS DataBase Reference]
32503-27-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Tetrabutylammonium hydrogen sulfate(32503-27-8) | [Storage Precautions]
Moisture sensitive | [EPA Substance Registry System]
Tetrabutylammonium sulfate (1:1) (32503-27-8) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H302-H314-H412 | [Precautionary statements ]
P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338 | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
8-10 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29239000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
Skin Corr. 1 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
A compound that displays antibacterial properties | [Uses]
Displays antibacterial properties due to the presence of the quaternary amine and the counter ion. | [Preparation]
Tetrabutylammonium hydrogen sulfate can be prepared from tetrabutylammonium azide by treating it with potassium hydrogen sulfate and 10% aqueous sulfuric acid in aqueous medium or from tetrabutylammonium thiocyanate by treating it with relatively concentrated sulfuric acid (70%) at 75 °C.
 | [General Description]
Tetrabutylammonium bisulfate, a quaternary ammonium salt, is a phase-transfer reagent. | [Purification Methods]
The sulfate crystallises from acetone. It has been used as a phase transfer catalyst. | [References]
[1] H. N. KARADE M. P K M Sathe. An efficient synthesis of 1, 8-dioxo-octahydroxanthenes using tetrabutylammonium hydrogen sulfate[J]. Arkivoc, 2007, 2007 1. DOI:10.3998/ARK.5550190.0008.D28.
[2] A. J. PARDEY. New media in homogeneous catalysis: wet sodium or tetrabutylammonium hydrogensulfate salts for reppe syntheses catalyzed by a ru(ii) carbonyl complex[J]. Journal of Coordination Chemistry, 2004, 57 1: 871-882. DOI:10.1080/00928970410001721998.
[3] A. J. PARDEY. Hydrocarboxylation and stepwise alternating oligomerization of carbon monoxide and ethylene catalyzed by cis-[Rh(CO)2(amine)2](PF6) complexes in a wet liquid tetrabutylammonium hydrogensulfate[J]. Polyhedron, 2004, 23 1: 1677-1683. DOI:10.1016/J.POLY.2004.03.023.
[4] NEETU TEWARI Rama P T Namrata Dwivedi. Tetrabutylammonium hydrogen sulfate catalyzed eco-friendly and efficient synthesis of glycosyl 1,4-dihydropyridines[J]. Tetrahedron Letters, 2004, 45 49: Pages 9011-9014. DOI:10.1016/j.tetlet.2004.10.057. |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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