| Identification | More | [Name]
Tetrabutylammonium tetrafluoroborate | [CAS]
429-42-5 | [Synonyms]
TETRABUTYLAMMONIUM FLUOROBORATE
TETRABUTYLAMMONIUM TETRAFLUOROBORATE
TETRA-N-BUTYLAMMONIUM FLUOROBORATE
TETRA-N-BUTYLAMMONIUM TETRAFLUOROBORATE
1-Butanaminium, N,N,N-tributyl-, tetrafluoroborate(1-)
1-Butanaminium,N,N,N-tributyl-,tetrafluoroborate(1-)
n,n,n-tributyl-1-butanaminiutetrafluoroborate(1-)
TETRABUTYLAMMONIUM TETRAFLUOROBORATE, EL ECTROCHEM. GRADE
TETRABUTYLAMMONIUM TETRAFLUOROBORATE, 99 %
Tetrabutylammonium tetrafluoroborate 99%
n,n,n-tributyl-1-butanaminiu tetrafluoroborate
tetrabutylammonium tetrafluoborate
Tetrabutylazanium tetrafluoroborate
Tetrabutylammonium tetrafluoroborate ,98% | [EINECS(EC#)]
207-058-8 | [Molecular Formula]
C16H36BF4N | [MDL Number]
MFCD00011634 | [Molecular Weight]
329.27 | [MOL File]
429-42-5.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE FINE CRYSTALLINE POWDER | [Melting point ]
155-161 °C(lit.)
| [Fp ]
>93℃ | [storage temp. ]
−20°C | [solubility ]
methanol: 0.1 g/mL, clear, colorless
| [form ]
Crystalline Powder | [color ]
White | [Water Solubility ]
Slightly soluble | [Sensitive ]
Hygroscopic | [Detection Methods]
HPLC,NMR | [BRN ]
3577508 | [InChI]
InChI=1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1 | [InChIKey]
DWWRDPSMLREDKW-UHFFFAOYSA-M | [SMILES]
[N+](CCCC)(CCCC)(CCCC)CCCC.[B-](F)(F)(F)F | [CAS DataBase Reference]
429-42-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Tetrabutylammonium tetrafluoroborate(429-42-5) | [EPA Substance Registry System]
429-42-5(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H302-H315-H318-H335 | [Precautionary statements ]
P261-P280-P305+P351+P338 | [Hazard Codes ]
Xi,T | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 1759 8/PG III | [WGK Germany ]
3
| [Hazard Note ]
Irritant/Hygroscopic | [TSCA ]
Yes | [HazardClass ]
TOXIC, HYGROSCOPIC | [PackingGroup ]
III | [HS Code ]
29239000 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE FINE CRYSTALLINE POWDER | [Uses]
TBATFB has been used as an electrolyte to understand the paraffin graphite powder modified with sweet potato tissue (PCPET) electrode response. | [Uses]
Tetrabutylammonium tetrafluoroborate may be used in the following studies:
- As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
- Synthesis of biologically relevant macrolactones, Sansalvamide A.
- As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
- Preparation of 1:1 adduct with 1,10-phenanthroline.
- Used to prepare other tetrabutylammonium salts in aqueous solutions.
- As electrolyte additive in the synthesis of conducting poly(thiophenes).
| [General Description]
Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold. | [Purification Methods]
Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.] |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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