1,1'-Bis(diisopropylphosphino)ferrocene
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- CAS-Nr.
- 97239-80-0
- Englisch Name:
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Synonyma:
- DIPPF;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%
- CBNumber:
- CB8105732
- Summenformel:
- C22H36FeP210*
- Molgewicht:
- 418.31
- MOL-Datei:
- 97239-80-0.mol
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1,1'-Bis(diisopropylphosphino)ferrocene Eigenschaften
- Schmelzpunkt:
- 50-52 °C(lit.)
- Flammpunkt:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Aggregatzustand
- Powder
- Farbe
- orange-yellow
- Wasserlöslichkeit
- Insoluble in water.
- InChI
- InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
- InChIKey
- LPBBEMRSRONKMN-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
- CAS Datenbank
- 97239-80-0(CAS DataBase Reference)
1,1'-Bis(diisopropylphosphino)ferrocene Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Beschreibung
1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.
Chemische Eigenschaften
orange crystalline powder
Verwenden
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
1,1'-Bis(diisopropylphosphino)ferrocene Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1,1'-Bis(diisopropylphosphino)ferrocene Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 185)Lieferanten
97239-80-0()Verwandte Suche:
- BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON
- 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- -BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%
- 1,1'-Bis(diisopropylphosphino)ferrocene,98%
- 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%
- 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene
- Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-
- 1,1'-Bis(di-i-propylphosphino)ferrocene,98%
- cyclopentyl(diisopropyl)phosphane
- 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF
- 1,1'-Bis(di-i-propylphosphino)f
- 1,1'-Bis(diisopropylphosphino)ferrocene>
- 1,1'-Bis(diisopropyL
- 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001：2015 REACH
- bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron
- 1,1'-bis-(di-Isopropylphosphino)ferrocene
- 1,1′-Bis(diisopropylphosphino)ferrocene, CAS 97239-80-0
- 1,1'-Bis(di-i-propylphosphino)ferrocene
- DIPPF
- 97239-80-0
- 97239-80-8
- C22H36FeP210
- C22H36FeP2
- 2C11H18PFe
- Phosphine Ligands
- Ferrocenes
- Metallocenes
- Polydentate Phosphine Ligands
- Phosphorus Compounds
- Catalysis and Inorganic Chemistry
- Achiral Phosphine
- Aryl Phosphine
- Ligand
- Ferrocenes
- Metallocenes
- Phosphine Ligands
- Synthetic Organic Chemistry
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Polydentate Phosphine Ligands
