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1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene Structure
1,1'-Bis(diisopropylphosphino)ferrocene structure
CAS No.
97239-80-0
Chemical Name:
1,1'-Bis(diisopropylphosphino)ferrocene
Synonyms
DIPPF;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%
CBNumber:
CB8105732
Molecular Formula:
C22H36FeP210*
Molecular Weight:
418.31
MDL Number:
MFCD02684559
MOL File:
97239-80-0.mol
MSDS File:
SDS
Last updated:2026-07-16 07:06:08
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1,1'-Bis(diisopropylphosphino)ferrocene Properties

Melting point 50-52 °C(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange-yellow
Water Solubility Insoluble in water.
InChI InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference 97239-80-0(CAS DataBase Reference)
UNSPSC Code 12350000
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501A
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26
WGK Germany  3
TSCA  No
HS Code  29319090
NFPA 704
0
2 0

1,1'-Bis(diisopropylphosphino)ferrocene price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 578266 1,1′-Bis(diisopropylphosphino)ferrocene 97% 97239-80-0 500mg $209 2026-04-30 Buy
TCI Chemical B2710 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) 97239-80-0 1g $144 2026-04-30 Buy
TCI Chemical B2710 1,1'-Bis(diisopropylphosphino)ferrocene >98.0%(T) 97239-80-0 100mg $38 2026-04-30 Buy
Strem Chemicals 26-0275 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% 97239-80-0 500mg $62 2026-04-30 Buy
Strem Chemicals 26-0275 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF min.98% 97239-80-0 2g $181 2026-04-30 Buy
Product number Packaging Price Buy
578266 500mg $209 Buy
B2710 1g $144 Buy
B2710 100mg $38 Buy
26-0275 500mg $62 Buy
26-0275 2g $181 Buy

1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties, Uses, Production

Reaction

  1. Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
  2. Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
  3. Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
  4. Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
  5. Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
  6. Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
  7. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Reactions of 97239-80-0_1
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Reactions of 97239-80-0_6Reactions of 97239-80-0_7

Description

1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.

Chemical Properties

orange crystalline powder

Uses

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Ferrocene Hexane N,N,N',N'-Tetramethylethylenediamine Chlorodiisopropylphosphine n-Butyllithium

Preparation Products

1,1'-Bis(diisopropylphosphino)ferrocene Suppliers

Global Suppliers ( 185)
Supplier Tel Email Country ProdList Advantage
Shaanxi Rock New Materials Co., Ltd. 0917-8888777 18691786767 liuwei@bjrock.com China 309 62
Henan Research New Material Co., Ltd. 86-18903931531 18903931628 sales036@researchvip.com China 180 58
BeiJing Greenchem Technology Co.,Ltd. 131-21959385 18804271668 chemrocking@bjgreenchem.com China 272 58
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Supplier Advantage
Shaanxi Rock New Materials Co., Ltd. 62
Henan Research New Material Co., Ltd. 58
BeiJing Greenchem Technology Co.,Ltd. 58
Xinxiang Runyu Material Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 59
INTATRADE GmbH 66
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81

View Latest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,1'-Bis(diisopropylphosphino)ferrocene pictures 2026-09-18 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,1'-bis-(di-Isopropylphosphino)ferrocene pictures 2026-08-25 1,1'-bis-(di-Isopropylphosphino)ferrocene
97239-80-0
 $2.00-6.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
1,1'-Bis(diisopropylphosphino)ferrocene pictures 2026-07-16 1,1'-Bis(diisopropylphosphino)ferrocene
97239-80-0
 1kg 98% 1000kg Shaanxi Dideu New Materials Co. Ltd

1,1'-Bis(diisopropylphosphino)ferrocene Spectrum

1,1'-Bis(diisopropylphosphino)ferrocene(97239-80-0)1HNMR1,1'-Bis(diisopropylphosphino)ferrocene(97239-80-0)31PNMR1,1'-Bis(diisopropylphosphino)ferrocene(97239-80-0)IR

97239-80-0 (1,1'-Bis(diisopropylphosphino)ferrocene) Related Search:

1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis(diphenylphosphino)ferrocene 1,1'-Bis(dicyclohexylphosphino)ferrocene 1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene 1,1'-Bis(di-I-propylphosphino)ferrocene(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate
Ferrocene 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1-Bis[(2S,3S,4S,5S)-2,5-dimethyl-3,4-O-isopropylidene-3,4-dihydroxyphospholanyl]ferrocene (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(dicyclohexylphosphino)ferrocene
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S,S-Me-FerrocelaneTM 1,1μ-Bis[(2R,5R)-2,5-diisopropylphospholano]ferrocene

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BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE -BIS(DIISOPROPYLPHOSPHINO)FERROCENE 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% 1,1'-Bis(diisopropylphosphino)ferrocene,98% 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98% 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]- 1,1'-Bis(di-i-propylphosphino)ferrocene,98% cyclopentyl(diisopropyl)phosphane 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF 1,1'-Bis(di-i-propylphosphino)f 1,1'-Bis(diisopropylphosphino)ferrocene> 1,1'-Bis(diisopropyL 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001：2015 REACH bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron 1,1'-bis-(di-Isopropylphosphino)ferrocene 1,1′-Bis(diisopropylphosphino)ferrocene, CAS 97239-80-0 1,1'-Bis(di-i-propylphosphino)ferrocene DIPPF 97239-80-0 97239-80-8 C22H36FeP210 C22H36FeP2 2C11H18PFe Phosphine Ligands Ferrocenes Metallocenes Polydentate Phosphine Ligands Phosphorus Compounds Catalysis and Inorganic Chemistry Achiral Phosphine Aryl Phosphine Ligand Ferrocenes Metallocenes Phosphine Ligands Synthetic Organic Chemistry Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands