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Methyl 3-amino-5-bromobenzoate

Methyl 3-amino-5-bromobenzoate structure

CAS No.: 706791-83-5

Chemical Name:: Methyl 3-amino-5-bromobenzoate

Synonyms: 3-AMINO-5-BROMOBENZOATE;Methyl 3-Amino-5-bromobenzoate;METHYL-3-BROMO-5-AMINO BENZOATE;Benzoic acid, 3-amino-5-bromo-, methyl ester

CBNumber:: CB01471014

Molecular Formula:: C8H8BrNO2

Molecular Weight:: 230.06

MDL Number:: MFCD07786958

MOL File:: 706791-83-5.mol

MSDS File:: SDS

Last updated:2026-05-27 17:18:38

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Methyl 3-amino-5-bromobenzoate Properties

Melting point	83-88℃
Boiling point	332.3±22.0 °C(Predicted)
Density	1.578±0.06 g/cm3(Predicted)
storage temp.	2-8°C(protect from light)
pka	2.38±0.10(Predicted)
Appearance	Yellow to brown Solid
InChI	InChI=1S/C8H8BrNO2/c1-12-8(11)5-2-6(9)4-7(10)3-5/h2-4H,10H2,1H3
InChIKey	MNXLJDUZJCMJCI-UHFFFAOYSA-N
SMILES	C1(C=C(Br)C=C(N)C=1)C(=O)OC

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338

Methyl 3-amino-5-bromobenzoate price More Price(36)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Activate Scientific	AS40790	Methyl 3-amino-5-bromobenzoate 98%	706791-83-5	1g	$23	2026-06-04	Buy
Activate Scientific	AS40790	Methyl 3-amino-5-bromobenzoate 98%	706791-83-5	5g	$39	2026-06-04	Buy
Activate Scientific	AS40790	Methyl 3-amino-5-bromobenzoate 98%	706791-83-5	25g	$129	2026-06-04	Buy
Activate Scientific	AS40790	Methyl 3-amino-5-bromobenzoate 98%	706791-83-5	100g	$370	2026-06-04	Buy
Matrix Scientific	065397	Methyl 3-amino-5-bromobenzoate	706791-83-5	10.00g	$24	2026-05-18	Buy

Product number	Packaging	Price	Buy
AS40790	1g	$23	Buy
AS40790	5g	$39	Buy
AS40790	25g	$129	Buy
AS40790	100g	$370	Buy
065397	10.00g	$24	Buy

Methyl 3-amino-5-bromobenzoate Chemical Properties, Uses, Production

Synthesis

3-Bromo-5-aminobenzoic acid (1.0 g, 4.62 mmol) was stirred in methanol (15mL) with ice cooling, and the yellow solution was treated with thionyl chloride (4.00 mL, 55.0 mmol) dropwise over 20 mm. The resulting mixture was allowed to warm to room temperature and left stirring overnight. The reaction mixture was quenched with aqueous saturated NaHCO3 solution at 0 C. The solvent was then removed under vacuum, and the residue was suspended in ethyl acetate (200 mL). The organic phase was washed with brine (100 mL), dried (Na2504) and concentrated to afford Methyl 3-amino-5-bromobenzoate as a yellow solid (1.08 g, 98%). NMR (400 MHz, Methanol-d) oe 7.10 (t, J 1.6 Hz, 1H), 6.83 (t, J 1.6 Hz, 1H), 6.57 (t, J= 1.6 Hz, 1H), 3.46 (s, 3H). 13C NMR (100 MHz, CDC13) oe: 52.3, 114.6, 121.6, 122.3, 122.9, 132.6, 147.7, 166.0. m/z (ESI, MH) 231.

References

[1] Tetrahedron, 2010, vol. 66, # 42, p. 8254 - 8260
[2] Patent: WO2004/50619, 2004, A1. Location in patent: Page 21
[3] Chirality, 2015, vol. 27, # 8, p. 487 - 491
[4] Journal of the American Chemical Society, 2013, vol. 135, # 46, p. 17408 - 17416
[5] Patent: WO2014/19685, 2014, A1. Location in patent: Page/Page column 13; 39; 40

Methyl 3-amino-5-bromobenzoate synthesis

Synthesis of Methyl 3-amino-5-bromobenzoate from 3-Nitrobenzoic acid

Methyl 3-amino-5-bromobenzoate Preparation Products And Raw materials

Raw materials

3-Bromo-5-nitrobenzoic acid 3-Amino-5-bromobenzoic acid Methyl 3-bromo-5-nitrobenzoate Methyl 3-nitrobenzoate Methanol

3-Nitrobenzoic acid Water Iron Hydrochloric acid

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Preparation Products

Methyl 3-acetamido-5-bromobenzoate Methyl 5-bromo-3-hydroxybenzoate

Methyl 3-amino-5-bromobenzoate Suppliers

Global Suppliers ( 111)

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Weitixi Chemical Technology Co., Ltd	0371-53370800 18037197114	3807961510@qq.com	China	9957	58
New Energy Chemicals	0515-82159099 13770142076	info@njuchem.com	China	251	65
Beijing Ouhe Technology Co., Ltd	13552068683 13522913783	2355560935@qq.com	China	11777	60
Jia Xing Isenchem Co.,Ltd	0573-85285100 18627885956	isenchem@163.com	China	9389	66
Accela ChemBio Co.,Ltd.	021-50795510 4000665055	marketing@accelachem.com	China	10972	64
Shanghai Harvest Chemical Industrial Co., Ltd.	15721252604 17321035817	sales@harvest-chem.com	China	2829	64
Shanghai Topbiochem Technology Co., Ltd	021-58170097	info@topbiochem.com	China	9510	58
Shanghai potentpharm CO.,Ltd	13524892556	sales-cn@potentpharm.com	China	1011	55
9ding chemical ( Shanghai) Limited	4009209199	sales@9dingchem.com	China	18201	56
Shanghai Raise Chemical Technology Co.,Ltd	+86-021-50935922		China	7854	55

Supplier	Advantage
Henan Weitixi Chemical Technology Co., Ltd	58
New Energy Chemicals	65
Beijing Ouhe Technology Co., Ltd	60
Jia Xing Isenchem Co.,Ltd	66
Accela ChemBio Co.,Ltd.	64
Shanghai Harvest Chemical Industrial Co., Ltd.	64
Shanghai Topbiochem Technology Co., Ltd	58
Shanghai potentpharm CO.,Ltd	55
9ding chemical ( Shanghai) Limited	56
Shanghai Raise Chemical Technology Co.,Ltd	55

View Latest Price from Methyl 3-amino-5-bromobenzoate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-09-02	3-AMINO-5-BROMOBENZOATE 706791-83-5	$3.00	1KG	98%		Henan Fengda Chemical Co., Ltd
2026-03-20	3-AMINO-5-BROMOBENZOATE 706791-83-5	$10.00	1KG	99%	10 mt	Hebei Chuanghai Biotechnology Co., Ltd
2024-04-29	Methyl 3-amino-5-bromobenzoate 706791-83-5	$5.00	1kg	99.92%	50000tons	Ouhuang Engineering Materials (Hubei) Co., Ltd

3-AMINO-5-BROMOBENZOATE
706791-83-5
$3.00
98%
Henan Fengda Chemical Co., Ltd

3-AMINO-5-BROMOBENZOATE
706791-83-5
$10.00
99%
Hebei Chuanghai Biotechnology Co., Ltd

Methyl 3-amino-5-bromobenzoate
706791-83-5
$5.00
99.92%
Ouhuang Engineering Materials (Hubei) Co., Ltd

Methyl 3-amino-5-bromobenzoate Spectrum

Methyl 3-amino-5-bromobenzoate(706791-83-5)¹HNMR

706791-83-5 (Methyl 3-amino-5-bromobenzoate) Related Search:

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3-AMINO-5-BROMOBENZOATE Methyl 3-Amino-5-bromobenzoate Benzoic acid, 3-amino-5-bromo-, methyl ester METHYL-3-BROMO-5-AMINO BENZOATE 706791-83-5