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5-Norbornene-2-carbonitrile

CAS No.
95-11-4
Chemical Name:
5-Norbornene-2-carbonitrile
Synonyms
Bicyclo[2.2.1]-5-hepten-2-carbonitrile;2-Cyano-5-nor;TIMTEC-BB SBB007934;2-Cyano-5-norbornene;5-Cyano-2-norbornene;2-Cyanonorborn-5-ene;5-Diopatene-2-nitrile;5-Norbornene-2-carbonitriL;5-NORBORNENE-2-CARBONITRILE;Norborn-5-ene-2-carbonitrile
CBNumber:
CB0153050
Molecular Formula:
C8H9N
Molecular Weight:
119.16
MDL Number:
MFCD00167563
MOL File:
95-11-4.mol
MSDS File:
SDS
Last updated:2026-05-27 17:19:44

5-Norbornene-2-carbonitrile Properties

Melting point 12-14 °C(lit.)
Boiling point 82-86 °C10 mm Hg(lit.)
Density 0.999 g/mL at 25 °C(lit.)
refractive index n20/D 1.488(lit.)
Flash point 150 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
color Light yellow to Amber to Dark green
InChI InChI=1S/C8H9N/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-8H,3-4H2
InChIKey BMAXQTDMWYDIJX-UHFFFAOYSA-N
SMILES C12CC(C=C1)CC2C#N
CAS DataBase Reference 95-11-4(CAS DataBase Reference)
EWG's Food Scores 1
NIST Chemistry Reference Bicyclo[2.2.1]hept-5-ene-2-carbonitrile(95-11-4)
EPA Substance Registry System Bicyclo[2.2.1]hept-5-ene-2-carbonitrile (95-11-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  26-36/37/39-36/37
WGK Germany  3
RTECS  RB7930000
HS Code  29269090
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Toxicity LD50 ivn-mus: 10 mg/kg CSLNX* NX#00780
NFPA 704
2
2 0

5-Norbornene-2-carbonitrile price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich PH001332 BICYCLO[2.2.1]HEPT-5-ENE-2-CARBONITRILE AldrichCPR 95-11-4 25MG $398 2023-06-20 Buy
Sigma-Aldrich 150576 5-Norbornene-2-carbonitrile, mixture of isomers 98% 95-11-4 10g $89.2 2023-01-07 Buy
TCI Chemical N0897 5-Norbornene-2-carbonitrile (mixture of isomers) >98.0%(GC) 95-11-4 5g $42 2026-04-30 Buy
TCI Chemical N0897 5-Norbornene-2-carbonitrile (mixture of isomers) >98.0%(GC) 95-11-4 25g $145 2026-04-30 Buy
Apolloscientific OR315245 5-Norbornene-2-carbonitrile 98% 95-11-4 5g $21 2026-06-04 Buy
Product number Packaging Price Buy
PH001332 25MG $398 Buy
150576 10g $89.2 Buy
N0897 5g $42 Buy
N0897 25g $145 Buy
OR315245 5g $21 Buy

5-Norbornene-2-carbonitrile Chemical Properties,Uses,Production

Chemical Properties

clear colourless liquid

Uses

Bicyclo[2.2.1]hept-2-ene-5-carbonitrile is used in method for continuously preparing cyanonorbornene by using microchannel reactor.

General Description

The hydrogenation of 5-norbornene-2-carbonitrile was studied using real-time mass spectrometric analysis.

Safety Profile

A poison by intravenous route.When heated to decomposition it emits toxic vapors ofNOx.

Synthesis

2-Nonene, 2,6-dimethyl-

67403-76-3

2,5-Norbornadiene

121-46-0

Dihydromyrcene

2436-90-0

5-Norbornene-2-carbonitrile

95-11-4

The general procedure for the synthesis of 3,7-dimethylocta-1,6-diene and bicyclo[2.2.1]hept-5-ene-2-carbonitrile from the compound (CAS:67403-76-3) and dicycloheptadiene was as follows: to a 4 mL screw-capped vial in an argon-protected glove box were added sequentially the compound 69 (82.6 mg, 0.50 mmol), norepiglottidiene 8 (51 μL, 0.5 mmol), hexane solution of 1.0 M AIMe2Cl (50 μL, 10.0 mol%, 0.05 mmol), Ni(COD)2 (3.45 mg, 2.5 mol%, 12.5 μmol), and DPEphos (6.75 mg, 2.5 mol%, 12.5 μmol) in THF ( 1.0 mL) solution. The vials were removed from the glove box and the reaction temperature was controlled at 28°C. The reaction mixture was stirred at 28 °C for 16 h and then concentrated under reduced pressure. The residue was purified by silica gel fast column chromatography (100% pentane as eluent) to afford product 70 (49.0 mg, 71% yield). The structure of the product was confirmed by 1H NMR (500 MHz, CDCl3) and 13C NMR (125 MHz, CDCl3) as follows: 1H NMR δ 5.74-5.64 (m, 1H), 5.13-5.06 (m, 1H), 4.99-4.88 (m, 2H), 2.12 (p, J=7.0 Hz, 1H ), 2.01-1.89 (m, 2H), 1.68 (s, 3H), 1.60 (s, 3H), 1.35-1.26 (m, 2H), 0.99 (d, J=6.9Hz, 3H); 13C NMR δ 144.91, 131.44, 124.80, 112.61, 37.51, 36.89, 25.88, 20.30, 17.83.

References

[1] Patent: WO2017/93149, 2017, A1. Location in patent: Page/Page column 28

1755-01-7
107-13-1
95-11-4
Synthesis of 5-Norbornene-2-carbonitrile from endo-Dicyclopentadiene and Acrylonitrile
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View Lastest Price from 5-Norbornene-2-carbonitrile manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-Norbornene-2-carbonitrile pictures 2026-08-25 5-Norbornene-2-carbonitrile
95-11-4
$2.00-6.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
5-Norbornene-2-carbonitrile pictures 2026-03-20 5-Norbornene-2-carbonitrile
95-11-4
1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
5-Norbornene-2-carbonitrile pictures 2025-12-24 5-Norbornene-2-carbonitrile
95-11-4
1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
5-NORBORNENE-2-CARBONITRILE 5-NORBORNENE-2-CARBONITRILE, 98%, MIXTUR E OF ISOMERS 5-norbornene-2-carbonitrile, mixture of isomers 2-Cyano-5-norbornene 2-Cyanobicyclo[2.2.1]hept-5-ene 5-Cyano-2-norbornene 5-Norbornene-2-carbonitrile, 98%, mixture of endo and exo 5-Norbornene-2-carbonitrile, mixture of endo and exo 2-Cyanonorborn-5-ene Bicyclo[2.2.1]hept-2-ene-5-carbonitrile Norborn-5-ene-2-carbonitrile 5-Cyano-bicyclo [2,2,1] heptene-2 2-Cyano-5-nor Bicyclo[2.2.1]hept-5-ene-2-carbonitrile 5-Cyanobicyclo[2.2.1]hept-2-ene 5-Cyano-2-norbornene 5-Norbornene-2-carbonitrile  6-bicyclo[2.2.1]hept-2-enecarbonitrile TIMTEC-BB SBB007934 5-Cyanobicyclo[2.2.1]hept-2-ene BICYCLO[2.2.1]HEPT-5-ENE-2-CARBONITRILE BICYCLO[2.2.1]-5-HEPTENE-2-CARBONITRILE 5-Norbornene-2-carbonitrile, mixture of isomers 98% bicyclo[2.2.1]hept-2-ene-6-carbonitrile Bicyclo[2.2.1]hept-5-ene-2-carbonitrile, exo- 5-Norbornene-2-carbonitrile, 98.5%, mixture of endo and exo 5-Norbornene-2-carbonitrile(mixtureofisomers)> 5-Norbornene-2-carbonitriL 5-Diopatene-2-nitrile 5-Norbornene-2-methanonitrile Bicyclo[2.2.1]-5-hepten-2-carbonitrile 95-11-4 1995-11-4 C7HCN Cyanides/Nitriles Organic Building Blocks Nitrogen Compounds Building Blocks C8 to C9 C8 to C9 Cyanides/Nitriles Nitrogen Compounds Building Blocks C8 to C9 Chemical Synthesis Norbornene Derivatives Nitrogen Compounds Organic Building Blocks Isoquinolines ,Quinolines ,Quinaldines