1-Ethyl-3-methylimidazolium bromide
- CAS No.
- 65039-08-9
- Chemical Name:
- 1-Ethyl-3-methylimidazolium bromide
- Synonyms
- EMIMBr;SKL1345;SKL1486;1-Ethyl-3-methylimidazole bromide;1-ETHYL-3-METHYLIMIDAZOLIUM BROMIDE;1-Ethyl-3-methylimidazoliumBromide>1,3-dimethyl-1H-imidazol-3-ium bromide;1-Ethyl-3-methylimidazolium bromide dry;1-Ethyl-3-methyl-imidazol-3-ium bromide;1-Ethyl-3-methylimidazolium bromide, 98+%
- CBNumber:
- CB1147830
- Molecular Formula:
- C6H11BrN2
- Molecular Weight:
- 191.07
- MDL Number:
- MFCD03427610
- MOL File:
- 65039-08-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 70-73°C |
|---|---|
| storage temp. | Store below +30°C. |
| form | Crystals, Crystalline Powder or Chunks |
| color | Pale yellow to yellow |
| PH | 7 (H2O, 20℃) |
| Water Solubility | Soluble in water, dichloromethane, ethanol, acetonitrile. Insoluble in ethyl acetate, ether, and alkane. |
| BRN | 5162084 |
| InChI | InChI=1S/C6H11N2.BrH/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1 |
| InChIKey | GWQYPLXGJIXMMV-UHFFFAOYSA-M |
| SMILES | N1(CC)C=C[N+](C)=C1.[Br-] |
| CAS DataBase Reference | 65039-08-9(CAS DataBase Reference) |
| FDA UNII | XO254YE73I |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-22 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 29332900 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 |
|||||||||
| NFPA 704 |
|
1-Ethyl-3-methylimidazolium bromide price More Price(43)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 89483 | 1-Ethyl-3-methylimidazolium bromide ≥97.0% (T) | 65039-08-9 | 5G | $61.3 | 2026-04-30 | Buy |
| Sigma-Aldrich | 89483 | 1-Ethyl-3-methylimidazolium bromide ≥97.0% (T) | 65039-08-9 | 50g | $256 | 2026-04-30 | Buy |
| Sigma-Aldrich | 03938 | 1-Ethyl-3-methylimidazolium bromide dry, ≥98.5% (HPLC/T) | 65039-08-9 | 5g | $257 | 2023-06-20 | Buy |
| Sigma-Aldrich | 03938 | 1-Ethyl-3-methylimidazolium bromide dry, ≥98.5% (HPLC/T) | 65039-08-9 | 25g | $490 | 2023-06-20 | Buy |
| TCI Chemical | E0543 | 1-Ethyl-3-methylimidazolium Bromide >98.0%(T) | 65039-08-9 | 5g | $32 | 2026-04-30 | Buy |
1-Ethyl-3-methylimidazolium bromide Chemical Properties, Uses, Production
Chemical Properties
pale yellow to yellow crystals, crystalline powder
Uses
An ionic liquid, 1-ethyl-3-methylimidazolium bromide is used as reaction medium for the synthesis and crystallization of a coordination polymer, (EMI)[Cd(BTC)]. 1-ethyl-3-methylimidazolium bromide was used as a solvent in [emim] 2 [Cd 2 (btec)Br 2 ]. Form the diene complexation; carbonyl insertion; cycloaddition; reduction and deoxygenation.
Synthesis
616-47-7
74-96-4
65039-08-9
All ligands (except #3) were synthesized with reference to the modified Starikova et al. method [20]. Typical generic synthesis steps are given below with spectral and analytical data. N-monosubstituted imidazole (0.1 mmol) and anhydrous toluene were added to a two-necked flask and stirred until a homogeneous solution was formed; followed by the slow dropwise addition of ethyl bromide (0.3 mmol) under continuous stirring. After the dropwise addition, the reaction mixture was heated with stirring at 40 °C for 24 hours. After completion of the reaction, the solvent was removed under reduced pressure and the resulting product was dried under vacuum to give the target ligand.2.2.2 1-Ethyl-3-methylimidazolium bromide (2) was a white solid with a yield of 4.70 g (98% yield).IR (ATR, cm1): 3065, 2975, 1670, 1571, 1467, 1172, 1101, 856, 789, 649, 621, 417. 649, 621, 417; 1H NMR (400 MHz, CDCl3): δ 1.47 (3H, t, J = 7.3 Hz, CH3), 3.97 (3H, s, NCH3), 4.32 (2H, q, NCH2), 7.54 (2H, s, NCH), 10.07 (1H, s, CH); 13C NMR (100 MHz, CDCl3): δ 15.64 (CH3), 36.63 (NCH3), 45.18 (NCH2), 122.01 (NCH), 123.71 (NCH), 136.73 (NCH). Mass spectrum (ESI): m/z 111.5 (M+Br). High-resolution mass spectrum (ESI): calculated value C6H11BrN2 (M+Br) 111.09222, measured value 111.09196.
References
[1] Angewandte Chemie - International Edition, 2012, vol. 51, # 46, p. 11483 - 11486
[2] Angew. Chem., 2012, vol. 124, # 46, p. 11650 - 11654,5
[3] Organic and Biomolecular Chemistry, 2013, vol. 11, # 15, p. 2534 - 2542
[4] Journal of Chemical and Engineering Data, 2004, vol. 49, # 4, p. 760 - 764
[5] Patent: WO2006/63656, 2006, A1. Location in patent: Page/Page column 32
1-Ethyl-3-methylimidazolium bromide Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jinan Xinda Chemical Co. LTD | 18615526239 | 363436853@qq.com | China | 167 | 58 |
| Jinan New Era Chemical Co., Ltd. | 0531-84319199 18660131512 | 1417934650@qq.com | China | 48 | 58 |
| Shandong Xinyang Chemical Co., Ltd | 13287720377 | 3585673409@qq.com | China | 166 | 58 |
| Jiangxi JinKai Chemical Co.,Ltd | 15376072011 | sales3@dyckbiotech.com | China | 15 | 58 |
| JINANJINGSHENGHUAGONGYOUXIANGONGSI | 178-66616785 15795376785 | 3193653335@qq.com | China | 210 | 58 |
| Shandong Jiaoyang Chemical Co., Ltd | 198 1918 9303/18265196555 18265196555 | 27207437@qq.com | China | 85 | 58 |
| Shanghai Boyle Chemical Co., Ltd. | sales@boylechem.com | China | 2915 | 55 | |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
View Latest Price from 1-Ethyl-3-methylimidazolium bromide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-18 | 1-Ethyl-3-methylimidazolium bromide
65039-08-9
|
1kg/bag | ≥98% | 50 T/Month | Hebei Qujie Technology Co., Ltd. | ||
 |
2026-09-18 | 1-ethyl-3-methylimidazolium bromide
65039-08-9
|
$120.00 | 1kg | 0.98 | 100kg | Shanghai UCHEM Inc. | |
 |
2026-09-18 | 1-Ethyl-3-methylimidazolium bromide
65039-08-9
|
1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD |
-
- 1-Ethyl-3-methylimidazolium bromide
65039-08-9
- $0.00
- ≥98%
- Hebei Qujie Technology Co., Ltd.
-
- 1-ethyl-3-methylimidazolium bromide
65039-08-9
- $120.00
- 0.98
- Shanghai UCHEM Inc.
-
- 1-Ethyl-3-methylimidazolium bromide
65039-08-9
- $0.00
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
