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ChemicalBook >> CAS DataBase List >>2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Structure
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane structure
CAS No.
69190-62-1
Chemical Name:
2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Synonyms
tylboronic Acid Pinacol Ester;Butylboronic Acid Pinacol Ester;N-BUTYLBORONIC ACID, PINACOL ESTER;But-1-ylboronic acid, pinacol ester;Butane-1-boronic acid, pinacol ester;n-Butylboronic acid pinacol ester 97%;n-Butylboronic acid pinacol ester;2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-butyl-4,4,5,5-tetramethyl-
CBNumber:
CB1301379
Molecular Formula:
C10H21BO2
Molecular Weight:
184.08
MDL Number:
MFCD03789255
MOL File:
69190-62-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:49:10
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2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Properties

Boiling point 185-189
Density 0.865
refractive index 1.4182
Flash point 58°C
storage temp. Inert atmosphere,Store in freezer, under -20°C
Appearance Colorless to light yellow Liquid
InChI 1S/C10H21BO2/c1-6-7-8-11-12-9(2,3)10(4,5)13-11/h6-8H2,1-5H3
InChIKey ZHBANXSNVFDSMK-UHFFFAOYSA-N
SMILES CCCCB1OC(C)(C)C(C)(C)O1
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
PPE Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-24/25
RIDADR  UN 1993 3/PG 3
WGK Germany  3
HS Code  29319090
Storage Class 3 - Flammable liquids

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 680923 n-Butylboronic acid pinacol ester 97% 69190-62-1 1g $51.1 2022-05-15 Buy
Sigma-Aldrich 680923 n-Butylboronic acid pinacol ester 97% 69190-62-1 10g $189 2022-05-15 Buy
Apolloscientific OR10624 Butane-1-boronic acid, pinacol ester 98% 69190-62-1 5g $21 2026-06-04 Buy
Apolloscientific OR10624 Butane-1-boronic acid, pinacol ester 98% 69190-62-1 25g $74 2026-06-04 Buy
Apolloscientific OR10624 Butane-1-boronic acid, pinacol ester 98% 69190-62-1 100g $263 2026-06-04 Buy
Product number Packaging Price Buy
680923 1g $51.1 Buy
680923 10g $189 Buy
OR10624 5g $21 Buy
OR10624 25g $74 Buy
OR10624 100g $263 Buy

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Chemical Properties, Uses, Production

Chemical Properties

Clear colorless to brown liquid

Uses

n-Butylboronic acid pinacol ester can be used to prepare the fusaric acid and its analogs as possible inhibitors of quorum sensing in bacteria.

Synthesis

n-Butyllithium

109-72-8

1,3,2-Dioxaborolan-2-amine, N,N,4,4,5,5-hexamethyl-

557087-01-1

2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE

69190-62-1

Under argon protection, 17.1 g (0.10 mol) of PinB (DMA) was added to a 500 mL reaction flask containing 100 mL of tetrahydrofuran. The temperature of the reaction system was lowered to 0~5°C and 44.3 mL of a 2.5 M solution of n-butyllithium (0.11 mol) was slowly added dropwise and stirred for 30 minutes keeping the temperature at 0~5°C. The reaction system was then warmed to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, the reaction was quenched by slow dropwise addition of 200 mL of 1 M KH2PO4 buffer and then extracted three times with 150 mL of ethyl acetate. The organic phases were combined, dried over anhydrous sodium sulfate, and the organic phase was concentrated. To the concentrate was added 40 g of n-hexane and filtered to give 12.9 g of white solid product in 70% yield and >97% GC purity. The 1H NMR, 11B NMR and IR spectra of the product were consistent with those of the standard.

References

[1] Patent: CN102093399, 2016, B. Location in patent: Paragraph 0027-0028

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane synthesis

109-69-3
73183-34-3
69190-62-1
Synthesis of 2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane from 1-Chlorobutane and Bis(pinacolato)diboron

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Preparation Products And Raw materials

Raw materials

Boronic acid, butyl-, dimethyl ester Triphenyltin hydride 2-(4-broMobutyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane 1,3,2-Dioxaborolan-2-amine, N,N,4,4,5,5-hexamethyl- Di-n-butylmagnesium
Pinacol 1-Chlorobutane cis-2-Butene 1-Bromobutane Pinacolborane

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Preparation Products

n-Butylboronic acid 1-HEPTEN-3-OL

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Suppliers

Global Suppliers ( 88)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Sunway Pharmaceutical Technology Co., Ltd 13761987713 hxzheng@sunwaypharm.cn China 8663 57
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9509 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. 64
Jia Xing Isenchem Co.,Ltd 66
Pure Chemistry Scientific Inc. 62
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai Sunway Pharmaceutical Technology Co., Ltd 57
Shanghai Topbiochem Technology Co., Ltd 58

View Latest Price from 2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE pictures 2020-02-04 2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
69190-62-1
 1KG 98%; 99% 1kg; 5kg Career Henan Chemical Co

2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Spectrum

2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE(69190-62-1)1HNMR

69190-62-1 (2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane) Related Search:

n-Pentylboronic acid 1-Hexaneboronic acid n-Butylboronic acid 2-Octyl-1,3,6,2-dioxazaborocane Propylboronic acid
1-Octylboronic acid n-Heptaneboronic acid N-Hexylboronic acid diethanolamine ester Cyclohexylboronic acid pinacol ester 3-Cyano-1-propylboronic acid pinacol ester, 96%
Cyclohexene-1-boronic acid pinacol ester 2-Cyclopentenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1,4-Dioxa-spiro[4,5]dec-7-en-8-boronic acid, pinacol ester 1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)heptene 2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1-cis-1,2-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentene (E)-1-Hexene-1,2-diboronic acid bis(pinacol) ester 2-Butyl-1,3,2-dioxaborolane-4s,5s-dicarboxylic acid bis(dimethylamide)

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n-Butylboronic acid pinacol ester 97% N-BUTYLBORONIC ACID, PINACOL ESTER 1,3,2-Dioxaborolane, 2-butyl-4,4,5,5-tetramethyl- But-1-ylboronic acid, pinacol ester Butane-1-boronic acid, pinacol ester Butylboronic Acid Pinacol Ester tylboronic Acid Pinacol Ester n-Butylboronic acid pinacol ester 2-Butyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 69190-62-1 C10H21BO2 Organometallic Reagents Alkyl Boronate Esters Boronic Acids and Derivatives Alkyl Organoborons