5-Methylthianaphthene
- CAS No.
- 14315-14-1
- Chemical Name:
- 5-Methylthianaphthene
- Synonyms
- 5-METHYLBENZO[B]THIOPHENE;BUTTPARK 33\04-62;5-methylthianaphthene;5-METHYLBENZOTHIOPHENE;Benzothiophene, 5-mehyl;Trofinetide Impurity 13;5-METHYL-1-BENZOTHIOPHENE;Benzo[b]thiophene, 5-methyl-;5-Methylbenzo[b]thiophene,98%;5-Methylbenzobüthiophene, 96%
- CBNumber:
- CB1362475
- Molecular Formula:
- C9H8S
- Molecular Weight:
- 148.22
- MDL Number:
- MFCD00052509
- MOL File:
- 14315-14-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 35-36 °C |
|---|---|
| Boiling point | 71-73°C 0,6mm |
| Density | 1,111 g/cm3 |
| refractive index | 1.6150 (estimate) |
| Flash point | 71-73°C/0.6mm |
| storage temp. | 2-8°C |
| form | Low Melting Mass |
| color | White |
| Water Solubility | Insoluble in water. |
| λmax | 303nm(Hexane)(lit.) |
| BRN | 109866 |
| CAS DataBase Reference | 14315-14-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzo[b]thiophene, 5-methyl-(14315-14-1) |
| EPA Substance Registry System | 5-Methylbenzo[b]thiophene (14315-14-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H301 | |||||||||
| Precautionary statements | P264-P270-P301+P310a-P321-P405-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-22 | |||||||||
| Safety Statements | 36/37/39-26-22 | |||||||||
| Hazard Note | Harmful | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
5-Methylthianaphthene price More Price(69)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | M2974 | 5-Methylbenzo[b]thiophene >98.0%(GC) | 14315-14-1 | 1g | $120 | 2026-04-30 | Buy |
| TCI Chemical | M2974 | 5-Methylbenzo[b]thiophene >98.0%(GC) | 14315-14-1 | 5g | $475 | 2026-04-30 | Buy |
| Apolloscientific | OR26010 | 5-Methylbenzo[b]thiophene ≥95% | 14315-14-1 | 250mg | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR26010 | 5-Methylbenzo[b]thiophene ≥95% | 14315-14-1 | 1g | $28 | 2026-06-04 | Buy |
| Apolloscientific | OR26010 | 5-Methylbenzo[b]thiophene ≥95% | 14315-14-1 | 5g | $82 | 2026-06-04 | Buy |
5-Methylthianaphthene Chemical Properties,Uses,Production
Chemical Properties
white low melting mass
Uses
5-Methylbenzo[b]thiophene is useful in substituted thiophene for proteomics research.
Synthesis
106-45-6
2032-35-1
14315-14-1
Step 1: 5.2 g of bromoacetaldehyde diethyl acetal was dissolved in 10 mL of tetrahydrofuran and slowly added dropwise to a mixture containing 4.00 g of 4-methylbenzenethiol, 1.4 g of 60% sodium hydride (dispersed in mineral oil) and 35 mL of tetrahydrofuran. The reaction mixture was stirred at room temperature for 15 hours. Upon completion of the reaction, the reaction was quenched by the addition of 10 mL of saturated aqueous ammonium chloride, followed by three extractions with tert-butyl methyl ether. The organic phases were combined, washed sequentially with water and saturated brine, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to remove the solvent. Step 2: The above concentrated residue was added to a mixture of 5 g of phosphorus pentoxide and 10 g of phosphoric acid that had been preheated to 175°C and stirred for 45 minutes, and stirring was continued for 5 minutes. At the end of the reaction, the mixture was quenched by pouring it into ice water and extracted three times with tert-butyl methyl ether. The organic phases were combined, washed sequentially with water and saturated brine, dried over anhydrous magnesium sulfate, and concentrated under reduced pressure to remove the solvent. Step 3: The final residue was purified by silica gel column chromatography to give 2.77 g 5-methylbenzo[b]thiophene.
References
[1] Patent: US2015/282482, 2015, A1. Location in patent: Paragraph 2116; 2117
5-Methylthianaphthene Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
5-Methylthianaphthene Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 |
View Lastest Price from 5-Methylthianaphthene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-02-02 | 5-Methylthianaphthene
14315-14-1
|
$1.00 | 1g | 99% | 50tons | Shaanxi Dideu Medichem Co. Ltd |
-
- 5-Methylthianaphthene
14315-14-1
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
