Tributyltin Hydride
- CAS No.
- 688-73-3
- Chemical Name:
- Tributyltin Hydride
- Synonyms
- Bu3SnH;TRIBUTYLSTANNANE;tbth;Tributyltin;TRI-N-BUTYLTIN HYDRIDE;TRI-N-BUTYLTIN;TRI-N-BUTYLSTANNANE;tributyl-stannan;Tributyltin hydrid;Stannane, tributyl-
- CBNumber:
- CB6736950
- Molecular Formula:
- C12H28Sn
- Molecular Weight:
- 291.06
- MDL Number:
- MFCD00009416
- MOL File:
- 688-73-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | <0°C |
|---|---|
| Boiling point | 80 °C0.4 mm Hg(lit.) |
| Density | 1.082 g/mL at 25 °C(lit.) |
| vapor pressure | 5 hPa (20 °C) |
| refractive index |
n |
| Flash point | 104 °F |
| storage temp. | Store below +30°C. |
| form | liquid |
| color | colorless |
| Specific Gravity | 1.103 (20℃) |
| Water Solubility | REACTS |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 3587329 |
| Exposure limits |
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/3C4H9.Sn/c3*1-3-4-2;/h3*1,3-4H2,2H3; |
| InChIKey | PIILXFBHQILWPS-UHFFFAOYSA-N |
| CAS DataBase Reference | 688-73-3(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 4XDX163P3D |
| NIST Chemistry Reference | Tri-n-butyltin hydride(688-73-3) |
| EPA Substance Registry System | Tributyltin (688-73-3) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312-H315-H319-H360-H372-H400-H410 | |||||||||
| Precautionary statements | P264-P270-P280-P201-P202-P260-P273-P301+P310-P330-P302+P352-P312-P362+P364-P332+P313-P305+P351+P338-P337+P313-P308+P313-P314-P391-P405-P501 | |||||||||
| Hazard Codes | T,N,F | |||||||||
| Risk Statements | 10-21-25-36/38-48/23/25-50/53-15-67-65-11 | |||||||||
| Safety Statements | 35-36/37/39-45-60-61-62-36/37-33-26-16 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | WH8675000 | |||||||||
| F | 1-10 | |||||||||
| Autoignition Temperature | >250 °C | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29310095 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Acute Tox. 3 Oral Acute Tox. 4 Dermal Aquatic Acute 1 Aquatic Chronic 1 Eye Irrit. 2 Flam. Liq. 3 Repr. 1B Skin Irrit. 2 STOT RE 1 |
|||||||||
| Hazardous Substances Data | 688-73-3(Hazardous Substances Data) | |||||||||
| REACH Registrations | Active | |||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Tributyltin Hydride price More Price(35)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.14109 | Tributyltin hydride (stabilized) for synthesis | 688-73-3 | 5ml | $45.6 | 2026-04-30 | Buy |
| Sigma-Aldrich | 8.14109 | Tributyltin hydride (stabilized) for synthesis | 688-73-3 | 25mL | $119 | 2026-04-30 | Buy |
| Sigma-Aldrich | 8.14109 | Tributyltin hydride (stabilized) for synthesis | 688-73-3 | 100mL | $356 | 2026-04-30 | Buy |
| Sigma-Aldrich | 234788 | Tributyltin hydride contains 0.05% BHT as stabilizer, 97% | 688-73-3 | 10g | $70.7 | 2026-04-30 | Buy |
| Sigma-Aldrich | 234788 | Tributyltin hydride contains 0.05% BHT as stabilizer, 97% | 688-73-3 | 50g | $205 | 2026-04-30 | Buy |
Tributyltin Hydride Chemical Properties, Uses, Production
Synthesis
In a 1000ml reaction flask, add 300g (0.5mol) of tributyltin hydride oxide and 100g of hydrogen-containing polysiloxane or hydrogen-containing polysiloxane waste (1% hydrogen content) while stirring. The reaction system is slowly heated (generally not exceeding 20℃; for large quantities, cooling should be considered). After about 1 hour, the heating is stopped, and stirring continues for 30 minutes. The fraction at 105~107℃/0.8kPa is collected by vacuum distillation to obtain a colorless liquid, namely tributyltin hydride.
Uses
Chemical Properties
clear colourless liquid
Uses
A widely used radical reagent used in reductive cleavage,1 radical dehalogenation, and intramolecular radical cyclization.2
Uses
Tributyltin hydride the most commonly used tin hydride，it is less toxic than the more volatile trierhyl and trimethyl analogues, and it is therefore the most widely used organostannane.
Tributyltin hydride, the reagent of choice for generating alkyl radical, is also widely used in aryl radical cyclization. Other reagents developed for this purpose include samarium diiodide, palladium reagents organosilanes as well as manganese triacetate and transition metals for carbocyclization.
Uses
Tributyltin hydride is used to effect carbon—carbon bond formation with the displacement of halide from a suitably oriented haloalkyl group.
Application
Has been reviewed. Catalyzes the Si-H reduction of α,β-unsaturated ketones. Useful in the reductive amination of ketones and aldehydes to form 3° amines.
Hazard
Moderately toxic by inhalation.
reaction suitability
reagent type: reductant
Safety Profile
Moderately toxic by inhalation. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS.
Purification Methods
Dissolve it in Et2O, add quinol (500mg for 300mL, to stabilize it), dry over Na2SO4, filter, evaporate and distil it under dry N2. It is a clear liquid if dry and decomposes very slowly. In the presence of H2O, traces of tributyl tin hydroxide are formed in a few days. Store it in sealed glass ampoules in small aliquots. It is estimated by reaction with aqueous NaOH when H2 is liberated. CARE: stored samples may be under pressure due to liberated H2. [Van Der Kerk et al. J Appl Chem 7 366 1937, Ono et al. Tetrahedron 41 4013 1985, Neuman Synthesis 665 1987, Curran Synthesis 417 1988, Beilstein 4 IV 4312.]
Tributyltin Hydride Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Nantong Haotai Products & Chemicals Co.,Ltd. | 0513-81063598 15996548297 | 2136488295@qq.com | China | 22 | 58 |
| Nanjing Kaitian Chemical Co., Ltd | 15951673915 | 377901895@qq.com | China | 94 | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451683 15021268886 | sales@arborchemical.com | China | 837 | 55 |
| Tangyuan Life Science (Shanghai) Co., Ltd | 400-618-1121 17316483629 | sales@townyuan.com | China | 2761 | 58 |
| Tianjin Zhongxin Chemtech Co., Ltd. | 022-66880623 | sales@tjzxchem.com | China | 612 | 60 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Chang Zhou Chemistar Chemistry Technology Co.,Ltd | +86 (519) 8689-6136 | kr@krchemistar.com | China | 181 | 55 |
| Beijing dtftchem Technology Co., Ltd. | 010-60275820 13031183356 | elainezt@sina.com | China | 1386 | 62 |
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View Latest Price from Tributyltin Hydride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-14 | Tributyltin Hydride
688-73-3
|
$1.00 | 1KG | 99% | 25kg | Career Henan Chemical Co |
-
- Tributyltin Hydride
688-73-3
- $1.00
- 99%
- Career Henan Chemical Co
