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ChemicalBook >> CAS DataBase List >>(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Structure
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane structure
CAS No.
824395-67-7
Chemical Name:
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane
Synonyms
(S,S)-Ph-BPE;Ph-BPE;1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane;1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane;(S,S)-Ph-BPE,BPE;1,2-Bis(2S,5S-2,5-diphenylphospholano)ethane;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane;1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+%;(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%;(2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphosphol...
CBNumber:
CB2128267
Molecular Formula:
C34H36P2
Molecular Weight:
506.61
MDL Number:
MFCD07369028
MOL File:
824395-67-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:50:13
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(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Properties

Melting point 143-147 °C
alpha +182.7° (c 1.0, CH2Cl2)
Boiling point 654.2±55.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Sparingly Soluble (3.2E-5 g/L) (25°C).
form solid
color white
Sensitive Air Sensitive
InChIKey VHHAZLMVLLIMHT-LXIGBKQFNA-N
SMILES C([P@@]1[C@H](C2C=CC=CC=2)CC[C@H]1C1C=CC=CC=1)C[P@@]1[C@H](C2C=CC=CC=2)CC[C@H]1C1C=CC=CC=1 |&1:1,2,11,19,20,29,r|
CAS DataBase Reference 824395-67-7
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
Storage Class 11 - Combustible Solids
NFPA 704
1
0 0

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 824395-67-7 100mg $110.25 2026-04-30 Buy
Sigma-Aldrich 667854 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane kanata purity 824395-67-7 500mg $434 2026-04-30 Buy
Strem Chemicals 15-0474 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE min.98% 824395-67-7 100mg $105 2026-04-30 Buy
Strem Chemicals 15-0474 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE min.98% 824395-67-7 500mg $393 2026-04-30 Buy
Strem Chemicals 15-0474 (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE min.98% 824395-67-7 2g $1140 2026-04-30 Buy
Product number Packaging Price Buy
667854 100mg $110.25 Buy
667854 500mg $434 Buy
15-0474 100mg $105 Buy
15-0474 500mg $393 Buy
15-0474 2g $1140 Buy

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Chemical Properties, Uses, Production

Reaction

  1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
  2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
  3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
  4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
  5. Ligand for asymmetric addition of allyl cyanide to ketones.
  6. Ligand for catalytic enantio- and diastereoselective aldol reaction of thioamides.
Reactions of 824395-67-7_1
Reactions of 824395-67-7_2

Uses

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane is a chiral reagent that is used as a catalyst and also as an enantioselective reagent in synthetic chemistry.

Uses

It is a DuPhos and BPE ligands which are highly efficient privileged ligands. It is a chiral phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides.

General Description

Chiral Phosphine ligand used in the asymmetric hydrogenation of allylic sulfoxides

Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Suppliers

Global Suppliers ( 63)
Supplier Tel Email Country ProdList Advantage
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Sinocompound Catalysts Co., Ltd. 0512-67216630 67216634 sales@sinocompound.com China 252 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Aikon International Limited 025-58851090 13913916777 sales01@aikonchem.com China 15947 58
Rhawn Reagent 400-400-1332688 18019345275 huyue@rhawn.cn China 14942 58
Supplier Advantage
Xinxiang Runyu Material Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sinocompound Catalysts Co., Ltd. 64
Sigma-Aldrich 80
LaaJoo 58
Aikon International Limited 58
Rhawn Reagent 58

View Latest Price from (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE pictures 2026-09-18 (+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE
824395-67-7
 1KG 98% 2000 Shenzhen Nexcon Pharmatechs Ltd.
1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane pictures 2026-08-25 1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane
824395-67-7
 $2.00-6.00 1KG 99% ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane pictures 2025-12-23 1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane
824395-67-7
 1kg 98%，ee>99 500kg XINXIANG RUNYU MATERIAL CO., LTD.

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Spectrum

(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(824395-67-7)1HNMR

824395-67-7 ((+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane) Related Search:

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Dibenzylphosphine (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(S,S)-Ph-BPE-Rh

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(+)-1,2-BIS((2S,5S)-2,5-DIPHENYLPHOSPHOLANO)ETHANE, KANATA PURITY (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane,min.98%(S,S)-Ph-BPE 1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane, 97+% (S,S)-Ph-BPE,BPE (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphospholane) Phospholane, 1,1'-(1,2-ethanediyl)bis[2,5-diphenyl-, (2S,2'S,5S,5'S)- (9CI) (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98%,99%ee (2S,5S,2'S,5'S)-1,1'-ethane-1,2-diylbis(2,5-diphenylphosphol... (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane (2S,5S)-1-[2-[(2S,5S)-2,5-diphenylphospholan-1-yl]ethyl]-2,5-diphenyl-phospholane - [D87488] (S,S)-Ph-BPE 1,2-Bis((2S,5S)-2,5-diphenylphospholan-1-yl)ethane 1,2-Bis[(2S,5S)-2,5-diphenyl-1-phospholanyl]ethane Ph-BPE 1,2-Bis(2S,5S-2,5-diphenylphospholano)ethane 824395-67-7 C34H36P2 New Products for Chemical Synthesis May/June 2007 Chiral Phosphine Chiral Catalysts, Ligands, and Reagents DuPhos/BPE Privileged Ligands and Complexes organophosphine ligand