Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate Structure
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate structure
CAS No.
528565-84-6
Chemical Name:
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate
Synonyms
(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(R,R)-PH-BPE-RH;(-)-1,2-Bis((2R,5R)-2,5-diphenyL;Rhodium(1+),?[(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanedi…;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate;1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-Ph-BPE-Rh;(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh
CBNumber:
CB7441024
Molecular Formula:
C42H48BF4P2Rh
Molecular Weight:
804.49
MDL Number:
MFCD07369037
MOL File:
528565-84-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:54:56
Request For Quotation

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate Properties

storage temp. 2-8°C, protect from light, stored under nitrogen
form crystal
color orange
Sensitive air sensitive
InChIKey HOYBXERAQSXVFT-FMUQXVHFSA-N
SMILES [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2C[C@@H](P(CCP3[C@H](CC[C@@H]3c4ccccc4)c5ccccc5)[C@H]2c6ccccc6)c7ccccc7
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 698350 1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 528565-84-6 50mg $143 2023-06-20 Buy
Sigma-Aldrich 698350 1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 528565-84-6 250mg $317 2023-06-20 Buy
Strem Chemicals 45-0201 (-)-1,2-Bis((2R,5R)-2,5-diphenyl­phospholano)ethane(1,5-cyclo­octadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh min.98% 528565-84-6 100mg $130 2026-04-30 Buy
Strem Chemicals 45-0201 (-)-1,2-Bis((2R,5R)-2,5-diphenyl­phospholano)ethane(1,5-cyclo­octadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh min.98% 528565-84-6 500mg $548 2026-04-30 Buy
Strem Chemicals 45-0201 (-)-1,2-Bis((2R,5R)-2,5-diphenyl­phospholano)ethane(1,5-cyclo­octadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh min.98% 528565-84-6 2g $1778 2026-04-30 Buy
Product number Packaging Price Buy
698350 50mg $143 Buy
698350 250mg $317 Buy
45-0201 100mg $130 Buy
45-0201 500mg $548 Buy
45-0201 2g $1778 Buy

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate Chemical Properties, Uses, Production

Reactions

1. Phenyl-BPE exhibits enhanced activity and selectivity over existing members of the BPE ligand family in rhodium catalysed asymmetric hydrogenation.
2. This ligand is highly efficient for the hydrogenation of N-acyl aryl-enamides.
3. Molar substrate/catalyst ratios of up to 100,000/1 are achieved with excellent reactivity and enantioselectivity using commercial grade substrates and solvents.
4. Ligand in the rhodium-catalyzed asymmetric hydroformylation of olefins.
Reactions of 528565-84-6

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate Suppliers

Global Suppliers ( 38)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 15221275939 shenlinxing@macklin.cn China 15775 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9170 60
Aikon International Limited 025-58859352 19370895928 sales01@aikonchem.com China 15078 58
Shanghai UCHEM Inc. +86-18930848214 +86-021-56762820 sales@myuchem.com China 8966 58
Henan Weituxi Chemical Technology Co., Ltd. 0371-63284658 18135795563 3905209149@qq.com China 9703 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
Energy Chemical 61
Shanghai Macklin Biochemical Co.,Ltd. 55
Sigma-Aldrich 80
Alfa Chemistry 60
Aikon International Limited 58
Shanghai UCHEM Inc. 58
Henan Weituxi Chemical Technology Co., Ltd. 58

View Latest Price from (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE pictures 2019-08-07 (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
528565-84-6
 $1.00 1KG 98% 1kg，5kg，100kg Career Henan Chemical Co
(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE pictures 2019-08-07 (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
528565-84-6
 $1.00 1KG 98% 1kg，5kg，100kg Career Henan Chemical Co

528565-84-6 ((-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate) Related Search:

Dibenzylphosphine (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate

1of2

(-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-Ph-BPE-Rh (R,R)-PH-BPE-RH (-)-1,2-Bis((2R,5R)-2,5-diphenyL (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-Ph-BPE-Rh 1,2-Bis[(2R,5R)-2,5-diphenylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Rhodium(1+),?[(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-ethanedi… (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate 528565-84-6 RhC8H12C34H36P2BF4 metal phosphine complex