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2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide

CAS No.
86608-70-0
Chemical Name:
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
Synonyms
2-(1,3-Dioxolan-2-yl)ethyltrip;2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSP;[2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide;2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;2- (1,3-dioxapron-2-yl) ethyltriphenylphosphine bromide;2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphoniumBromide>[2-(1,3-dioxolan-2-yl)ethyl]triphenylphosphanium bromide;[2-(1,3-dioxalan-2-yl)ethyl]triphenylphosphonium bromide;2-(1,3)-DIOXOLANE-2-YL) ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;Phosphonium, 2-(1,3-dioxolan-2-yl)ethyltriphenyl-, bromide
CBNumber:
CB2208826
Molecular Formula:
C23H24BrO2P
Molecular Weight:
443.31
MDL Number:
MFCD00075119
MOL File:
86608-70-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:59:20
Product description Number Pack Size Price
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide 97% 338117 5g $46.4
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) D2056 5g $107
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) D2056 25g $312
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide TRC-D487548-50MG 50mg $65
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide TRC-D487548-500MG 500mg $103
More product size

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Properties

Melting point 144-146 °C(lit.)
storage temp. Store at room temperature
solubility soluble in Methanol
form solid
color White to Light yellow to Light orange
BRN 5209374
InChI 1S/C23H24O2P.BrH/c1-4-10-20(11-5-1)26(21-12-6-2-7-13-21,22-14-8-3-9-15-22)19-16-23-24-17-18-25-23;/h1-15,23H,16-19H2;1H/q+1;/p-1
InChIKey ZCJKBPSRKLHANV-UHFFFAOYSA-M
SMILES [Br-].C1COC(CC[P+](c2ccccc2)(c3ccccc3)c4ccccc4)O1
CAS DataBase Reference 86608-70-0(CAS DataBase Reference)
EPA Substance Registry System Phosphonium, [2-(1,3-dioxolan-2-yl)ethyl]triphenyl-, bromide (1:1) (86608-70-0)
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Health Hazard (GHS08)Corrosion (GHS05)Exclamation Mark (GHS07)
GHS08,GHS05,GHS07
Signal word  Danger
Hazard statements  H315-H302-H318-H373-H412
Precautionary statements  P273-P280-P305+P351+P338-P264-P270-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P501
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn
Risk Statements  22-33-41-52/53
Safety Statements  22-26-39-61
WGK Germany  2
3
TSCA  TSCA listed
HS Code  29322090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
STOT RE 2
REACH Registrations Inactive
NFPA 704
0
2 0

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 338117 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide 97% 86608-70-0 5g $46.4 2022-05-15 Buy
TCI Chemical D2056 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) 86608-70-0 5g $107 2026-04-30 Buy
TCI Chemical D2056 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) 86608-70-0 25g $312 2026-04-30 Buy
TRC TRC-D487548-50MG 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide 86608-70-0 50mg $65 2026-06-03 Buy
TRC TRC-D487548-500MG 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide 86608-70-0 500mg $103 2026-06-03 Buy
Product number Packaging Price Buy
338117 5g $46.4 Buy
D2056 5g $107 Buy
D2056 25g $312 Buy
TRC-D487548-50MG 50mg $65 Buy
TRC-D487548-500MG 500mg $103 Buy

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

Pale yellow powder

Uses

suzuki reaction

Uses

Reactant for:

  • Wittig olefination
  • Preparationof ligands for histamine receptor binding with H3/H4 subtype selectivity
  • Preparation of dual inhibitors of phosphodiesterase-4 and serotonin reuptake

reaction suitability

reaction type: C-C Bond Formation

Synthesis

In a 100ml four-necked flask equipped with reflux condenser tube (gas absorption device at the top), dropping funnel, stirrer, add 20ml of water, slowly add 24ml of concentrated sulfuric acid, cool down and then add 2-(2-hydroxyethyl)-1,3-dioxane, mix well and then add 20g of finely ground sodium bromide, heated to reflux for 1h. Cool down and then converted to decompression distillation device, reduce the pressure to 6mmHg, collect the crude product. 90-100 when the fraction, the crude product. The crude product was poured into a separatory funnel, 20 ml of water was added to wash out the aqueous layer, the organic phase was poured into another dry separatory funnel, washed with 10 ml of concentrated sulfuric acid to separate out the acid layer, and the organic phase was washed with 20 ml of water and 20 ml of saturated sodium bicarbonate solution, respectively, to obtain the pure product of 2-(1,3-dioxolan-2-yl)ethyltriphenylene. In a 100 ml four-necked flask equipped with a thermometer and a stirrer, 10 g of triphenylphosphine, 10.5 g of 2-(2-bromoethyl)-1,3-dioxane were added, and heated at 100C under the protection of N2 for 12 h. The reaction was then dispersed with ether and placed in dry ethyl acetate to form crystals by precipitating twice with ether. Recrystallization was carried out with a mixed solvent of ethyl acetate and ether to obtain the target compound 2-(1,3-dioxolan-2-yl)ethyltriphenylphosphonium bromide.

2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 155)Suppliers
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Henan Fengda Chemical Co., Ltd
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Shanghai Daken Advanced Materials Co.,Ltd
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Henan Tianfu Chemical Co.,Ltd.
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SIMAGCHEM CORP
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Shanghai UCHEM Inc.
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Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 17705817739 info@dycnchem.com China 52693 58

View Lastest Price from 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
	2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide pictures 2026-08-14 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
$5.00-8.00 1KG 99% Henan Fengda Chemical Co., Ltd
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide pictures 2025-04-04 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
[2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide pictures 2024-03-28 [2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide
86608-70-0
25kg 98%-99% PNP Biotech Co. Ltd
2-(1,3)-DIOXOLANE-2-YL) ETHYLTRIPHENYLPHOSPHONIUM BROMIDE 2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSP Phosphonium, 2-(1,3-dioxolan-2-yl)ethyltriphenyl-, bromide [2-(1,3-dioxalan-2-yl)ethyl]triphenylphosphonium bromide 2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSPHONIUM BROMIDE 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide,97% 2-(1,3-Dioxolan-2-yl)ethyltrip Phosphonium,[2-(1,3-dioxolan-2-yl)ethyl]triphenyl-, bromide (1:1) [2-(1,3-dioxolan-2-yl)ethyl]triphenylphosphanium bromide [2-(1,3-dioxolan-2-yl)phenyl]-ethyl-diphenylphosphonium bromide 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphoniumBromide> TIANFU-CHEM--2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide [2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide 2- (1,3-dioxapron-2-yl) ethyltriphenylphosphine bromide 86608-70-0 C-C Bond Formation Wittig & Horner-Emmons Reaction Dioxolanes Dioxanes & Dioxolanes Wittig Reaction Phosphonium Compounds Olefination Wittig Reagents Synthetic Reagents Dioxanes & Dioxolanes Dioxolanes Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction C-C Bond Formation Olefination Wittig Reagents