2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
- CAS No.
- 86608-70-0
- Chemical Name:
- 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
- Synonyms
- 2-(1,3-Dioxolan-2-yl)ethyltrip;2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSP;[2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide;2-(1,3-DIOXOLAN-2-YL)ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;2- (1,3-dioxapron-2-yl) ethyltriphenylphosphine bromide;2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphoniumBromide>[2-(1,3-dioxolan-2-yl)ethyl]triphenylphosphanium bromide;[2-(1,3-dioxalan-2-yl)ethyl]triphenylphosphonium bromide;2-(1,3)-DIOXOLANE-2-YL) ETHYLTRIPHENYLPHOSPHONIUM BROMIDE;Phosphonium, 2-(1,3-dioxolan-2-yl)ethyltriphenyl-, bromide
- CBNumber:
- CB2208826
- Molecular Formula:
- C23H24BrO2P
- Molecular Weight:
- 443.31
- MDL Number:
- MFCD00075119
- MOL File:
- 86608-70-0.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide 97% | 338117 | 5g | $46.4 |
| 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) | D2056 | 5g | $107 |
| 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) | D2056 | 25g | $312 |
| 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide | TRC-D487548-50MG | 50mg | $65 |
| 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide | TRC-D487548-500MG | 500mg | $103 |
| More product size | |||
| Melting point | 144-146 °C(lit.) |
|---|---|
| storage temp. | Store at room temperature |
| solubility | soluble in Methanol |
| form | solid |
| color | White to Light yellow to Light orange |
| BRN | 5209374 |
| InChI | 1S/C23H24O2P.BrH/c1-4-10-20(11-5-1)26(21-12-6-2-7-13-21,22-14-8-3-9-15-22)19-16-23-24-17-18-25-23;/h1-15,23H,16-19H2;1H/q+1;/p-1 |
| InChIKey | ZCJKBPSRKLHANV-UHFFFAOYSA-M |
| SMILES | [Br-].C1COC(CC[P+](c2ccccc2)(c3ccccc3)c4ccccc4)O1 |
| CAS DataBase Reference | 86608-70-0(CAS DataBase Reference) |
| EPA Substance Registry System | Phosphonium, [2-(1,3-dioxolan-2-yl)ethyl]triphenyl-, bromide (1:1) (86608-70-0) |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() ![]() GHS08,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H302-H318-H373-H412 | |||||||||
| Precautionary statements | P273-P280-P305+P351+P338-P264-P270-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P501 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-33-41-52/53 | |||||||||
| Safety Statements | 22-26-39-61 | |||||||||
| WGK Germany | 2 | |||||||||
| F | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 29322090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Aquatic Chronic 3 Eye Dam. 1 STOT RE 2 |
|||||||||
| REACH Registrations | Inactive | |||||||||
| NFPA 704 |
|
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide price More Price(47)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 338117 | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide 97% | 86608-70-0 | 5g | $46.4 | 2022-05-15 | Buy |
| TCI Chemical | D2056 | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) | 86608-70-0 | 5g | $107 | 2026-04-30 | Buy |
| TCI Chemical | D2056 | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide >97.0%(T) | 86608-70-0 | 25g | $312 | 2026-04-30 | Buy |
| TRC | TRC-D487548-50MG | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide | 86608-70-0 | 50mg | $65 | 2026-06-03 | Buy |
| TRC | TRC-D487548-500MG | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide | 86608-70-0 | 500mg | $103 | 2026-06-03 | Buy |
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Chemical Properties,Uses,Production
Chemical Properties
Pale yellow powder
Uses
suzuki reaction
Uses
Reactant for:
- Wittig olefination
- Preparationof ligands for histamine receptor binding with H3/H4 subtype selectivity
- Preparation of dual inhibitors of phosphodiesterase-4 and serotonin reuptake
reaction suitability
reaction type: C-C Bond Formation
Synthesis
In a 100ml four-necked flask equipped with reflux condenser tube (gas absorption device at the top), dropping funnel, stirrer, add 20ml of water, slowly add 24ml of concentrated sulfuric acid, cool down and then add 2-(2-hydroxyethyl)-1,3-dioxane, mix well and then add 20g of finely ground sodium bromide, heated to reflux for 1h. Cool down and then converted to decompression distillation device, reduce the pressure to 6mmHg, collect the crude product. 90-100 when the fraction, the crude product. The crude product was poured into a separatory funnel, 20 ml of water was added to wash out the aqueous layer, the organic phase was poured into another dry separatory funnel, washed with 10 ml of concentrated sulfuric acid to separate out the acid layer, and the organic phase was washed with 20 ml of water and 20 ml of saturated sodium bicarbonate solution, respectively, to obtain the pure product of 2-(1,3-dioxolan-2-yl)ethyltriphenylene. In a 100 ml four-necked flask equipped with a thermometer and a stirrer, 10 g of triphenylphosphine, 10.5 g of 2-(2-bromoethyl)-1,3-dioxane were added, and heated at 100C under the protection of N2 for 12 h. The reaction was then dispersed with ether and placed in dry ethyl acetate to form crystals by precipitating twice with ether. Recrystallization was carried out with a mixed solvent of ethyl acetate and ether to obtain the target compound 2-(1,3-dioxolan-2-yl)ethyltriphenylphosphonium bromide.
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20111 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14034 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21531 | 55 |
| JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 | andy@katchemical.com | CHINA | 59 | 55 |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29780 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569266 +86-17392581500 | 1015@dideu.com | China | 3861 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21135 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17339 | 58 |
| Shanghai UCHEM Inc. | +86-18930848214 +86-021-56762820 | sales@myuchem.com | China | 8898 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52693 | 58 |
View Lastest Price from 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-08-14 | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
|
$5.00-8.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
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2025-04-04 | 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
|
1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
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2024-03-28 | [2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide
86608-70-0
|
25kg | 98%-99% | PNP Biotech Co. Ltd |
-

- 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
- $5.00-8.00
- 99%
- Henan Fengda Chemical Co., Ltd
-

- 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide
86608-70-0
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
![[2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide pictures](/ProductImageEN/2022-09/Small/2e2d03b5-6b13-4109-b7e3-5faf71616ac3.jpg)
- [2-(1,3-Dioxolan-2-yl)ethyl]triphosphonium bromide
86608-70-0
- $0.00
- 98%-99%
- PNP Biotech Co. Ltd
2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium bromide Spectrum
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