2-Methyl-3-nitroanisole
- CAS No.
- 4837-88-1
- Chemical Name:
- 2-Methyl-3-nitroanisole
- Synonyms
- 1-METHOXY-2-METHYL-3-NITROBENZENE;2-Methyl-3-nit;BUTTPARK 52\11-31;2-METHYL-3-NITROANISOLE;3-nitro-2-methylanisole;2-Methy1-3-nitroanisole;2-METHOXY-6-NITROTOLUENE;6-METHOXY-2-NITROTOLUENE;Anisole, 2-methyl-3-nitro-;2-Methoxy-6-nitrotoluene>
- CBNumber:
- CB2309796
- Molecular Formula:
- C8H9NO3
- Molecular Weight:
- 167.16
- MDL Number:
- MFCD00007159
- MOL File:
- 4837-88-1.mol
- MSDS File:
- SDS
| Melting point | 54-56 °C (lit.) |
|---|---|
| Boiling point | 94-96°C 0,5mm |
| Density | 1.180±0.06 g/cm3(Predicted) |
| Flash point | >230 °F |
| storage temp. | Store at room temperature |
| solubility | soluble in Methanol |
| form | Powder or Crystalline Powder |
| color | Yellow to pale brown |
| BRN | 2328599 |
| InChI | InChI=1S/C8H9NO3/c1-6-7(9(10)11)4-3-5-8(6)12-2/h3-5H,1-2H3 |
| InChIKey | HQCZLEAGIOIIMC-UHFFFAOYSA-N |
| SMILES | C1(OC)=CC=CC([N+]([O-])=O)=C1C |
| CAS DataBase Reference | 4837-88-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-methoxy-2-methyl-3-nitro-(4837-88-1) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H301-H302 | |||||||||
| Precautionary statements | P264-P270-P301+P312+P330-P501-P301+P310a-P321-P405-P501a | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-36/37/38 | |||||||||
| Safety Statements | 22-36/37-36-26 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Harmful | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29093090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral | |||||||||
| NFPA 704 |
|
2-Methyl-3-nitroanisole price More Price(69)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 115428 | 2-Methyl-3-nitroanisole 99% | 4837-88-1 | 10g | $235 | 2026-04-30 | Buy |
| TCI Chemical | M1416 | 2-Methoxy-6-nitrotoluene >97.0%(GC) | 4837-88-1 | 5g | $70 | 2026-04-30 | Buy |
| TCI Chemical | M1416 | 2-Methoxy-6-nitrotoluene >97.0%(GC) | 4837-88-1 | 25g | $213 | 2026-04-30 | Buy |
| Usbiological | 283561 | 2-Methyl-3-nitroanisole Asreported | 4837-88-1 | 5g | $378 | 2026-06-03 | Buy |
| Usbiological | 283561 | 2-Methyl-3-nitroanisole Asreported | 4837-88-1 | 10g | $526 | 2026-06-03 | Buy |
2-Methyl-3-nitroanisole Chemical Properties, Uses, Production
Uses
2-Methyl-3-nitroanisole may be used in chemical synthesis studies.
Synthesis
A solution of dimethyl sulfoxide (80 mL) was added to a 500 mL three-necked vial at 25 . 29.7 g (0.32 mol) of methanol and 14 g (0.35 mol) of 60% sodium hydride were added slowly with stirring, the temperature was raised to 120 , and a solution of dimethyl sulfoxide containing 56.3 g (0.3 mol) of 2-methyl-3-nitrochlorobenzene was added dropwise. After dropwise reaction for 3 h. Decrease to 25 , add toluene (150 mL) and water (200 mL), partitioning, the aqueous layer was extracted with toluene (100 mL) twice, 50 mL each time, combined with the organic phase and washed with 5% aqueous sodium hydroxide (40 mL) once, partitioning. The organic layer was washed with water, the organic layer was dried with anhydrous sodium sulfate, filtered and evaporated. Get 2-methyl-3-nitro anisole.
Purification Methods
2-Methyl-5-nitroanisole crystallises from MeOH (yellow needles) and sublimes in vacuo. [Kuffner Monatsh Chem 91 1152 1960, Beilstein 6 I 178.]
2-Methyl-3-nitroanisole Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Z IntellecChem & Tech. Co., Ltd | 13179383568; 15050866711 | contact@zintellec.com | China | 317 | 58 |
| Suzhou Sino Rare Chemical Co., Ltd. | 0512-62857507 | sales@sinorarechem.com | China | 999 | 58 |
| Xi 'an billiton biological technology co., LTD | 029-88764766 | wang.yali@xatuochao.com | China | 521 | 58 |
| Taizhou Tongxin Bio-Tech Co., Ltd | 0523-86818997 18652728585 | sales@allyrise.com | China | 2986 | 60 |
| Shanghai Licheng Chemical Co., Ltd. | 021-67100011 15867680329 | 1241713527@qq.com | China | 85 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 |
View Latest Price from 2-Methyl-3-nitroanisole manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-02 | 2-methyl-3-nitroanisole
4837-88-1
|
$1.00-122.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
 |
2025-05-12 | 2-Methyl-3-nitroanisole
4837-88-1
|
1kg | 98% | 500 kgs | PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD | ||
 |
2023-08-15 | 2-Methyl-3-nitroanisole
4837-88-1
|
$30.00 | 1kg | 99.99% | 50000tons | Henan Bao Enluo International TradeCo.，LTD |
-
- 2-methyl-3-nitroanisole
4837-88-1
- $1.00-122.00
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 2-Methyl-3-nitroanisole
4837-88-1
- $0.00
- 98%
- PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD
-
- 2-Methyl-3-nitroanisole
4837-88-1
- $30.00
- 99.99%
- Henan Bao Enluo International TradeCo.，LTD
