ChemicalBook >> CAS DataBase List >>Carbonyltris(triphenylphosphine)rhodium(I) hydride
Carbonyltris(triphenylphosphine)rhodium(I) hydride
- CAS No.
- 17185-29-4
- Chemical Name:
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
- Synonyms
- CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE;HRh(CO)(PPh3)3;(betab-5-23)-rhodiu;Carbonyltris(triphen;HRh(CO)(PPh3)3 - RODRIDO;Carbonyltris(triphenylphosphine)rhodium;Carbonylhydridotris(triphenylphosphine);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
- CBNumber:
- CB2322445
- Molecular Formula:
- 3C18H15P.CO.HRh
- Molecular Weight:
- 918.8
- MDL Number:
- MFCD00151644
- MOL File:
- 17185-29-4.mol
- MSDS File:
- SDS
Last updated:2026-05-28 00:26:32
| Melting point | 150 °C (dec.) (lit.) |
|---|---|
| Density | 1.33 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| solubility | Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands |
| form | crystal |
| color | light yellow |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,9758 |
| Exposure limits |
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;; |
| InChIKey | CEKFIOLKXHVOKA-UHFFFAOYSA-N |
| SMILES | [RhH].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| CAS DataBase Reference | 17185-29-4(CAS DataBase Reference) |
| FDA UNII | 720P7594ZM |
| NIST Chemistry Reference | carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4) |
| EPA Substance Registry System | Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H413-H301+H311+H331 | |||||||||
| Precautionary statements | P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P403+P233-P405-P501 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 23/24/25 | |||||||||
| Safety Statements | 36/37/39-45-36/37 | |||||||||
| RIDADR | UN 2811 6.1/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 10-23 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| REACH Registrations | Inactive | |||||||||
| NFPA 704 |
|
Carbonyltris(triphenylphosphine)rhodium(I) hydride price More Price(57)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 225665 | Tris(triphenylphosphine)rhodium(I) carbonyl hydride 97% | 17185-29-4 | 500mg | $276 | 2026-04-30 | Buy |
| Sigma-Aldrich | 225665 | Tris(triphenylphosphine)rhodium(I) carbonyl hydride 97% | 17185-29-4 | 5g | $1930 | 2026-04-30 | Buy |
| TCI Chemical | C1383 | Carbonylhydridotris(triphenylphosphine)rhodium(I) | 17185-29-4 | 1g | $715 | 2026-04-30 | Buy |
| TCI Chemical | C1383 | Carbonylhydridotris(triphenylphosphine)rhodium(I) | 17185-29-4 | 5g | $2147 | 2026-04-30 | Buy |
| Strem Chemicals | 45-0900 | Hydridocarbonyltris(triphenylphosphine)rhodium(I), 98% 98% | 17185-29-4 | 250mg | $88 | 2026-04-30 | Buy |
Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties, Uses, Production
Chemical Properties
Carbonylhydrido-tris(triphenylphosphine)rhodium(I), carbonyl-tris(triphenylphosphine)rhodium(I) hydride, forms yellow crystals that are stable in air, mp 172 – 174℃ in a closed nitrogen-filled capillary. It is readily soluble in benzene, chloroform, and dichloromethane. In solution, one phosphine ligand is readily lost by dissociation to give a 16-electron complex that is an active catalyst for the hydrogenation of alkenes and for hydroformylation.
Uses
Carbonylhydrido-tris(triphenylphosphine)rhodium(I) is used in industry for the hydroformylation of alkenes by the low pressure oxo (LPO) process developed by Union Carbide, Davy Power Gas, and Johnson Matthey. The reaction takes place rapidly at 25℃ giving a product in which the ratio of n- to iso-aldehydes is very favorable (ca. 20 : 1), a much higher ratio than can be obtained with cobalt catalysts.
Uses
Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation
Production Methods
Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa).
reaction suitability
core: rhodium
reagent type: catalyst
Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials
Global Suppliers ( 254)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jiangsu Boquan Biotechnology Co., Ltd. | 19351501195 | 1464906612@qq.com | China | 494 | 58 |
| Yunnan Boquan Metal Materials Co., Ltd | 18251603297 15096626657 | 1464906612@qq.com | China | 644 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Latest Price from Carbonyltris(triphenylphosphine)rhodium(I) hydride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | carbon monoxide; rhodium; triphenylphosphane
17185-29-4
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2020-11-19 | Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
|
$30.00 | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
 |
2020-02-14 | Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
|
$7.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- carbon monoxide; rhodium; triphenylphosphane
17185-29-4
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
- $30.00
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
- $7.00
- 99%
- Career Henan Chemical Co
17185-29-4 (Carbonyltris(triphenylphosphine)rhodium(I) hydride) Related Search:
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1of4
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE
(betab-5-23)-rhodiu
carbonylhydrotris(triphenylphosphine)rhodium
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9%
CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I)
Hydridocarbonyltris(triphenylphosphine)rhodium(I),98%
Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-
tris(triphenylphosphine)rhodium carbonyl hydride
Carbonyltris(triphenylphosphine)rhodium
Carbonylhydrotris(triphenylphosphin)rhodium
Carbonylhydridotris tris (triphenylphosphine) rhodiuM (I)
Rhodium monocarbonyl hydrogen tris(triphenylphosphine)
trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
Carbonylhydridotris(triphenylphosphine)
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRI
Efficient hydroformylation catalyst. Unstable in solution in presence of air.
rhodium(I) tris(triphenylphosphine) carbonyl hydride
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2%
Carbonyl hydridotris(triphenylphosphine) rhodium
Hydridocarbonyltris(triphenylphosphine)rhodium
Tris(triphenylphosphine)carbonylrhodium hydride
Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbonyl hydride
Carbonyltris(triphenylphosphine)rhodium(I)hydride,97%
Carbonylhydridotris(triphenylphosphine)rhodium/ 98+%
Tris(triphenylphosphine)rhodium(I) carbonyl hydride,Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbony
Carbonyltris(triphen
Tris(triphenylphosphine)rhodium(I) carbonyl hydride ,98%
Carbonyl triphenylphosphine rhodiuM hydride
Carbonyltris(triphenylphosphine)rhodiuM(I)
Carbonyltris(triphenylphosphine)rhodium(I) Hydride
Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
Tris(triphenylphosphine)rhodium(Ⅰ) carbonyl hydride
RHODIUM(I) HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% min
Carbonylhydridotris(triphenylphosphane)rhodium(I) “RODRIDO”
Carbonyltris(triphenylphosphine)rhodium(I) hydride ISO 9001：2015 REACH
HRh(CO)(PPh3)3 - RODRIDO
Carbonylhydridotris(triphenylphosphine)rhodium(I)[RhH(CO)(PPh3)3
HRh(CO)(PPh3)3
Trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]
Carbonylhydridotris(triphenylphosphine)rhodium(I) , Tris(triphenylphosphine)rhodium(I) carbonyl hydride
CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE
17185-29-4
C6H53P3RhCOH
C55H46O1P3Rh1
RhHCOPPh33
RhHCOPC6H533
C55H46OP3Rh
C54H46P3Rh
3C18H15PCOHRh
Transition Metal Compounds
Catalysts for Organic Synthesis
Rh (Rhodium) Compounds
Classes of Metal Compounds
