(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
- CAS No.
- 27032-63-9
- Chemical Name:
- (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
- Synonyms
- 5-CHLORO-2-HYDRAZINOPYRIDINE;PYRIDINE,5-CHLORO-2-HYDRAZINYL-;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE;5-chloro-2-hydrazono-1,2-dihydropyridine;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 5193-03-3
- CBNumber:
- CB2349930
- Molecular Formula:
- C5H6ClN3
- Molecular Weight:
- 143.57
- MDL Number:
- MFCD07786313
- MOL File:
- 27032-63-9.mol
Melting point | 127-128 |
---|---|
Boiling point | 221.6±50.0 °C(Predicted) |
Density | 1.43±0.1 g/cm3(Predicted) |
storage temp. | Keep in dark place,Inert atmosphere,Store in freezer, under -20°C |
form | solid |
pka | 9.00±0.70(Predicted) |
color | Beige |
InChI | InChI=1S/C5H6ClN3/c6-4-1-2-5(9-7)8-3-4/h1-3H,7H2,(H,8,9) |
InChIKey | UXJYFOOFLZGBEK-UHFFFAOYSA-N |
SMILES | C1(NN)=NC=C(Cl)C=C1 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
Hazard Codes | Xi |
HazardClass | IRRITANT |
HS Code | 2933399990 |
(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE price More Price(33)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | C349405 | 5-Chloro-2-hydrazinopyridine | 27032-63-9 | 100mg | $45 | 2021-12-16 | Buy |
TRC | C349405 | 5-Chloro-2-hydrazinopyridine | 27032-63-9 | 500mg | $65 | 2021-12-16 | Buy |
Biosynth Carbosynth | FC139335 | 5-Chloro-2-hydrazinylpyridine | 27032-63-9 | 2g | $57 | 2021-12-16 | Buy |
Ark Pharm | AK126165 | 5-Chloro-2-hydrazinylpyridine 97% | 27032-63-9 | 1g | $18 | 2021-12-16 | Buy |
Matrix Scientific | 047249 | 5-Chloro-2-hydrazinopyridine >95% | 27032-63-9 | 1g | $24 | 2021-12-16 | Buy |
(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Chemical Properties,Uses,Production
Synthesis

16110-09-1

27032-63-9
General procedure for the synthesis of 5-chloro-2-hydrazinopyridine from 2,5-dichloropyridine: A mixed solution of 2,5-dichloropyridine (7.4 g, 50.0 mmol) and hydrazine hydrate (101 mL, 3250 mmol) in pyridine (100 mL) was heated and refluxed for 6 hours. Upon completion of the reaction, the reaction solution was concentrated to dryness in vacuum. The resulting residue was dissolved in dichloromethane (500 mL) and washed sequentially with 1N aqueous sodium hydroxide (500 mL) and water (3 x 500 mL). The organic layer was dried with anhydrous magnesium sulfate, filtered and concentrated to dryness in vacuo to afford 5-chloro-2-hydrazinopyridine (2.95 g, 20.55 mmol, 41% yield) as a light yellow solid.1H NMR (300 MHz, DMSO-d6) δ 7.97 (d, J = 2.5 Hz, 1H), 7.67 (s, 1H), 7.50 (dd, J = 9.0, 2.6 Hz, 1H), 6.73 (dd, J = 9.0, 0.6 Hz, 1H), 4.17 (s, 2H); MS (ES+) m/z 144.2 ([M+H]+).
References
[1] Journal of the American Chemical Society, 2011, vol. 133, # 17, p. 6780 - 6790
[2] Patent: US2003/187014, 2003, A1
[3] Patent: WO2015/134998, 2015, A1. Location in patent: Page/Page column 147
[4] Patent: US5750550, 1998, A
[5] Patent: US4997835, 1991, A
(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29800 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
Blocksynth Pharmaceutical Technology Co.,Ltd | 0086-19817745290; +8619817745290 | bd@blocksynth.com | China | 5661 | 58 |
Hefei Hirisun Pharmatech Co., Ltd | +8615056975894 | shawn@hirisunpharm.com | CHINA | 9911 | 58 |
Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19987 | 58 |
Nanjing Hengbei Chemicals Co., Ltd. | +86-25-58393656 | sales@hengbeichem.cn | China | 6854 | 58 |
LEAP CHEM CO., LTD. | +86-852-30606658 19957148339; | market18@leapchem.com | China | 24727 | 58 |
Wuhan Topule Biopharmaceutical Co., Ltd | +8618327326525 | masar@topule.com | China | 8467 | 58 |
Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33338 | 58 |
View Lastest Price from (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2020-01-03 | (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
27032-63-9
|
US $1.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
27032-63-9
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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