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(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE

CAS No.
27032-63-9
Chemical Name:
(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
Synonyms
5-CHLORO-2-HYDRAZINOPYRIDINE;PYRIDINE,5-CHLORO-2-HYDRAZINYL-;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE;5-chloro-2-hydrazono-1,2-dihydropyridine;(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 5193-03-3
CBNumber:
CB2349930
Molecular Formula:
C5H6ClN3
Molecular Weight:
143.57
MDL Number:
MFCD07786313
MOL File:
27032-63-9.mol
Last updated:2025-07-24 18:13:47

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Properties

Melting point 127-128
Boiling point 221.6±50.0 °C(Predicted)
Density 1.43±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form solid
pka 9.00±0.70(Predicted)
color Beige
InChI InChI=1S/C5H6ClN3/c6-4-1-2-5(9-7)8-3-4/h1-3H,7H2,(H,8,9)
InChIKey UXJYFOOFLZGBEK-UHFFFAOYSA-N
SMILES C1(NN)=NC=C(Cl)C=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
HazardClass  IRRITANT
HS Code  2933399990

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC C349405 5-Chloro-2-hydrazinopyridine 27032-63-9 100mg $45 2021-12-16 Buy
TRC C349405 5-Chloro-2-hydrazinopyridine 27032-63-9 500mg $65 2021-12-16 Buy
Biosynth Carbosynth FC139335 5-Chloro-2-hydrazinylpyridine 27032-63-9 2g $57 2021-12-16 Buy
Ark Pharm AK126165 5-Chloro-2-hydrazinylpyridine 97% 27032-63-9 1g $18 2021-12-16 Buy
Matrix Scientific 047249 5-Chloro-2-hydrazinopyridine >95% 27032-63-9 1g $24 2021-12-16 Buy
Product number Packaging Price Buy
C349405 100mg $45 Buy
C349405 500mg $65 Buy
FC139335 2g $57 Buy
AK126165 1g $18 Buy
047249 1g $24 Buy

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Chemical Properties,Uses,Production

Synthesis

2,5-Dichloropyridine

16110-09-1

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE

27032-63-9

General procedure for the synthesis of 5-chloro-2-hydrazinopyridine from 2,5-dichloropyridine: A mixed solution of 2,5-dichloropyridine (7.4 g, 50.0 mmol) and hydrazine hydrate (101 mL, 3250 mmol) in pyridine (100 mL) was heated and refluxed for 6 hours. Upon completion of the reaction, the reaction solution was concentrated to dryness in vacuum. The resulting residue was dissolved in dichloromethane (500 mL) and washed sequentially with 1N aqueous sodium hydroxide (500 mL) and water (3 x 500 mL). The organic layer was dried with anhydrous magnesium sulfate, filtered and concentrated to dryness in vacuo to afford 5-chloro-2-hydrazinopyridine (2.95 g, 20.55 mmol, 41% yield) as a light yellow solid.1H NMR (300 MHz, DMSO-d6) δ 7.97 (d, J = 2.5 Hz, 1H), 7.67 (s, 1H), 7.50 (dd, J = 9.0, 2.6 Hz, 1H), 6.73 (dd, J = 9.0, 0.6 Hz, 1H), 4.17 (s, 2H); MS (ES+) m/z 144.2 ([M+H]+).

References

[1] Journal of the American Chemical Society, 2011, vol. 133, # 17, p. 6780 - 6790
[2] Patent: US2003/187014, 2003, A1
[3] Patent: WO2015/134998, 2015, A1. Location in patent: Page/Page column 147
[4] Patent: US5750550, 1998, A
[5] Patent: US4997835, 1991, A

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 104)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
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career henan chemical co
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Blocksynth Pharmaceutical Technology Co.,Ltd
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Labnetwork lnc.
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LEAP CHEM CO., LTD.
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Wuhan Topule Biopharmaceutical Co., Ltd
+8618327326525 masar@topule.com China 8467 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+86-18621343501; +undefined18621343501 product@acmec-e.com China 33338 58

View Lastest Price from (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE pictures 2020-01-03 (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE
27032-63-9
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co

(5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE Spectrum

5-CHLORO-2-HYDRAZINOPYRIDINE (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE (5-CHLORO-PYRIDIN-2-YL)-HYDRAZINE 5193-03-3 PYRIDINE,5-CHLORO-2-HYDRAZINYL- 5-chloro-2-hydrazono-1,2-dihydropyridine 27032-63-9 5193-3-3