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[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)

CAS No.
18498-01-6
Chemical Name:
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
Synonyms
ethane]dichlorocobalt(II);[1,2-BIs(diphenylphosphino);bis(1,2-diphenylphosphino)ethane]cobalt(II);Dichloro[ethylenebis[diphenylphosphine]]cobalt;(1,2-bis(diphenylphosphino)ethane)-dichlorocobalt;1,2-[Bis(diphenylphosphino)ethane]cobaltdichloride;Dichloro[Ethylenebis[Diphenylphosphine]]Cobalt(II);[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ);[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II);[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROCOBALT(II)
CBNumber:
CB2473390
Molecular Formula:
C26H26Cl2CoP2
Molecular Weight:
530.27
MDL Number:
MFCD00134173
MOL File:
18498-01-6.mol
MSDS File:
SDS
Last updated:2026-05-28 00:38:39

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Properties

Melting point 260 °C (dec.)(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color green
Water Solubility Insoluble in water.
Sensitive Hygroscopic
InChI 1S/C26H24P2.2ClH.Co/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChIKey SYTWXWRJCLAZFP-UHFFFAOYSA-L
SMILES Cl[Co]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
UNSPSC Code 12352300
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H312-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501a
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  26-37/39
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 1

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 360147 [1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II) 18498-01-6 1g $59 2023-01-07 Buy
Strem Chemicals 27-0478 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II), min. 97% min.97% 18498-01-6 1g $39 2026-04-30 Buy
Strem Chemicals 27-0478 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II), min. 97% min.97% 18498-01-6 5g $154 2026-04-30 Buy
Activate Scientific AS225935 [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) 95% 18498-01-6 1g $109 2026-06-04 Buy
Activate Scientific AS225935 [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) 95% 18498-01-6 5g $384 2026-06-04 Buy
Product number Packaging Price Buy
360147 1g $59 Buy
27-0478 1g $39 Buy
27-0478 5g $154 Buy
AS225935 1g $109 Buy
AS225935 5g $384 Buy

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Chemical Properties, Uses, Production

Reactions

  1. Catalyst used for the hydrovinylation of styrene.
  2. Cobalt-catalyzed hydroalkylation of [60] fullerene with active alkyl bromides.
  3. Cobalt-catalyzed 1,4-addition of organoboronic acids to activated alkenes. 
Reactions of 18498-01-6

Uses

Dichloro[bis(1,2-diphenylphosphino)ethane]cobalt(II) is used as a catalyst for regio- and stereoselective intermolecular enzyme coupling, cross-coupling reactions of alkyl halides with aryl Grignard reagents, hydrovinylation of styrene, tandem radical cyclization and cross-coupling, dimethylation, hydrodechlorination and addition reactions.

reaction suitability

core: cobalt
reagent type: catalyst

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Preparation Products And Raw materials

Raw materials

Preparation Products

[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) Suppliers

Global Suppliers ( 71)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Hunan Hui Bai Shi Biotechnology Co., Ltd. 0731-85526065 13308475853 ivy@hnhbsj.com China 7236 62
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58

View Latest Price from [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II) pictures 2026-09-14 [1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II)
18498-01-6
$101.00-336.00 25g 0.98 25kg Shanghai UCHEM Inc.
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) pictures 2022-09-24 [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
18498-01-6
1kg 99% 1000kg henan kanbei chemical co.,ltd
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) pictures 2020-02-06 [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II)
18498-01-6
$3.00 1KG 98% 100KG Career Henan Chemical Co
1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),Min.97% 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II),97% (DPPE)CoCl2 Dichloro[ethylenebis[diphenylphosphine]]cobalt [1,2-BIs(diphenylphosphino) ethane]dichlorocobalt(II) (1,2-bis(diphenylphosphino)ethane)-dichlorocobalt [1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) [1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(Ⅱ) [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROCOBALT(II) [1,2-bis(diphenylphosphino)ethane]cobalt(II) chloride 1,2-[Bis(diphenylphosphino)ethane]cobaltdichloride 1,2-Bis(diphenylphosphino)ethanedichlorocobalt(II), min. 97% Dichloro[Ethylenebis[Diphenylphosphine]]Cobalt(II) dichlorocobalt,2-diphenylphosphanylethyl(diphenyl)phosphane bis(1,2-diphenylphosphino)ethane]cobalt(II) 18498-01-6 C6H52PCH2CH2PC6H52CoCl2 C26H24Cl2CoP2 Catalysis and Inorganic Chemistry Co Catalysis and Inorganic Chemistry Chemical Synthesis Cobalt API intermediates metal-phosphine complex