ChemicalBook >> CAS DataBase List >>(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate structure

CAS No.: 213343-65-8

Chemical Name:: (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate

Synonyms: (S,S)-ME-BPE-RH;[((SS)-Me-BPE)Rh(COD)]BF4;1,2-Bis((2S,5S)-2,5-dimethyL;(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,97%

CBNumber:: CB2485872

Molecular Formula:: C22H40BF4P2Rh-

Molecular Weight:: 556.21

MDL Number:: MFCD32853739

MOL File:: 213343-65-8.mol

MSDS File:: SDS

Last updated:2026-09-12 18:51:19

Request For Quotation

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate Properties

Melting point	152.2-156.3 °C
storage temp.	2-8°C, protect from light, stored under nitrogen
form	Crystalline Powder
color	Orange to red to brown
Sensitive	air sensitive
InChIKey	CVUPEPGZCZHSOF-ASDDUFFSSA-N
SMILES	[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2CCP3[C@@H](C)CC[C@@H]3C
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs	Respiratory system
PPE	dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	22-24/25-26
WGK Germany	3
Storage Class	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate price More Price(19)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	675547	1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate	213343-65-8	100mg	$163	2026-04-30	Buy
Sigma-Aldrich	675547	1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate	213343-65-8	500mg	$581	2026-04-30	Buy
Strem Chemicals	45-0169	(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 98+%	213343-65-8	100mg	$130	2026-04-30	Buy
Strem Chemicals	45-0169	(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 98+%	213343-65-8	500mg	$548	2026-04-30	Buy
Strem Chemicals	45-0169	(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh 98+%	213343-65-8	2g	$1778	2026-04-30	Buy

Product number	Packaging	Price	Buy
675547	100mg	$163	Buy
675547	500mg	$581	Buy
45-0169	100mg	$130	Buy
45-0169	500mg	$548	Buy
45-0169	2g	$1778	Buy

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate Chemical Properties, Uses, Production

Reaction

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 213343-65-8

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

Asymmetric hydrogenation

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate Suppliers

Global Suppliers ( 37)

Supplier	Tel	Email	Country	ProdList	Advantage
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
Beijing HwrkChemical Technology Co., Ltd	89508211 18501085097	sales.bj@hwrkchemical.com	China	9407	55
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Thermo Fisher Scientific	800-810-5118	cnchemical@thermofisher.com	China	17752	75
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	025-66028182 17714375163	yftan@aikonchem.com	China	16674	50
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51389	80
Shanghai Chiral bio-compound co., Ltd.	021-5068 3667/17749785980/1029026415; 17749785980	1029026415@qq.com	China	4501	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29626	60

Supplier	Advantage
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
Beijing HwrkChemical Technology Co., Ltd	55
Energy Chemical	61
Thermo Fisher Scientific	75
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	50
Sigma-Aldrich	80
Shanghai Chiral bio-compound co., Ltd.	58
Capot Chemical Co.,Ltd.	60

213343-65-8 ((-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate) Related Search:

(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane 1,3-Cyclooctadiene (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate

1,2-Bis(diethylphosphino)ethane

1of2

(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97% (-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh (à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH (2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane 1,2-Bis((2S,5S)-2,5-dimethyL (+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,97% (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate [((SS)-Me-BPE)Rh(COD)]BF4 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate , (S,S)-Me-BPE-Rh BF4 (S,S)-ME-BPE-RH (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium (I) tetrafluoroborate 213343-65-8 RhC8H12C14H28P2BF4 C22H40BF4P2Rh Hydrogenation New Products for Chemical Synthesis May/June 2007 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Catalysts, Ligands, and Reagents DuPhos/BPE Privileged Ligands and Complexes organometallic complex