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2-Methyl-4-methoxybenzenamine

2-Methyl-4-methoxybenzenamine Structure
2-Methyl-4-methoxybenzenamine structure
CAS No.
102-50-1
Chemical Name:
2-Methyl-4-methoxybenzenamine
Synonyms
4-METHOXY-2-METHYLANILINE;Benzenamine, 4-methoxy-2-methyl-;2-Methoxy-3-methylaniline;4-Methoxy-2-methylbenzenamine;AKOS 91136;NCI-C02993;M-CRESIDINE;N-cresidine;meta-cresidine;2-methyl-p-anisidin
CBNumber:
CB2712327
Molecular Formula:
C8H11NO
Molecular Weight:
137.18
MDL Number:
MFCD00007735
MOL File:
102-50-1.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:45
Product description Number Pack Size Price
4-Methoxy-2-methylaniline 98% M15001 5g $79.3
4-Methoxy-2-methylaniline 98% M15001 25g $108
4-Methoxy-2-methylaniline >99.0%(GC)(T) M1474 25g $100
4-Methoxy-2-methylaniline >99.0%(GC)(T) M1474 500g $892
4-Methoxy-2-methylaniline M263620 25g $185
More product size
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2-Methyl-4-methoxybenzenamine Properties

Melting point 13-14 °C(lit.)
Boiling point 248-249 °C(lit.)
Density 1.065 g/mL at 25 °C(lit.)
refractive index n20/D 1.565(lit.)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Acetonitrile (Slightly), Chloroform (Slightly), DMSO, Methanol (Slightly)
form Oil
pka 5.05±0.10(Predicted)
color Light Brown to Very Dark Red
Water Solubility insoluble, <0.1 g/100 mL at 21.5 ºC
BRN 774727
Stability Stable. May be light or air-sensitive. Combustible. Incompatible with acids, strong oxidizing agents.
InChIKey CDGNLUSBENXDGG-UHFFFAOYSA-N
Toxicology and Carcinogenesis Bioassay of m-Cresidine for Possible Carcinogenicity (CASRN 102-50-1)
CAS DataBase Reference 102-50-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII F0E8Y56GUK
NIST Chemistry Reference Benzenamine, 4-methoxy-2-methyl-(102-50-1)
IARC 3 (Vol. 27, Sup 7) 1987
EPA Substance Registry System m-Cresidine (102-50-1)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn,T
Risk Statements  36/37/38-40-45
Safety Statements  26-36/37/39-53-45
RIDADR  2810
WGK Germany  3
RTECS  BZ6730000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29222990
Hazardous Substances Data 102-50-1(Hazardous Substances Data)
NFPA 704
1
2 0

2-Methyl-4-methoxybenzenamine price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich M15001 4-Methoxy-2-methylaniline 98% 102-50-1 5g $79.3 2025-07-31 Buy
Sigma-Aldrich M15001 4-Methoxy-2-methylaniline 98% 102-50-1 25g $108 2023-06-20 Buy
TCI Chemical M1474 4-Methoxy-2-methylaniline >99.0%(GC)(T) 102-50-1 25g $100 2025-07-31 Buy
TCI Chemical M1474 4-Methoxy-2-methylaniline >99.0%(GC)(T) 102-50-1 500g $892 2025-07-31 Buy
TRC M263620 4-Methoxy-2-methylaniline 102-50-1 25g $185 2021-12-16 Buy
Product number Packaging Price Buy
M15001 5g $79.3 Buy
M15001 25g $108 Buy
M1474 25g $100 Buy
M1474 500g $892 Buy
M263620 25g $185 Buy

2-Methyl-4-methoxybenzenamine Chemical Properties,Uses,Production

Chemical Properties

brick red crystals or liquid

Uses

4-Methoxy-2-methylaniline is a reagent used in organic synthesis of more complex compounds that have a more specific function. For example, enzyme inhibitors.

Definition

ChEBI: Meta-Cresidine is a member of methoxybenzenes.

General Description

Crystals or brick red liquid.

Air & Water Reactions

Sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

2-Methyl-4-methoxybenzenamine neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. Reacts with oxidizing agents .

Health Hazard

ACUTE/CHRONIC HAZARDS: 2-Methyl-4-methoxybenzenamine is a local irritant. When heated to decomposition it emits toxic fumes of NOx. 2-Methyl-4-methoxybenzenamine is an experimental animal carcinogen.

Fire Hazard

2-Methyl-4-methoxybenzenamine is probably combustible.

Safety Profile

Suspected carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.

Synthesis

3-Methyl-4-nitroanisole

5367-32-8

2-Methyl-4-methoxybenzenamine

102-50-1

GENERAL PROCEDURE: 3-methyl-4-nitroanisole (1.0 mmol), B2(OH)4 (5.0 eq., 5.0 mmol) and H2O (3.0 mL) were added to a 10 mL reaction tube. The reaction mixture was stirred at 80 °C for 8 hours. After completion of the reaction (monitored by TLC), the mixture was cooled to room temperature and extracted with ethyl acetate (3 x 20 mL). The organic phases were combined, dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure. The residue was purified by silica gel column chromatography to give 2-methyl-4-methoxyaniline.

References

[1] Analytical Chemistry, 1992, vol. 64, # 8, p. 837 - 842
[2] ChemCatChem, 2017, vol. 9, # 16, p. 3236 - 3244
[3] Synlett, 2018, vol. 29, # 13, p. 1765 - 1768
[4] Tetrahedron, 2017, vol. 73, # 27-28, p. 3898 - 3904
[5] Helvetica Chimica Acta, 1924, vol. 7, p. 698

2-Methyl-4-methoxybenzenamine synthesis

5367-32-8
102-50-1
Synthesis of 2-Methyl-4-methoxybenzenamine from 3-Methyl-4-nitroanisole

2-Methyl-4-methoxybenzenamine Preparation Products And Raw materials

Raw materials

3-Methyl-4-nitrophenol Hydrazinium hydroxide solution Sodium Palladium Sodium Methoxide
Hydrochloric acid Sodium bicarbonate Methanol Iron Dimethyl sulfate

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Preparation Products

NAPHTHOL AS-LT 2-Hydroxy-N-(4-methoxy-2-methylphenyl)-11H-benzo[a]carbazole-3-carboxamide Methoxymethyldiphenylamine 1H-Indazol-5-ol 2-Bromo-5-methoxytoluene
5-METHOXY-1H-INDAZOLE NAPHTHOL AS-LT 2-Hydroxy-N-(4-methoxy-2-methylphenyl)-11H-benzo[a]carbazole-3-carboxamide

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2-Methyl-4-methoxybenzenamine Suppliers

Global( 283)Suppliers
Supplier Tel Email Country ProdList Advantage
Taixing Foreign Trade Nanjing Co., Ltd.
+86-025-83346564; +8613182976929 sales@tx-chem.com China 123 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615350571055 Sibel@chuanghaibio.com China 8772 58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		+8613288715578 sales@sichuanzyyt.com China 12247 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20175 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29734 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29852 58
Win-Win Chemical CO., Limited 		0086-577-64498589 sales@win-winchemical.com CHINA 998 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Supplier Advantage
Taixing Foreign Trade Nanjing Co., Ltd.
58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Win-Win Chemical CO., Limited 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Hubei Jusheng Technology Co.,Ltd. 		58

View Lastest Price from 2-Methyl-4-methoxybenzenamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methyl-4-methoxybenzenamine pictures 2025-10-16 2-Methyl-4-methoxybenzenamine
102-50-1
 US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
2-Methyl-4-methoxybenzenamine pictures 2025-10-11 2-Methyl-4-methoxybenzenamine
102-50-1
 US $1.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
2-Methyl-4-methoxybenzenamine pictures 2025-09-25 2-Methyl-4-methoxybenzenamine
102-50-1
 US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd

2-Methyl-4-methoxybenzenamine Spectrum

2-Methyl-4-methoxybenzenamine(102-50-1)MS2-Methyl-4-methoxybenzenamine(102-50-1)1HNMR2-Methyl-4-methoxybenzenamine(102-50-1)13CNMR2-Methyl-4-methoxybenzenamine(102-50-1)IR1

102-50-1(2-Methyl-4-methoxybenzenamine)Related Search:

6-NITROPIPERONYL ALCOHOL 2-Methyl-4-methoxybenzenamine 6-Nitroveratraldehyde 4-METHOXY-2-METHYLPHENYL ISOCYANATE ETHYL 4,5-DIMETHOXY-2-NITROBENZOATE
D-ribo-Hexanoic acid, 3-deoxy-, γ-lactone 2,3-DIMETHYL-4-NITROANISOLE Methyl 2-amino-3,4,5-trimethoxybenzoate 4,5-DIMETHOXY-2-NITROBENZYL ALCOHOL BRUCINE SULFATE
6-NITROPIPERONAL Methyl 4,5-dimethoxy-2-nitrobenzoate Methyl 2-amino-4,5-dimethoxybenzoate 2-Amino-5-methoxybenzoic acid Methyl 2-nitro-3,4,5-trimethoxybenzoate
2-Amino-4,5-dimethoxybenzoic acid 3-Methyl-4-nitroanisole 2-Methoxy-5-methylaniline

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AKOS 91136 6-AMINO-3-METHOXYTOLUENE 4-METHOXY-2-METHYLANILINE 4-METHOXY-O-TOLUIDINE 3-METHYL-4-AMINOANISOLE 2-METHYL-P-ANISIDINE 2-METHYL-4-METHOXYBENZENAMINE 1-AMINO-4-METHOXY-2-METHYLBENZENE M-CRESIDINE 1-Amino-4-methoxy-2-methylbenzene m-Cresidine 4-Methoxy-o-toluidine 2-Amino-5-methoxytoluene, 4-Amino-3-methylanisole, 2-Methyl-p-anisidine, 4-Methoxy-o-toluidine 4-Methoxy-2-Methylaniline, 98% 5GR 4-AMino-3-Methylanisole[4-Methoxy-2-Methylaniline] 4-Methoxy-2-Methylaniline , 98.0%(GC&T 4-Methoxy-2-methyl-phenylamine Benzenamine, 4-methoxy-2-methyl- 4-Amino-3-methylanisole 2-Methyl-4-methoxybenzemine 4-Methoxy-2-methylaniline (m-Cresidine) 2-Amino-5-Methoxytoluene 4-METHOXY-2-METHYLANILINE 98.5% 2-Amino-5-methoxytoluene, 4-Amino-3-methylanisole 2-Methyl-p-anisidine, m-Cresidine 2-methyl-p-anisidin 4-methoxy-2-methyl-benzenamin 4-Methoxy-2-methylbenzenamine NCI-C02993 p-Anisidine, 2-methyl- 2-Methyl-4-Methoxybenzenamine 2-Amino-5-Methoxytoluene 5-methoxy-2-methylbenzenamine meta-cresidine 2-Methyl-p-anisidine(NH2=1) N-[1,2-Dihydroxy-2-(prop-2-enoylamino)ethyl]prop-2-enamide 4-Methoxy-2-methylaniline ,98% N-cresidine 2-Methoxy-3-methylaniline 2-Methyl-4-emthoxyaniline 4-Methoxy-2-methylaniline> 2-Methyl-4-methoxybenzenamine ISO 9001：2015 REACH 2-Methyl-4-(methyloxy)aniline 4-Methoxy-2-methylaniline, ≥ 98.0% 4-Amino-m-metylanisole 102-50-1 CH3OC6H3CH3NH2 Organic Building Blocks Nitrogen Compounds Amines Building Blocks C8 Amines and Anilines Intermediates of Dyes and Pigments Amines Building Blocks C8 to C9 Chemical Synthesis Nitrogen Compounds Organic Building Blocks