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4-AMINO-3-BROMO-5-NITROPYRIDINE

CAS No.
89284-05-9
Chemical Name:
4-AMINO-3-BROMO-5-NITROPYRIDINE
Synonyms
4-AMino-3-broMo-5-nitropy...;3-bromo-5-nitro-4-pyridinamine;4-AMino-3-nitro-5-broMopyridine;4-AMINO-3-BROMO-5-NITROPYRIDINE;3-Bromo-4-amino-5-nitropyridine;4-Pyridinamine, 3-bromo-5-nitro-;4-Amino-3-bromo-5-nitropyridine 97%;4-AMINO-3-BROMO-5-NITROPYRIDINE ISO 9001:2015 REACH
CBNumber:
CB31076135
Molecular Formula:
C5H4BrN3O2
Molecular Weight:
218.01
MDL Number:
MFCD01646057
MOL File:
89284-05-9.mol
Last updated:2025-07-24 18:13:53

4-AMINO-3-BROMO-5-NITROPYRIDINE Properties

Melting point 174-175℃
Boiling point 346.5±37.0 °C(Predicted)
Density 1.929
refractive index 1.682
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form claggy powder
pka 2.87±0.24(Predicted)
color Amber/gold
InChI InChI=1S/C5H4BrN3O2/c6-3-1-8-2-4(5(3)7)9(10)11/h1-2H,(H2,7,8)
InChIKey UXDLBXRMNSJEPB-UHFFFAOYSA-N
SMILES C1=NC=C([N+]([O-])=O)C(N)=C1Br

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P280-P305+P351+P338-P310
HS Code  2933399990

4-AMINO-3-BROMO-5-NITROPYRIDINE price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC A602458 4-Amino-3-bromo-5-nitropyridine 89284-05-9 1g $75 2021-12-16 Buy
SynQuest Laboratories 4H55-9-02 4-Amino-3-bromo-5-nitropyridine 89284-05-9 1g $75 2021-12-16 Buy
AK Scientific W9221 3-Bromo-5-nitropyridin-4-amine 89284-05-9 5g $78 2021-12-16 Buy
Biosynth Carbosynth FB139502 3-Bromo-5-nitropyridin-4-amine 89284-05-9 5G $110 2021-12-16 Buy
American Custom Chemicals Corporation HCH0037552 4-AMINO-3-BROMO-5-NITROPYRIDINE 95.00% 89284-05-9 50MG $117.6 2021-12-16 Buy
Product number Packaging Price Buy
A602458 1g $75 Buy
4H55-9-02 1g $75 Buy
W9221 5g $78 Buy
FB139502 5G $110 Buy
HCH0037552 50MG $117.6 Buy

4-AMINO-3-BROMO-5-NITROPYRIDINE Chemical Properties,Uses,Production

Synthesis

4-Amino-3-nitropyridine

1681-37-4

4-AMINO-3-BROMO-5-NITROPYRIDINE

89284-05-9

The general procedure for the synthesis of 4-amino-3-bromo-5-nitropyridine from 4-amino-3-nitropyridine was as follows: 3-nitropyridin-4-amine (LXVIII) (10 g, 71.88 mmol) was mixed with acetic acid (100 ml) in a sealed tube, followed by the addition of sodium acetate (NaOAc) (29.50 g, 359 mmol), and the slow dropwise addition of bromine ( 4.43 ml, 86.3 mmol). The sealed tube was heated at 100 °C for overnight reaction under stirring conditions. Upon completion of the reaction, the mixture was concentrated under vacuum and the resulting solid was dissolved in water, alkalized with saturated aqueous sodium bicarbonate (NaHCO3) and extracted with dichloromethane (DCM). The organic phases were combined, dried and concentrated to give 3-bromo-5-nitropyridin-4-amine (LXIX) as a yellow solid (13.7 g, 62.8 mmol, 87% yield). The product was identified by 1H NMR (DMSO-d6, 500 MHz): δ 8.58 (s, 1H), 9.19 (s, 1H); ESIMS analysis showed the molecular ion peak m/z 218.1 (M + H), corresponding to the molecular formula C5H4BrN3O2.

References

[1] Patent: US2013/296302, 2013, A1. Location in patent: Paragraph 0563
[2] Patent: WO2011/84486, 2011, A1. Location in patent: Page/Page column 119-120
[3] Patent: US2013/267495, 2013, A1. Location in patent: Paragraph 0460-0461
[4] Patent: EP2464232, 2015, B1. Location in patent: Paragraph 0087; 0088
[5] Patent: US2016/68548, 2016, A1. Location in patent: Paragraph 0852

4-AMINO-3-BROMO-5-NITROPYRIDINE Preparation Products And Raw materials

Global( 125)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+8613336195806 sales@capot.com China 29734 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Nanjing Dolon Biotechnology Co.,Ltd.
18905173768 52513593@qq.com CHINA 2972 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5906 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29800 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-87569262 +86-15003564040 1087@dideu.com China 3971 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10035 58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
+8613580539051 joe@yuhengpharm.com CHINA 21142 58

View Lastest Price from 4-AMINO-3-BROMO-5-NITROPYRIDINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Amino-3-bromo-5-nitropyridine pictures 2025-01-03 4-Amino-3-bromo-5-nitropyridine
89284-05-9
US $1.00-1.00 / Kg/Drum 1g 98% 50tons Shaanxi Dideu Medichem Co. Ltd
4-AMINO-3-BROMO-5-NITROPYRIDINE pictures 2021-09-09 4-AMINO-3-BROMO-5-NITROPYRIDINE
89284-05-9
US $1.10 / g 1g 99.00% 100 Tons min Dideu Industries Group Limited
4-AMINO-3-BROMO-5-NITROPYRIDINE pictures 2019-12-23 4-AMINO-3-BROMO-5-NITROPYRIDINE
89284-05-9
US $1.00 / g 1g 99% 1000KGS Career Henan Chemical Co

4-AMINO-3-BROMO-5-NITROPYRIDINE Spectrum

4-AMINO-3-BROMO-5-NITROPYRIDINE 4-AMino-3-nitro-5-broMopyridine 4-AMino-3-broMo-5-nitropy... 4-Amino-3-bromo-5-nitropyridine 97% 3-bromo-5-nitro-4-pyridinamine 3-Bromo-4-amino-5-nitropyridine 4-Pyridinamine, 3-bromo-5-nitro- 4-AMINO-3-BROMO-5-NITROPYRIDINE ISO 9001:2015 REACH 89284-05-9 Pyridine