2-Chloro-5-nitrotoluene
- CAS No.
- 13290-74-9
- Chemical Name:
- 2-Chloro-5-nitrotoluene
- Synonyms
- 2-Chloro-5-nit;oro-5-nitrotoL;Chloronitroluene,98%;2-Chloro-5-nitroluene;2-Chloro-5-nitrotolune;Toltrazuril Impurity B;2-CHLORO-5-NITROTOLUENE;5-NITRO-2-CHLOROTOLUENE;3-Nitro-6-chlorotoluene;2-Chloro-5-nitrotoluene >
- CBNumber:
- CB3346769
- Molecular Formula:
- C7H6ClNO2
- Molecular Weight:
- 171.58
- MDL Number:
- MFCD00041430
- MOL File:
- 13290-74-9.mol
- MSDS File:
- SDS
| Melting point | 40-44 °C |
|---|---|
| Boiling point | 94-96°C 4mm |
| Density | 1.3246 (rough estimate) |
| refractive index | 1.5377 (estimate) |
| Flash point | 94-96°C/4mm |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Yellow to Green |
| BRN | 2044766 |
| InChI | 1S/C7H6ClNO2/c1-5-4-6(9(10)11)2-3-7(5)8/h2-4H,1H3 |
| InChIKey | BGDCQZFFNFXYQC-UHFFFAOYSA-N |
| SMILES | Cc1cc(ccc1Cl)[N+]([O-])=O |
| CAS DataBase Reference | 13290-74-9(CAS DataBase Reference) |
| EPA Substance Registry System | 2-Chloro-5-nitrotoluene (13290-74-9) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() ![]() ![]() GHS07,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H312-H331-H373-H401-H411-H302+H312+H332-H315-H319-H412 | |||||||||
| Precautionary statements | P261-P264-P270-P271-P273-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P501-P260-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,N | |||||||||
| Risk Statements | 22-52/53 | |||||||||
| Safety Statements | 22-36/37-61 | |||||||||
| RIDADR | UN 3457 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2902900000 | |||||||||
| Storage Class | 6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 4 Oral | |||||||||
| REACH Registrations | Active | |||||||||
| NFPA 704 |
|
2-Chloro-5-nitrotoluene price More Price(46)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | C1233 | 2-Chloro-5-nitrotoluene >98.0%(GC) | 13290-74-9 | 25g | $37 | 2026-04-30 | Buy |
| TCI Chemical | C1233 | 2-Chloro-5-nitrotoluene >98.0%(GC) | 13290-74-9 | 500g | $281 | 2026-04-30 | Buy |
| Usbiological | 267314 | 2-Chloro-5-nitrotoluene Asreported | 13290-74-9 | 25g | $392 | 2026-06-03 | Buy |
| Usbiological | 267314 | 2-Chloro-5-nitrotoluene Asreported | 13290-74-9 | 50g | $573 | 2026-06-03 | Buy |
| Usbiological | 267314 | 2-Chloro-5-nitrotoluene Asreported | 13290-74-9 | 100g | $822 | 2026-06-03 | Buy |
2-Chloro-5-nitrotoluene Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder
Uses
2-Chloro-5-nitrotoluene can be used to synthesize diazo photosensitive materials, microwave photography, and other applications.
Synthesis
99-52-5
13290-74-9
General procedure for the synthesis of 2-chloro-5-nitrotoluene from 4-nitro-2-methylaniline: First, 152 kg of 2-amino-5-nitrotoluene was dissolved in 600 kg of concentrated sulfuric acid, followed by the addition of 150 kg of water, and naturally heated to 100°C. After the reaction solution was completely dissolved, the temperature was lowered to 300 kg of industrial hydrochloric acid at a concentration of 30%. After 2-amino-5-nitrotoluene was completely dissolved, the temperature was lowered and 300 kg of industrial hydrochloric acid with a mass concentration of 30% was added, during which it was necessary to ensure that the temperature of the reaction solution did not exceed 0°C. The temperature of the reaction solution was then increased by 27 kg at a constant rate. Next, 276 kg of a 25% sodium nitrite solution was added at a constant rate to produce the diazonium salt solution. In another reactor, 450 kg of industrial hydrochloric acid was added and 225 kg of cuprous chloride was dissolved with stirring, and the temperature was reduced to below 20°C after dissolution. The prepared diazonium salt solution was quickly added to this reactor for rapid stirring and hydrolysis reaction. The reaction mixture was held for 2 hours before being warmed up to 55°C and maintained at this temperature for 2 hours. Finally, water vapor was distilled out by increasing the temperature until 160 kg of 2-chloro-5-nitrotoluene was collected in 93.3% yield.
References
[1] Patent: CN108373434, 2018, A. Location in patent: Paragraph 0032; 0033; 0035; 0036; 0037; 0040; 0041
[2] Chemische Berichte, 1887, vol. 20, p. 200
[3] Arzneimittel-Forschung/Drug Research, 1989, vol. 39, # 9, p. 1073 - 1080
2-Chloro-5-nitrotoluene Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TAIYUAN RHF CO.,LTD. | +86 351 7031519 | sales@RHFChem.com | China | 2334 | 56 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Shijiazhuang Sdyano Fine Chemical Co., Ltd. | 0311-89250318 13582355795 | master@sjzsdyn.com | China | 2776 | 65 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
View Lastest Price from 2-Chloro-5-nitrotoluene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-09-02 | 2-Chloro-5-nitrotoluene
13290-74-9
|
$1.00-100.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
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2026-06-30 | 2-Chloro-5-nitrotoluene
13290-74-9
|
1KG | 98.0% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
![]() |
2020-02-26 | 2-Chloro-5-nitrotoluene
13290-74-9
|
1KG | 99.0%+ | 100 tons | Shaanxi Dideu Medichem Co. Ltd |
-

- 2-Chloro-5-nitrotoluene
13290-74-9
- $1.00-100.00
- 99%
- Henan Fengda Chemical Co., Ltd
-

- 2-Chloro-5-nitrotoluene
13290-74-9
- 98.0%
- Shaanxi Dideu New Materials Co. Ltd
-

- 2-Chloro-5-nitrotoluene
13290-74-9
- 99.0%+
- Shaanxi Dideu Medichem Co. Ltd
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