3-Bromobenzenesulfonamide
- CAS No.
- 89599-01-9
- Chemical Name:
- 3-Bromobenzenesulfonamide
- Synonyms
- TCMDC-123819;BUTTPARK 95\57-08;3-BROMOBENZENESULFON;m-bromobenzenesulfonamide;3-Bromobenzenesulfonamide;3-BROMOBENZENESULPHONAMIDE;Benzenesulfonamide, 3-bromo-;3-BROMOBENZENE-1-SULFONAMIDE;3-Bromobenzene-1-Sulphonamide;3-Bromobenzenesulfonamide,97%
- CBNumber:
- CB3366169
- Molecular Formula:
- C6H6BrNO2S
- Molecular Weight:
- 236.09
- MDL Number:
- MFCD00084903
- MOL File:
- 89599-01-9.mol
- MSDS File:
- SDS
| Melting point | 151-156 °C(lit.) |
|---|---|
| Boiling point | 375.8±44.0 °C(Predicted) |
| Density | 1.754±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| pka | 9.81±0.60(Predicted) |
| color | White to Light yellow |
| InChI | 1S/C6H6BrNO2S/c7-5-2-1-3-6(4-5)11(8,9)10/h1-4H,(H2,8,9,10) |
| InChIKey | MUBJNMWVQGHHLG-UHFFFAOYSA-N |
| SMILES | NS(=O)(=O)c1cccc(Br)c1 |
| CAS DataBase Reference | 89599-01-9(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29350090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
3-Bromobenzenesulfonamide price More Price(58)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 563609 | 3-Bromobenzenesulfonamide 97% | 89599-01-9 | 1g | $57.6 | 2023-06-20 | Buy |
| TCI Chemical | B5734 | 3-Bromobenzenesulfonamide >98.0%(GC) | 89599-01-9 | 5g | $145 | 2026-04-30 | Buy |
| TCI Chemical | B5734 | 3-Bromobenzenesulfonamide >98.0%(GC) | 89599-01-9 | 25g | $424 | 2026-04-30 | Buy |
| Usbiological | 264035 | 3-Bromobenzenesulfonamide Asreported | 89599-01-9 | 5g | $433 | 2026-06-03 | Buy |
| Usbiological | 264035 | 3-Bromobenzenesulfonamide Asreported | 89599-01-9 | 10g | $616 | 2026-06-03 | Buy |
3-Bromobenzenesulfonamide Chemical Properties, Uses, Production
Uses
3-Bromobenzenesulfonamide is an amine derivative that can be used as a pharmaceutical intermediate.
Application
3-Bromobenzenesulfonamide can be used as a pharmaceutical synthesis intermediate. It can be prepared by reacting 3-bromobenzenesulfonyl chloride with ammonia, or by preparing it in one step from the diazonium salt of m-bromobenzene tetrafluoride.
Chemical Properties
white powder
Synthesis
2905-24-0
89599-01-9
Under ice bath conditions, 3-bromobenzenesulfonyl chloride (4.073 g, 15.94 mmol) was dissolved in dichloromethane (67 mL) and 25% ammonia solution (3.7 mL, 57.15 mmol) was slowly added. The reaction mixture was stirred at ice bath temperature for 0.5 hr, then brought to room temperature and continued stirring for 6 hr. Upon completion of the reaction, the precipitated solid was collected by filtration, washed with water and dried under vacuum in the presence of phosphorus pentoxide to afford 3-bromobenzenesulfonamide (3.270 g, 87% yield) in white crystalline form. NMR hydrogen spectrum (DMSO-d6) δ: 7.97 (t, J = 1.9 Hz, 1H), 7.84-7.80 (m, 2H), 7.54 (t, J = 7.9 Hz, 1H), 7.50 (bs, 2H). Liquid chromatography-mass spectrometry (ESI) m/z: 235.98 [M-H]-.
References
[1] Patent: WO2016/129983, 2016, A1. Location in patent: Page/Page column 18; 19
[2] Justus Liebigs Annalen der Chemie, 1875, vol. 177, p. 82
[3] ACS Medicinal Chemistry Letters, 2011, vol. 2, # 8, p. 603 - 607
[4] Bioorganic and Medicinal Chemistry Letters, 2014, vol. 24, # 9, p. 2222 - 2225
3-Bromobenzenesulfonamide Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Ark Pharm, Inc. | 847-367-3680 | sales@arkpharminc.com | United States | 1669 | 56 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Nanjing Chemlin Chemical Co., Ltd | 025-83697070 13770331960 | info@chemlin.com.cn | China | 16305 | 64 |
| Supplier | Advantage |
|---|---|
| J & K SCIENTIFIC LTD. | 76 |
| Alfa Aesar | 84 |
| Ark Pharm, Inc. | 56 |
| Energy Chemical | 61 |
| Wuhan Chemwish Technology Co., Ltd | 56 |
| Capot Chemical Co., Ltd | 66 |
| Jia Xing Isenchem Co.,Ltd | 66 |
| Adamas Reagent, Ltd. | 59 |
| Accela ChemBio Co.,Ltd. | 64 |
| Nanjing Chemlin Chemical Co., Ltd | 64 |
View Latest Price from 3-Bromobenzenesulfonamide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 3-BROMOBENZENESULFONAMIDE USP/EP/BP
89599-01-9
|
$1.10 | 1g | 99.9% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2020-01-03 | 3-BROMOBENZENESULFONAMIDE
89599-01-9
|
$1.00 | 1KG | 95-99% | 1ton | Career Henan Chemical Co |
-
- 3-BROMOBENZENESULFONAMIDE USP/EP/BP
89599-01-9
- $1.10
- 99.9%
- Dideu Industries Group Limited
-
- 3-BROMOBENZENESULFONAMIDE
89599-01-9
- $1.00
- 95-99%
- Career Henan Chemical Co
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