Methyl-2-bromo-4-bromomethylbenzoate
- CAS No.
- 128577-48-0
- Chemical Name:
- Methyl-2-bromo-4-bromomethylbenzoate
- Synonyms
- CAS:128577-48-0;2-bromo-4-bromethyl benzoate;Methyl 2-bromo-4-(bromomethyl);Methyl-2-bromo-4-bromomethylbenzoate;Benzoic acid, 2-bromo-4-(bromomethyl)-, methyl ester
- CBNumber:
- CB3491995
- Molecular Formula:
- C9H8Br2O2
- Molecular Weight:
- 307.97
- MDL Number:
- MFCD03840738
- MOL File:
- 128577-48-0.mol
- MSDS File:
- SDS
| Melting point | 53 - 56°C |
|---|---|
| Boiling point | 340.3±32.0 °C(Predicted) |
| Density | 1.780±0.06 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Soluble) |
| form | Solid |
| color | White to Off-White |
| Stability | Hygroscopic, Moisture Sensitive |
| InChI | InChI=1S/C9H8Br2O2/c1-13-9(12)7-3-2-6(5-10)4-8(7)11/h2-4H,5H2,1H3 |
| InChIKey | ZTDXOVAPGGNGSD-UHFFFAOYSA-N |
| SMILES | C(OC)(=O)C1=CC=C(CBr)C=C1Br |
Methyl-2-bromo-4-bromomethylbenzoate price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | TRC-M296273-500MG | Methyl-2-bromo-4-bromomethylbenzoate | 128577-48-0 | 500mg | $91 | 2026-06-03 | Buy |
| TRC | TRC-M296273-250MG | Methyl-2-bromo-4-bromomethylbenzoate | 128577-48-0 | 250mg | $78 | 2026-06-03 | Buy |
| TRC | TRC-M296273-100MG | Methyl-2-bromo-4-bromomethylbenzoate | 128577-48-0 | 100mg | $65 | 2026-06-03 | Buy |
| Apolloscientific | OR480825 | Methyl 2-bromo-4-(bromomethyl)benzoate 97% | 128577-48-0 | 100mg | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR480825 | Methyl 2-bromo-4-(bromomethyl)benzoate 97% | 128577-48-0 | 250mg | $24 | 2026-06-04 | Buy |
Methyl-2-bromo-4-bromomethylbenzoate Chemical Properties,Uses,Production
Synthesis
87808-49-9
128577-48-0
General procedure for the synthesis of methyl 2-bromo-4-bromomethylbenzoate from methyl 2-bromo-4-methylbenzoate: the reaction mixture was placed in a controlled microwave synthesizer of the model Biotage Initiator + SP Wave (power range 0-200 W, frequency 2.45 GHz, 60 W capped at steady state) and heated to 120 °C at 1 bar pressure for for several minutes. Upon completion of the reaction, the target product was isolated and purified by column chromatography using ethyl acetate-hexane gradient elution.
References
[1] Synlett, 2014, vol. 25, # 17, p. 2485 - 2487
[2] Patent: WO2016/89062, 2016, A2. Location in patent: Page/Page column 38; 39
[3] Patent: US2005/70584, 2005, A1. Location in patent: Page/Page column 24
[4] Patent: WO2008/124575, 2008, A1. Location in patent: Page/Page column 144
[5] Patent: WO2017/156165, 2017, A1. Location in patent: Paragraph 00504; 00505
Methyl-2-bromo-4-bromomethylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Suzhou Vosun Biotech Co.,Ltd | 18934576691 | yq@vosunbio.com | China | 704 | 58 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 18930552037 | 3bsc@sina.com | China | 15813 | 69 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Shanghai Ennopharm Co., Ltd. | +86 (21) 6435-5022 | China | 4263 | 65 | |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| Shanghai Topbiochem Technology Co., Ltd | 021-58170097 | info@topbiochem.com | China | 9513 | 58 |
| Nanjing Norris-Pharm Technology Co., Ltd | 13901585132 | sales@norris-pharm.com | China | 8869 | 55 |
| Hubei XinyuanShun Chemical Co., Ltd. | 13971561712, 13995564702, 027-50664929 | hbeixys2001@163.com | China | 3110 | 55 |
