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METHYL 2-BROMO-4-METHYLBENZOATE

METHYL 2-BROMO-4-METHYLBENZOATE structure

CAS No.: 87808-49-9

Chemical Name:: METHYL 2-BROMO-4-METHYLBENZOATE

Synonyms: RARECHEM AL BF 0916;2-bromo-4-methylbenzoate;Methyl2-Bromo-4-Methylbenzoat;METHYL 2-BROMO-4-METHYLBENZOATE;Methyl2-bromo-4-methylbenzoate,98%;Benzoic acid, 2-bromo-4-methyl-, methyl ester

CBNumber:: CB3473892

Molecular Formula:: C9H9BrO2

Molecular Weight:: 229.07

MDL Number:: MFCD03840737

MOL File:: 87808-49-9.mol

MSDS File:: SDS

Last updated:2026-05-28 01:12:02

Product description	Number	Pack Size	Price
Methyl 2-bromo-4-methylbenzoate 98%	AS40633	1g	$22
Methyl 2-bromo-4-methylbenzoate 98%	AS40633	5g	$33
Methyl 2-bromo-4-methylbenzoate 98%	AS40633	25g	$100
Methyl 2-bromo-4-methylbenzoate 98%	AS40633	100g	$271
Methyl 2-bromo-4-methylbenzoate 97%	AMTH186	1g	$12
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METHYL 2-BROMO-4-METHYLBENZOATE Properties

Boiling point	161-164 °C(Press: 32 Torr)
Density	1.433±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
form	Solid
Appearance	Colorless to off-white Solid-liquid mixture

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

HS Code

2916399090

NFPA 704

	1
2		0

METHYL 2-BROMO-4-METHYLBENZOATE price More Price(44)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Activate Scientific	AS40633	Methyl 2-bromo-4-methylbenzoate 98%	87808-49-9	1g	$22	2026-06-04	Buy
Activate Scientific	AS40633	Methyl 2-bromo-4-methylbenzoate 98%	87808-49-9	5g	$33	2026-06-04	Buy
Activate Scientific	AS40633	Methyl 2-bromo-4-methylbenzoate 98%	87808-49-9	25g	$100	2026-06-04	Buy
Activate Scientific	AS40633	Methyl 2-bromo-4-methylbenzoate 98%	87808-49-9	100g	$271	2026-06-04	Buy
AK Scientific	AMTH186	Methyl 2-bromo-4-methylbenzoate 97%	87808-49-9	1g	$12	2026-06-04	Buy

Product number	Packaging	Price	Buy
AS40633	1g	$22	Buy
AS40633	5g	$33	Buy
AS40633	25g	$100	Buy
AS40633	100g	$271	Buy
AMTH186	1g	$12	Buy

METHYL 2-BROMO-4-METHYLBENZOATE Chemical Properties,Uses,Production

Chemical Properties

off-white powder

Synthesis

67-56-1

7697-27-0

87808-49-9

The general procedure for the synthesis of methyl 2-bromo-4-methylbenzoate from methanol and 2-bromo-4-methylbenzoic acid was as follows: concentrated sulfuric acid (4 mL) was slowly added to an anhydrous methanol (200 mL) solution of 2-bromo-4-methylbenzoic acid (10.0 g, 46.5 mmol). The reaction mixture was heated to reflux for 18 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was concentrated. The residue was partitioned between water and ethyl acetate for extraction. After separating the organic and aqueous layers, the aqueous layer was then extracted with ethyl acetate (3 x 100 mL). All organic extracts were combined and washed sequentially with saturated sodium bicarbonate solution (2 x 50 mL) and brine, followed by drying with anhydrous magnesium sulfate. After filtration to remove the desiccant, the filtrate was concentrated to afford methyl 2-bromo-4-methylbenzoate (10.50 g, 99% yield), the product was a light amber colored oil. Mass spectrometry (MS) analysis showed m/z of 229.2 (M+H+).

References

[1] Patent: WO2008/124575, 2008, A1. Location in patent: Page/Page column 144
[2] Patent: WO2014/8197, 2014, A1. Location in patent: Page/Page column 163
[3] Patent: WO2015/95767, 2015, A1. Location in patent: Page/Page column 178
[4] Antimicrobial Agents and Chemotherapy, 2016, vol. 60, # 7, p. 3980 - 3987
[5] Patent: US2005/70584, 2005, A1. Location in patent: Page/Page column 23; 24

METHYL 2-BROMO-4-METHYLBENZOATE Preparation Products And Raw materials

Raw materials

2-Bromo-4-methylbenzoic acid Methanol

Preparation Products

Methyl 2-bromo-4-cyanobenzoate METHYL-2-BROMO-4-BROMOMETHYLBENZOATE

METHYL 2-BROMO-4-METHYLBENZOATE Suppliers

Global( 126)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Nanjing Dolon Biotechnology Co.,Ltd.	18905173768	52513593@qq.com	CHINA	2972	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2165	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
Fluoropharm Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Changzhou Ansciep Chemical Co., Ltd.	58
Jinan Carbotang Biotech Co.,Ltd.	58
Nanjing Dolon Biotechnology Co.,Ltd.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
Antai Fine Chemical Technology Co.,Limited	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58

METHYL 2-BROMO-4-METHYLBENZOATE Spectrum

METHYL 2-BROMO-4-METHYLBENZOATE(87808-49-9)¹HNMR

87808-49-9(METHYL 2-BROMO-4-METHYLBENZOATE)Related Search:

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METHYL 2-BROMO-4-METHYLBENZOATE 2-bromo-4-methylbenzoate RARECHEM AL BF 0916 Methyl2-Bromo-4-Methylbenzoat Benzoic acid, 2-bromo-4-methyl-, methyl ester Methyl2-bromo-4-methylbenzoate,98% 87808-49-9