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Methyl 2-bromo-4-methylbenzoate

Methyl 2-bromo-4-methylbenzoate Structure
Methyl 2-bromo-4-methylbenzoate structure
CAS No.
87808-49-9
Chemical Name:
Methyl 2-bromo-4-methylbenzoate
Synonyms
RARECHEM AL BF 0916;2-bromo-4-methylbenzoate;Methyl2-Bromo-4-Methylbenzoat;Methyl 2-bromo-4-methylbenzoate;Methyl2-bromo-4-methylbenzoate,98%;Benzoic acid, 2-bromo-4-methyl-, methyl ester
CBNumber:
CB3473892
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MDL Number:
MFCD03840737
MOL File:
87808-49-9.mol
MSDS File:
SDS
Last updated:2026-09-12 18:52:05
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Methyl 2-bromo-4-methylbenzoate Properties

Boiling point 161-164 °C(Press: 32 Torr)
Density 1.433±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form Solid
Appearance Colorless to off-white Solid-liquid mixture

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
HS Code  2916399090
NFPA 704
1
2 0

Methyl 2-bromo-4-methylbenzoate price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Activate Scientific AS40633 Methyl 2-bromo-4-methylbenzoate 98% 87808-49-9 1g $22 2026-06-04 Buy
Activate Scientific AS40633 Methyl 2-bromo-4-methylbenzoate 98% 87808-49-9 5g $33 2026-06-04 Buy
Activate Scientific AS40633 Methyl 2-bromo-4-methylbenzoate 98% 87808-49-9 25g $100 2026-06-04 Buy
Activate Scientific AS40633 Methyl 2-bromo-4-methylbenzoate 98% 87808-49-9 100g $271 2026-06-04 Buy
AK Scientific AMTH186 Methyl 2-bromo-4-methylbenzoate 97% 87808-49-9 1g $12 2026-06-04 Buy
Product number Packaging Price Buy
AS40633 1g $22 Buy
AS40633 5g $33 Buy
AS40633 25g $100 Buy
AS40633 100g $271 Buy
AMTH186 1g $12 Buy

Methyl 2-bromo-4-methylbenzoate Chemical Properties,Uses,Production

Chemical Properties

off-white powder

Synthesis

Methanol

67-56-1

2-Bromo-4-methylbenzoic acid

7697-27-0

METHYL 2-BROMO-4-METHYLBENZOATE

87808-49-9

The general procedure for the synthesis of methyl 2-bromo-4-methylbenzoate from methanol and 2-bromo-4-methylbenzoic acid was as follows: concentrated sulfuric acid (4 mL) was slowly added to an anhydrous methanol (200 mL) solution of 2-bromo-4-methylbenzoic acid (10.0 g, 46.5 mmol). The reaction mixture was heated to reflux for 18 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was concentrated. The residue was partitioned between water and ethyl acetate for extraction. After separating the organic and aqueous layers, the aqueous layer was then extracted with ethyl acetate (3 x 100 mL). All organic extracts were combined and washed sequentially with saturated sodium bicarbonate solution (2 x 50 mL) and brine, followed by drying with anhydrous magnesium sulfate. After filtration to remove the desiccant, the filtrate was concentrated to afford methyl 2-bromo-4-methylbenzoate (10.50 g, 99% yield), the product was a light amber colored oil. Mass spectrometry (MS) analysis showed m/z of 229.2 (M+H+).

References

[1] Patent: WO2008/124575, 2008, A1. Location in patent: Page/Page column 144
[2] Patent: WO2014/8197, 2014, A1. Location in patent: Page/Page column 163
[3] Patent: WO2015/95767, 2015, A1. Location in patent: Page/Page column 178
[4] Antimicrobial Agents and Chemotherapy, 2016, vol. 60, # 7, p. 3980 - 3987
[5] Patent: US2005/70584, 2005, A1. Location in patent: Page/Page column 23; 24

Methyl 2-bromo-4-methylbenzoate Preparation Products And Raw materials

Raw materials

2-Bromo-4-methylbenzoic acid Methanol

Preparation Products

Methyl 2-bromo-4-cyanobenzoate Methyl-2-bromo-4-bromomethylbenzoate

Methyl 2-bromo-4-methylbenzoate Suppliers

Global( 133)Suppliers
Supplier Tel Email Country ProdList Advantage
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Shanghai Ennopharm Co., Ltd. +86 (21) 6435-5022 China 4263 65
Shanghai Sunway Pharmaceutical Technology Co., Ltd 13761987713 hxzheng@sunwaypharm.cn China 8663 57
Shanghai Sphchem Co., Ltd. 021-56491756 13512199871 2819742715@qq.com China 3994 55
Supplier Advantage
Alfa Aesar 84
Energy Chemical 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 65
Capot Chemical Co., Ltd 66
Accela ChemBio Co.,Ltd. 64
Shanghai Longsheng chemical Co.,Ltd. 59
Shanghai Harvest Chemical Industrial Co., Ltd. 64
Shanghai Ennopharm Co., Ltd. 65
Shanghai Sunway Pharmaceutical Technology Co., Ltd 57
Shanghai Sphchem Co., Ltd. 55

Methyl 2-bromo-4-methylbenzoate Spectrum

METHYL 2-BROMO-4-METHYLBENZOATE(87808-49-9)1HNMR

87808-49-9(Methyl 2-bromo-4-methylbenzoate)Related Search:

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Benzoic acid,4-bromo-2-methyl-,methyl ester 2-Bromo-4-methylbenzoic acid METHYL 4-BROMO-3-METHYLBENZOATE METHYL 2-BROMO-3-METHYLBENZOATE methyl 5-bromo-2-methyl-benzoate
METHYL 3-BROMO-4-METHYLBENZOATE Methyl 2-bromo-6-methylbenzoate dimethyl 2,5-dibromoterephthalate Dimethyl 2-bromoterephthalate 2,5-Dibromo-4-methylbenzoic acid methyl ester
Methyl 4-bromo-2-methylbenzoate Methyl 5-bromo-2-methylbenzoate RARECHEM AL BI 0916

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2-bromo-4-methylbenzoate RARECHEM AL BF 0916 Methyl2-Bromo-4-Methylbenzoat Benzoic acid, 2-bromo-4-methyl-, methyl ester Methyl2-bromo-4-methylbenzoate,98% Methyl 2-bromo-4-methylbenzoate 87808-49-9