(2-Chlorobenzyl)triphenylphosphonium chloride hydrate
- CAS No.
- 18583-55-6
- Chemical Name:
- (2-Chlorobenzyl)triphenylphosphonium chloride hydrate
- Synonyms
- (2-chlorobenzyl)triphenylchlorophosphino;TRIPHENYL(2-CHLOROBENZYL)PHOSPHONIUM CHLORIDE;(O-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE;(2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE;(2-Chlorobenzyl)triphenylphosphonium Chloride >(2-Chlorobenzyl)triphenylphosphonium chloride hydrate;(2-Chlorobenzyl)triphenylphosphonium chloride - [C88869];(2-Chlorobenzyl)triphenylphosphonium chloridehydrate,98%;(2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE 98%;Phosphonium,[(2-chlorophenyl)methyl]triphenyl-, chloride (1:1)
- CBNumber:
- CB4247047
- Molecular Formula:
- C25H21ClP.Cl
- Molecular Weight:
- 423.31
- MDL Number:
- MFCD03427596
- MOL File:
- 18583-55-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 243-245 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | powder to crystal |
| color | White to Almost white |
| FDA UNII | BF8XZH2GMF |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-20/22 | |||||||||
| Safety Statements | 36/37/39-26 | |||||||||
| HS Code | 2931599090 | |||||||||
| NFPA 704 |
|
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate price More Price(31)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | C1759 | (2-Chlorobenzyl)triphenylphosphonium Chloride >98.0%(HPLC) | 18583-55-6 | 25g | $273 | 2026-04-30 | Buy |
| ChemScene | CS-0179381 | (2-Chlorobenzyl)triphenylphosphonium chloride ≥98% | 18583-55-6 | 25g | $64 | 2026-06-04 | Buy |
| ChemScene | CS-0179381 | (2-Chlorobenzyl)triphenylphosphonium chloride ≥98% | 18583-55-6 | 100g | $239 | 2026-06-04 | Buy |
| Activate Scientific | AS107553 | (2-Chlorobenzyl)triphenylphosphonium chloride 96% | 18583-55-6 | 1g | $24 | 2026-06-04 | Buy |
| Activate Scientific | AS107553 | (2-Chlorobenzyl)triphenylphosphonium chloride 96% | 18583-55-6 | 5g | $49 | 2026-06-04 | Buy |
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate Chemical Properties, Uses, Production
Synthesis
(1) Synthetic route of (2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE 1 mmol of 2-chlorobenzyltriphenylphosphine and 1.6 mmol of triphenylphosphine were dissolved in 20 mL of acetone and stirred under reflux at 65–70 °C for 24 hours. During this period, a white precipitate was formed. After natural cooling, the mixture was filtered and the filter cake was washed with a small amount of acetone and diethyl ether to remove impurities and accelerate drying. Then, it was dried under vacuum to obtain 2-chlorobenzyltriphenylphosphine bromide with a yield of 79.3%. Infrared spectroscopy analysis: IR (cm-1): (benzene ring C-H): 3053; (CH2): 2925, 2884; (C=C): 1587, 1432; (C-P): 1111; (2) 1 mmol of the obtained 2-chlorobenzyltriphenylphosphine bromide and 0.45 μL of CuCl2·2H2O were added. mmol was dissolved in 15 mL of methanol, and then 0.5 mL of hydrochloric acid was added. The mixture was stirred continuously and heated under reflux for 0.5 h. After natural cooling, it was filtered. The filtrate was allowed to stand and evaporate naturally. After 2 weeks, light green crystals precipitated, which was the product, with a yield of 68.0%.
Chemical Properties
white to light yellow crystalline powder
Uses
(2-Chlorobenzyl)triphenylphosphonium Chloride is a reagent in Wittig reaction with imidazolecarboxaldehyde to synthesize elevel 4-(5)arylethenylimidazoles.
(2-Chlorobenzyl)triphenylphosphonium chloride hydrate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Beijing Donghualituo Techonlogy Development Co.,Ltd. | 010-88425576 | sales@dhltchem.com | China | 793 | 59 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7236 | 62 |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
View Latest Price from (2-Chlorobenzyl)triphenylphosphonium chloride hydrate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-07-06 | (2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
18583-55-6
|
$1.00 | 1KG | 95% | 500KG | Career Henan Chemical Co |
-
- (2-CHLOROBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
18583-55-6
- $1.00
- 95%
- Career Henan Chemical Co
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