Carbonyldihydrotris(triphenylphosphine)ruthenium
- CAS No.
- 25360-32-1
- Chemical Name:
- Carbonyldihydrotris(triphenylphosphine)ruthenium
- Synonyms
- ruthenium(II);CARBONYLDIHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);Carbonyl(dihydrido);tris(triphenylphosphine);carbon monoxide ruthenium triphenylphosphane;CARBONYLTRIS(TRIPHENYLPYOSPHINE)RUTHENIUM(II);Carbonyldihydrotris(triphenylphosphine)ruthenium;Dihydridocarbonyltris(triphenylphosphine) ruthenium;Dihydridotris(triphenylphosphine)ruthenium carbonyl;Dihydridocarbonyltris-(triphenylphosphino)-ruthenium
- CBNumber:
- CB4491543
- Molecular Formula:
- C55H45OP3Ru
- Molecular Weight:
- 915.94
- MDL Number:
- MFCD00015870
- MOL File:
- 25360-32-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 161-163 °C(lit.) |
|---|---|
| storage temp. | Inert atmosphere,2-8°C |
| form | Powder |
| color | white to off-white |
| Water Solubility | Insoluble in water. |
| Sensitive | Moisture Sensitive |
| InChI | 1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;; |
| InChIKey | MLIYPCQSOXNTLJ-UHFFFAOYSA-N |
| SMILES | [RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| UNSPSC Code | 12352202 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332 | |||||||||
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 36 | |||||||||
| RIDADR | UN2813 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral |
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| NFPA 704 |
|
Carbonyldihydrotris(triphenylphosphine)ruthenium price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 335002 | Carbonyldihydridotris(triphenylphosphine)ruthenium(II) | 25360-32-1 | 1g | $180 | 2026-04-30 | Buy |
| TCI Chemical | C2251 | Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II) | 25360-32-1 | 1g | $108 | 2026-04-30 | Buy |
| TCI Chemical | C2251 | Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II) | 25360-32-1 | 250mg | $41 | 2026-04-30 | Buy |
| Strem Chemicals | 44-0100 | Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II), 99% 99% | 25360-32-1 | 250mg | $61 | 2026-04-30 | Buy |
| Strem Chemicals | 44-0100 | Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II), 99% 99% | 25360-32-1 | 1g | $179 | 2026-04-30 | Buy |
Carbonyldihydrotris(triphenylphosphine)ruthenium Chemical Properties, Uses, Production
Reaction
- Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.
- Catalytic C-C bond formation.
- Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.
- Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.
- Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.
- Precatalyst for hydrogen production by means of alcohol dehydrogenation.
Chemical Properties
White to off-white powder
Uses
&bull Catalyst for conversion of 1,4-alkynediols into pyrroles &bull Catalyst for oxidation of primary alcohols to methyl esters &bull Catalyst for rearrangement of oximes to amides &bull Catalyst for C-C coupling via directed C-H activation &bull Cata
Uses
Carbonyldihydrotris(triphenylphosphine)ruthenium(II) is a catalyst used in the preparation of ruthenium (diphenylphosphino)ethyl)amine complexes pre-catalysts for hydrogenation and dehydrogenation.
Uses
- Catalyst for conversion of 1,4-alkynediols into pyrroles
- Catalyst for oxidation of primary alcohols to methyl esters
- Catalyst for rearrangement of oximes to amides
- Catalyst for C-C coupling via directed C-H activation
- Catalyst for enyne cyclization
reaction suitability
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
Carbonyldihydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| T&W GROUP | 021-61551611 13296011611 | contact@trustwe.com | China | 9884 | 58 |
| Shanghai civi chemical technology co.,Ltd | 86-21-34053660 | sale@labgogo.com | China | 9853 | 52 |
View Latest Price from Carbonyldihydrotris(triphenylphosphine)ruthenium manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2021-07-02 | Carbonyldihydrotris(triphenylphosphine)ruthenium
25360-32-1
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
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2019-07-06 | Carbonyldihydrotris(triphenylphosphine)ruthenium
25360-32-1
|
$1.00 | 1kg | 95%-99% | 100kg | Career Henan Chemical Co |
-

- Carbonyldihydrotris(triphenylphosphine)ruthenium
25360-32-1
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- Carbonyldihydrotris(triphenylphosphine)ruthenium
25360-32-1
- $1.00
- 95%-99%
- Career Henan Chemical Co
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