Ruthenium carbonyl
- CAS No.
- 15243-33-1
- Chemical Name:
- Ruthenium carbonyl
- Synonyms
- Ru3(CO)12;TRIRUTHENIUM DODECACARBONYL;DODECACARBONYLTRIRUTHENIUM;pentaoxonium;RUTHENIUM CARBONYL;Rutheniumcarbonyl,99%;Ruthenium carbonyl 99%;carbon monoxide ruthenium;DIRUTHENIUM DODECACARBONYL;Ruthenium,dodecacarbonyltri-
- CBNumber:
- CB9426890
- Molecular Formula:
- C12O12Ru3
- Molecular Weight:
- 639.33
- MDL Number:
- MFCD00011209
- MOL File:
- 15243-33-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 150 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. |
| form | crystal |
| color | orange |
| InChI | InChI=1S/12CO.3Ru/c12*1-2;;; |
| InChIKey | NQZFAUXPNWSLBI-UHFFFAOYSA-N |
| SMILES | [O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[Ru].[Ru].[Ru] |
| CAS DataBase Reference | 15243-33-1(CAS DataBase Reference) |
| EPA Substance Registry System | Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H332 | |||||||||
| Precautionary statements | P261-P271-P304+P340+P312 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | F,Xn | |||||||||
| Risk Statements | 11-20-2017/11/20 | |||||||||
| Safety Statements | 24/25 | |||||||||
| RIDADR | 1325 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Flammable/Harmful | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Inhalation | |||||||||
| NFPA 704 |
|
Ruthenium carbonyl price More Price(42)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 245011 | Triruthenium dodecacarbonyl 99% | 15243-33-1 | 1g | $129 | 2026-04-30 | Buy |
| Sigma-Aldrich | 245011 | Triruthenium dodecacarbonyl 99% | 15243-33-1 | 5g | $460 | 2026-04-30 | Buy |
| TCI Chemical | T2181 | Triruthenium Dodecacarbonyl | 15243-33-1 | 100mg | $61 | 2026-04-30 | Buy |
| TCI Chemical | T2181 | Triruthenium Dodecacarbonyl | 15243-33-1 | 1g | $284 | 2026-04-30 | Buy |
| Strem Chemicals | 44-1850 | Ruthenium carbonyl, 99% 99% | 15243-33-1 | 25g | $5000 | 2026-04-30 | Buy |
Ruthenium carbonyl Chemical Properties, Uses, Production
Description
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.
Chemical Properties
The substance appears as orange plates or powder and is soluble in non-polar organic solvents.
Uses
Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
Reactions
- Catalyst for the conversion of enynes to catechol derivatives.
- Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
- 3-Component couplings.
- Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
- Ester decarboxylation.
- Catalyst for hydroamination and C-H bond activation.
- Used in sp3 C-H bond arylation and carbonylation.
- Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
- Amination of α-hydroxy amides.
General Description
Atomic number of base material: 44 Ruthenium
reaction suitability
core: ruthenium
reaction type: C-H Activation
reagent type: catalyst
Ruthenium carbonyl Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Rock New Materials Co., Ltd. | 0917-8888777 18691786767 | liuwei@bjrock.com | China | 309 | 62 |
| Fujian Wolfa Biotechnology Co., Ltd | 18050950397 | jomin@wolfachem.com | China | 230 | 58 |
| Shandong Xiya Chemical Co., Ltd. | 4009903999 13395398332 | sales@xiyashiji.com | China | 20788 | 60 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3563 | 66 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
View Latest Price from Ruthenium carbonyl manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-18 | Ruthenium Carbonyl
15243-33-1
|
1g | 98%min Ru:46.45% | 500g | WUHAN FORTUNA CHEMICAL CO., LTD | ||
 |
2026-03-20 | Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12
15243-33-1
|
$1.00 | 1KG | 99 | 300kg | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2019-12-23 | RUTHENIUM CARBONYL
15243-33-1
|
$1.00 | 100g | 99% | Career Henan Chemical Co |
-
- Ruthenium Carbonyl
15243-33-1
- $0.00
- 98%min Ru:46.45%
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12
15243-33-1
- $1.00
- 99
- Hebei Chuanghai Biotechnology Co., Ltd
-
- RUTHENIUM CARBONYL
15243-33-1
- $1.00
- 99%
- Career Henan Chemical Co
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